File name: Pandora105s1_Helsinki_20161113_L2Fit_fwvt1c2d20161104p1-8.txt File generation date: 20251122T143513.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20150702.txt Instrument calibration file used: Pandora105s1_CF_v2d20161104.txt Level 1 file used: Pandora105s1_Helsinki_20161113_L1_smca1c2d20161104p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20161113 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1622 1772 Nominal wavelengths inside fitting window [nm]: 492.0569 492.1776 492.2983 492.4190 492.5397 492.6603 492.7810 492.9016 493.0222 493.1428 493.2633 493.3839 493.5044 493.6249 493.7454 493.8659 493.9864 494.1069 494.2273 494.3477 494.4681 494.5885 494.7088 494.8292 494.9495 495.0698 495.1901 495.3104 495.4307 495.5509 495.6711 495.7914 495.9115 496.0317 496.1519 496.2720 496.3921 496.5122 496.6323 496.7524 496.8725 496.9925 497.1125 497.2325 497.3525 497.4725 497.5924 497.7123 497.8323 497.9522 498.0720 498.1919 498.3117 498.4316 498.5514 498.6712 498.7910 498.9107 499.0305 499.1502 499.2699 499.3896 499.5092 499.6289 499.7485 499.8682 499.9878 500.1073 500.2269 500.3464 500.4660 500.5855 500.7050 500.8245 500.9439 501.0634 501.1828 501.3022 501.4216 501.5410 501.6603 501.7797 501.8990 502.0183 502.1376 502.2568 502.3761 502.4953 502.6145 502.7337 502.8529 502.9721 503.0912 503.2104 503.3295 503.4486 503.5676 503.6867 503.8057 503.9248 504.0438 504.1628 504.2817 504.4007 504.5196 504.6385 504.7574 504.8763 504.9952 505.1140 505.2328 505.3517 505.4705 505.5892 505.7080 505.8267 505.9454 506.0642 506.1828 506.3015 506.4202 506.5388 506.6574 506.7760 506.8946 507.0132 507.1317 507.2502 507.3688 507.4873 507.6057 507.7242 507.8426 507.9611 508.0795 508.1978 508.3162 508.4346 508.5529 508.6712 508.7895 508.9078 509.0261 509.1443 509.2626 509.3808 509.4990 509.6171 509.7353 509.8535 509.9716 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20161113T062428.0Z 6161.266991 2 1 32.01 2 89.92 128.86 105.94 321.05 0.00 1 0.00 1 0 29 9.235e-02 8.782e-02 1.053e-01 1.022e-01 -1.929801e+03 5.709608e+03 2.530736e+02 -6.000000e+00 4.871753e+03 265.33 -2.00 20.00 -2.00 505.21 0.00e+00 1.189060e-03 2.696370e-03 1.703229e-04 -6.000000e+00 2.517431e-03 265.33 -2.00 20.00 -2.00 499.84 0.00e+00 4.249371e+00 2.097876e+00 3.787304e-02 -6.000000e+00 1.852033e+00 218.89 -2.00 4.26 -2.00 501.51 0.00e+00 20.740 0.232 489.00 513.00 1 9.1345e-01 1.5979e-01 4.4020e-02 -6.0000e+00 1.4117e-01 1.2107e-01 4.1256e-02 2.4873e-03 -6.0000e+00 3.6802e-02 3.0777e-02 1.8135e-02 9.4026e-03 6.3471e-05 -6.0000e+00 8.8773e-03 -1.7833e-02 3.9300e-04 12 9 8 11 8 0 65.07 17.66 0.11 -0.01783 0.10796 8 2 1 5 0 4000.000 20.56 14.80 17.66 8032 -814 7066 -7438 9672 7589 -1786 -3925 715 7910 1058 -7750 245 -3304 -2587 11636 -4107 -5524 5795 -1585 -1692 -6193 7610 -6683 6549 5154 2029 500 1390 -10923 -5179 1731 -2148 8108 -453 1460 3861 5632 -6065 4062 5020 2738 10920 7831 -8956 -7443 4898 -2907 11363 3479 120 -12353 -15362 -11885 -6366 16308 5838 6577 8500 4931 6634 2522 -2535 8966 7789 -19451 -4914 4149 9679 -6596 -11598 -10360 903 -11886 13528 -6660 22397 5314 2027 20557 -5750 11929 13382 -1371 15822 -6509 -3452 -14743 13246 -10931 -311 -1171 14072 3712 -6628 -5706 4347 -12022 493 13028 8858 3363 844 -14005 12218 2017 -14603 -1796 6287 14145 21786 -4119 1395 3260 -6401 15044 2832 -5811 -3648 5576 16295 -14238 3353 4737 -12240 5839 6724 4747 -14378 5690 8050 166 11642 -5607 19599 7971 6583 -11420 13885 -12327 -19598 23006 -4492 -888 4375 11721 -1807 951 -3928 18242 900000 7543 -858 7102 -8843 9882 8048 -2077 -4638 795 8134 1141 -8998 260 -3614 -2827 11329 -4772 -6605 6286 -1836 -1962 -7521 8155 -8230 7057 5605 2244 546 1455 -12740 -5745 1841 -2445 8591 -519 1620 4130 5847 -7032 4260 5252 2960 10992 8186 -10975 -8900 5140 -3208 10667 3426 119 -13642 -17680 -13602 -7096 14875 5886 6551 8264 4967 6598 2617 -2735 8587 7416 -23506 -5102 3883 8510 -6702 -12403 -11054 872 -13014 11536 -6746 16783 4643 1826 15569 -5611 9873 10980 -1304 12844 -6556 -3368 -15970 11048 -11507 -301 -1151 12032 3472 -6791 -5698 3835 -12175 431 10071 7175 2963 787 -15227 10223 1820 -15287 -1642 5342 11392 16573 -4066 1329 3071 -6620 12688 2669 -5907 -3573 4912 12869 -15025 3013 4224 -12851 5152 5870 4229 -15415 5003 6811 148 9214 -5222 14499 6729 5754 -12030 11542 -13275 -22600 17699 -4548 -870 4041 9865 -1695 849 -3670 13831 900000 SO 20161113T062632.0Z 6161.268426 4 1 32.01 2 89.72 129.30 106.09 321.54 0.00 1 0.00 1 0 41 1.101e-01 1.003e-01 9.757e-02 9.367e-02 -4.314703e+03 5.348465e+03 4.998748e+02 -6.000000e+00 5.805107e+03 265.33 -2.00 20.00 -2.00 505.21 0.00e+00 -1.347699e-03 2.526915e-03 9.310482e-05 -6.000000e+00 3.001384e-03 265.33 -2.00 20.00 -2.00 499.77 0.00e+00 5.418250e+00 1.969196e+00 3.688836e-02 -6.000000e+00 2.202045e+00 218.89 -2.00 4.26 -2.00 501.46 0.00e+00 20.453 0.222 489.00 513.00 1 8.1656e-01 1.5126e-01 4.2644e-02 -6.0000e+00 1.6802e-01 1.1115e-01 3.8581e-02 2.4812e-03 -6.0000e+00 4.3611e-02 3.3639e-02 -1.8593e-03 8.6342e-03 7.9410e-05 -6.0000e+00 1.0652e-02 -1.7238e-04 5.5539e-04 12 9 8 11 8 0 -272.66 17.68 2.99 -0.00017 -0.01307 8 2 1 5 0 4000.000 20.67 15.10 17.68 9076 -3778 18680 -13232 -7712 -8944 6672 -1169 -5193 -7710 9688 5382 -5904 35636 6257 2518 546 6885 -3787 11327 -408 2118 -4140 14516 -432 9241 -3487 3743 -6137 2588 -1028 6762 4962 -3198 1018 -11622 -5783 -17473 4368 -13457 -5070 8007 7931 6195 15006 6346 15497 804 6542 3168 -12350 8035 -558 48927 -316 -14648 -2261 6346 -13450 5991 -13579 20525 1794 7005 -5367 4780 8991 20410 4040 -10120 3775 -6912 -463 -24679 -6792 -4709 6776 6612 11943 14522 -658 13668 -2442 28598 9994 -2388 -14628 730 -147 -871 -5572 16529 -21135 67 -1436 11281 -3435 10810 -5773 -9036 9677 768 6772 -7488 6503 20030 10499 -11907 8312 3947 21305 -7494 -11990 -3170 15469 -6012 -6049 7862 4545 4759 13496 3150 -13449 6082 -5063 27 -8587 14842 -265 16720 10048 -2463 2452 -118 4116 -4433 -10322 401 13792 434 19777 -2571 -1209 -10929 -5324 -5575 -5514 -9249 12352 24209 900000 8392 -4047 16691 -16478 -9287 -11126 7273 -1375 -6320 -9492 9977 5671 -6873 27571 6378 2690 608 7414 -4597 11994 -482 2439 -5083 14969 -514 9952 -4237 4162 -7305 2737 -1116 6867 5289 -3802 1181 -15257 -7065 -23469 4692 -17016 -5942 8277 8269 6627 14753 6774 14918 875 6624 3221 -14088 7351 -547 30411 -323 -17615 -2455 6323 -16106 5918 -16182 17582 1838 6827 -5791 4574 8167 16309 3719 -10575 3404 -6958 -442 -30171 -6959 -4693 5886 5653 9606 11376 -598 10934 -2289 19943 8405 -2286 -15726 678 -138 -828 -5550 13487 -25052 65 -1406 9631 -3346 8914 -5479 -8698 7718 681 5835 -7586 5767 15433 8709 -12046 6824 3414 15870 -7471 -12710 -3112 12778 -6129 -6166 6924 4082 4201 10872 2774 -13914 5254 -4872 24 -8544 11750 -242 13026 8314 -2257 2102 -103 3431 -4065 -10300 368 11287 406 15428 -2500 -1168 -11655 -5386 -5609 -5427 -9198 9785 17152 900000 SO 20161113T062831.0Z 6161.269803 6 1 32.00 2 89.53 129.74 106.23 322.00 0.00 1 0.00 1 0 40 8.315e-02 8.060e-02 8.727e-02 8.510e-02 1.718044e+03 4.947056e+03 4.170289e+02 -6.000000e+00 4.384460e+03 265.33 -2.00 20.00 -2.00 505.18 0.00e+00 3.375835e-03 2.268536e-03 1.182049e-04 -6.000000e+00 2.262623e-03 265.33 -2.00 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