File name: Pandora105s1_Helsinki_20161112_L2Fit_fwvt1c2d20161104p1-8.txt File generation date: 20251122T143517.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20150702.txt Instrument calibration file used: Pandora105s1_CF_v2d20161104.txt Level 1 file used: Pandora105s1_Helsinki_20161112_L1_smca1c2d20161104p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20161112 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1622 1772 Nominal wavelengths inside fitting window [nm]: 492.0569 492.1776 492.2983 492.4190 492.5397 492.6603 492.7810 492.9016 493.0222 493.1428 493.2633 493.3839 493.5044 493.6249 493.7454 493.8659 493.9864 494.1069 494.2273 494.3477 494.4681 494.5885 494.7088 494.8292 494.9495 495.0698 495.1901 495.3104 495.4307 495.5509 495.6711 495.7914 495.9115 496.0317 496.1519 496.2720 496.3921 496.5122 496.6323 496.7524 496.8725 496.9925 497.1125 497.2325 497.3525 497.4725 497.5924 497.7123 497.8323 497.9522 498.0720 498.1919 498.3117 498.4316 498.5514 498.6712 498.7910 498.9107 499.0305 499.1502 499.2699 499.3896 499.5092 499.6289 499.7485 499.8682 499.9878 500.1073 500.2269 500.3464 500.4660 500.5855 500.7050 500.8245 500.9439 501.0634 501.1828 501.3022 501.4216 501.5410 501.6603 501.7797 501.8990 502.0183 502.1376 502.2568 502.3761 502.4953 502.6145 502.7337 502.8529 502.9721 503.0912 503.2104 503.3295 503.4486 503.5676 503.6867 503.8057 503.9248 504.0438 504.1628 504.2817 504.4007 504.5196 504.6385 504.7574 504.8763 504.9952 505.1140 505.2328 505.3517 505.4705 505.5892 505.7080 505.8267 505.9454 506.0642 506.1828 506.3015 506.4202 506.5388 506.6574 506.7760 506.8946 507.0132 507.1317 507.2502 507.3688 507.4873 507.6057 507.7242 507.8426 507.9611 508.0795 508.1978 508.3162 508.4346 508.5529 508.6712 508.7895 508.9078 509.0261 509.1443 509.2626 509.3808 509.4990 509.6171 509.7353 509.8535 509.9716 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20161112T062152.0Z 6160.265185 2 1 32.00 2 89.91 128.21 113.78 332.69 0.00 1 0.00 1 0 34 1.765e-01 1.509e-01 1.810e-01 1.696e-01 7.571515e+03 1.131359e+04 2.031460e+03 -6.000000e+00 9.314065e+03 265.51 -2.00 20.00 -2.00 505.24 0.00e+00 1.053785e-03 4.489741e-03 1.432121e-04 -6.000000e+00 4.815797e-03 265.51 -2.00 20.00 -2.00 500.00 0.00e+00 -1.193213e+00 3.522209e+00 2.868979e-01 -6.000000e+00 3.541283e+00 219.03 -2.00 4.26 -2.00 501.63 0.00e+00 20.730 0.232 489.00 513.00 1 1.8067e+00 2.6646e-01 4.8063e-02 -6.0000e+00 2.6995e-01 2.0458e-01 7.0309e-02 3.6141e-03 -6.0000e+00 7.0434e-02 1.8128e-02 3.2383e-03 1.5158e-02 1.4058e-04 -6.0000e+00 1.6976e-02 2.2619e-02 9.3657e-05 12 8 8 10 0 0 69.59 17.36 13.27 0.02262 0.04508 8 2 1 5 0 4000.000 20.35 14.83 17.36 28314 5763 8472 1042 -9244 4301 7689 18407 -7955 -6245 -1295 17518 -10673 26932 -11096 27349 -8068 18779 14667 18202 2346 7596 4105 -23065 1347 -7894 11746 -15669 -13406 -4810 8409 -6908 30164 14619 7540 10972 28590 -22276 -5357 12258 -12080 -3813 -6862 -7324 -18900 34650 -3053 11058 -10259 3470 -13197 5796 10981 36626 -5333 11426 4190 1860 -6635 -15598 -9567 19636 7414 -16460 -9747 1295 6689 -3786 5490 4939 12690 17383 7443 -14048 -15196 12591 2053 10037 -9144 24097 15601 19272 18678 26814 -26966 73714 4257 11784 13535 28404 34256 -3940 -8221 5650 4096 47 25469 7786 33670 -5134 5821 -34838 -920 17709 11220 -10274 -457 -3311 -4901 -3368 -24292 48054 -4110 4163 -2709 17345 -30469 33881 -20131 69466 2101 10763 1337 -828 -3209 16314 2237 1554 589 -19231 10939 -944 20917 8254 -1336 -21335 -3260 -2334 6980 -6067 9948 7424 371 -204 13179 20019 2457 41463 -4072 11112 900000 21537 5586 8272 1128 -11229 4647 8147 17740 -9818 -7457 -1449 16149 -12638 22006 -12987 22309 -9398 17323 14384 17321 2591 7951 4455 -32712 1513 -9626 11794 -20194 -16383 -5266 7970 -7642 24107 14037 7868 11047 24035 -30253 -6123 11690 -14610 -4282 -8031 -8709 -25207 27702 -3470 10847 -12116 3479 -15176 5433 9709 25659 -5772 10778 4326 1957 -7577 -19423 -11247 17486 7424 -20705 -11341 1339 6446 -4004 5233 4674 11039 14493 6944 -16363 -18003 11257 1998 8866 -9629 18314 12965 15551 15272 20416 -34728 36355 4071 10498 11806 21549 24703 -4158 -9081 5449 3928 45 18796 6625 21804 -4781 4853 -43836 -865 14577 10044 -11353 -455 -3319 -4957 -3380 -30267 30111 -4302 4022 -2807 14891 -41605 25009 -24760 35654 2022 9322 1254 -796 -3179 13409 2095 1459 557 -21957 9217 -879 15509 6828 -1219 -23767 -3118 -2247 6193 -6190 8700 6683 360 -197 11239 15793 2248 25430 -3802 8950 900000 SO 20161112T062355.0Z 6160.266609 4 1 32.00 2 89.72 128.66 113.88 333.21 0.00 1 0.00 1 0 47 1.439e-01 1.331e-01 1.584e-01 1.506e-01 3.037497e+03 9.208747e+03 3.343718e+02 -6.000000e+00 7.587969e+03 265.51 -2.00 20.00 -2.00 505.17 0.00e+00 4.899798e-03 3.914770e-03 3.522186e-04 -6.000000e+00 3.915546e-03 265.51 -2.00 20.00 -2.00 499.86 0.00e+00 -4.905102e-01 3.069201e+00 5.938072e-02 -6.000000e+00 2.861306e+00 219.03 -2.00 4.26 -2.00 501.49 0.00e+00 20.442 0.222 489.00 513.00 1 1.6330e+00 2.3123e-01 4.3399e-02 -6.0000e+00 2.1849e-01 2.3121e-01 6.1169e-02 2.3657e-03 -6.0000e+00 5.6268e-02 2.0535e-02 1.2714e-02 1.3752e-02 1.0346e-04 -6.0000e+00 1.3626e-02 3.5163e-02 -1.5278e-04 12 9 8 11 8 0 -219.40 17.38 9.49 0.03516 0.12335 8 2 1 5 0 4000.000 20.35 15.26 17.38 -8757 22430 2484 -11512 -7508 6035 18947 16805 -92 29512 -9320 4962 37417 -6787 -23842 16603 22584 -8342 5755 3687 -16857 10094 -12356 7727 -3511 27766 -5602 18507 -13653 8653 9335 13139 -781 -15132 14057 10104 20966 8910 -12232 22222 14421 10039 -13588 -7714 -9114 5507 21297 -23638 -10443 1963 4340 -12166 8528 -14484 -18360 -2605 -5945 16995 4261 2641 -5191 7678 -13962 -10068 2133 24724 1571 -457 10936 1936 10343 23809 27654 -13576 24999 -10339 6279 -994 28942 17113 28351 3455 13142 19662 3372 -9513 -1709 14319 -14385 1347 -11630 -15507 1009 -3887 11012 17890 -956 -13469 -9280 13682 31947 22587 -8288 6366 10136 -22993 -3079 18337 -10936 -10273 1609 19864 13208 -5490 -17573 -854 8078 -2163 -4273 -593 -6931 15095 11490 1779 17785 30792 13460 -9282 -7143 -8638 -15256 -4729 1455 -15378 9819 -2124 15557 14965 -4242 8879 -9730 -4144 15885 2440 39349 -14267 -9997 16399 5093 17420 5594 -9926 19518 2707 -14677 -9369 6685 18769 16959 -107 25355 -11420 5228 28297 -7771 -32296 15268 19963 -10201 6188 4045 -22463 10351 -15779 8187 -4140 24271 -6666 17059 -16626 8261 8809 12127 -850 -19475 13900 10227 18943 8900 -14848 19427 13620 10027 -17275 -9363 -11281 5872 19341 -32596 -12450 2010 4221 -13717 7825 -16974 -23111 -2876 -6875 15757 4436 2790 -5960 7792 -17468 -12037 2243 20551 1608 -472 9927 1898 9279 18933 21427 -15815 19928 -11446 5812 -968 20936 13927 20710 3225 11183 15780 3182 -10225 -1693 12117 -16051 1289 -12813 -17941 1009 -4037 9773 14516 -914 -14113 -9098 10557 20700 16395 -8347 5702 8819 -27376 -2976 14235 -11206 -10609 1504 15852 11400 -5708 -20540 -855 7429 -2180 -4339 -574 -6967 12127 9575 1632 14062 21533 11077 -9479 -7076 -8656 -16119 -4440 1261 -15497 7771 -1909 12027 11792 -4054 7476 -9807 -3983 12528 2204 24854 -14830 -9705 11985 4098 12415 4558 SO 20161112T062554.0Z 6160.267986 6 1 32.00 2 89.52 129.09 113.98 333.72 0.00 1 0.00 1 0 36 1.484e-01 1.277e-01 1.391e-01 1.318e-01 6.436139e+03 8.695096e+03 6.923560e+02 -6.000000e+00 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