File name: Pandora105s1_Helsinki_20161118_L2Fit_fwvt1c2d20161104p1-8.txt File generation date: 20251122T143557.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20150702.txt Instrument calibration file used: Pandora105s1_CF_v2d20161104.txt Level 1 file used: Pandora105s1_Helsinki_20161118_L1_smca1c2d20161104p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20161118 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1622 1772 Nominal wavelengths inside fitting window [nm]: 492.0569 492.1776 492.2983 492.4190 492.5397 492.6603 492.7810 492.9016 493.0222 493.1428 493.2633 493.3839 493.5044 493.6249 493.7454 493.8659 493.9864 494.1069 494.2273 494.3477 494.4681 494.5885 494.7088 494.8292 494.9495 495.0698 495.1901 495.3104 495.4307 495.5509 495.6711 495.7914 495.9115 496.0317 496.1519 496.2720 496.3921 496.5122 496.6323 496.7524 496.8725 496.9925 497.1125 497.2325 497.3525 497.4725 497.5924 497.7123 497.8323 497.9522 498.0720 498.1919 498.3117 498.4316 498.5514 498.6712 498.7910 498.9107 499.0305 499.1502 499.2699 499.3896 499.5092 499.6289 499.7485 499.8682 499.9878 500.1073 500.2269 500.3464 500.4660 500.5855 500.7050 500.8245 500.9439 501.0634 501.1828 501.3022 501.4216 501.5410 501.6603 501.7797 501.8990 502.0183 502.1376 502.2568 502.3761 502.4953 502.6145 502.7337 502.8529 502.9721 503.0912 503.2104 503.3295 503.4486 503.5676 503.6867 503.8057 503.9248 504.0438 504.1628 504.2817 504.4007 504.5196 504.6385 504.7574 504.8763 504.9952 505.1140 505.2328 505.3517 505.4705 505.5892 505.7080 505.8267 505.9454 506.0642 506.1828 506.3015 506.4202 506.5388 506.6574 506.7760 506.8946 507.0132 507.1317 507.2502 507.3688 507.4873 507.6057 507.7242 507.8426 507.9611 508.0795 508.1978 508.3162 508.4346 508.5529 508.6712 508.7895 508.9078 509.0261 509.1443 509.2626 509.3808 509.4990 509.6171 509.7353 509.8535 509.9716 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20161118T063728.0Z 6166.276019 2 1 32.01 2 89.92 131.98 66.76 264.84 0.00 1 0.00 1 0 81 1.502e-01 1.316e-01 1.306e-01 1.241e-01 -3.215341e+03 7.088916e+03 5.107120e+02 -6.000000e+00 7.895137e+03 264.75 -2.00 20.00 -2.00 505.20 0.00e+00 6.927253e-03 3.336671e-03 4.018415e-04 -6.000000e+00 4.081325e-03 264.75 -2.00 20.00 -2.00 499.95 0.00e+00 3.410847e+00 2.588008e+00 7.128677e-02 -6.000000e+00 2.983170e+00 218.57 -2.00 4.26 -2.00 501.59 0.00e+00 20.760 0.233 489.00 513.00 1 1.0861e+00 1.9841e-01 4.5227e-02 -6.0000e+00 2.2780e-01 1.4235e-01 5.0675e-02 2.5557e-03 -6.0000e+00 5.8591e-02 2.5049e-02 -1.3990e-02 1.1148e-02 1.4064e-04 -6.0000e+00 1.4338e-02 3.5352e-02 -7.8624e-05 12 8 8 10 0 0 8.24 17.93 6.95 0.03535 -0.06168 8 2 1 5 0 4000.000 20.77 15.00 17.93 -6775 9457 -15713 2401 -1749 4368 2741 7235 10429 7347 7757 -12018 20249 -13667 14305 -4692 17572 -15690 23456 7155 -2714 -12218 -9144 -4588 10614 777 -4535 13395 -3324 32357 -5230 1216 9657 -946 -8261 9024 -1053 -1497 -4651 -392 -10741 23502 4745 -17360 -619 7452 2642 -230 -7606 -3066 25387 2238 1373 3707 6903 -722 1919 27276 1824 -135 579 835 15366 -13397 6899 2855 -19457 3549 -18185 11173 -1996 37491 9090 12410 11440 18901 9548 -16412 7079 -18464 21368 -5426 2828 -24095 9598 -3051 7338 -10771 -1595 -997 -4095 -12861 -19730 2005 13374 12217 -7031 31538 5336 29987 -31351 33630 -3659 12991 -8051 1153 -26 23412 9497 13141 29601 6200 11645 -11944 17507 -743 10664 3669 52084 -13009 3002 -7989 15422 -15557 24425 -9199 8672 -7550 -5559 32430 2545 8611 -17829 4975 -13360 41339 -20327 -3809 -8195 21313 14396 26438 -3960 3 12325 -18165 39659 -5653 19120 -13685 1115 -7261 8636 -18783 2503 -1945 4673 3036 7769 10879 7831 8084 -14876 18167 -16675 13140 -5140 15602 -19575 20433 7417 -3120 -15287 -11085 -5330 10754 868 -5348 13256 -3800 25531 -5714 1237 9093 -1010 -9845 9254 -1195 -1671 -5297 -424 -12845 20237 4990 -22742 -702 7869 2932 -261 -9090 -3466 21217 2272 1375 3596 6570 -759 2023 22931 1972 -148 630 907 14524 -16790 7089 2995 -24874 3568 -22219 10196 -2029 25802 8244 10981 10342 15928 8663 -18753 6329 -20959 16493 -5402 2622 -28830 8344 -3001 6517 -11435 -1538 -953 -4046 -13873 -23202 1936 11751 10862 -7466 22834 4832 20970 -38564 21824 -3413 10477 -8140 1079 -24 17106 7783 10339 20149 5371 9795 -12919 14466 -739 9593 3519 31328 -14370 2802 -8214 12542 -17013 18345 -9598 7646 -7773 -5607 22731 2374 7576 -19823 4349 -13702 24946 -22433 -3664 -8331 16449 11979 19682 -3935 3 10583 -20897 25980 -5576 14511 -13870 977 SO 20161118T063931.0Z 6166.277442 4 1 32.00 2 89.73 132.43 67.01 265.28 0.00 1 0.00 1 0 15 1.068e-01 1.014e-01 1.173e-01 1.135e-01 5.930696e+03 7.426480e+03 7.519106e+02 -6.000000e+00 5.619376e+03 264.75 -2.00 20.00 -2.00 505.23 0.00e+00 5.688375e-04 2.990655e-03 1.012300e-04 -6.000000e+00 2.903731e-03 264.75 -2.00 20.00 -2.00 499.95 0.00e+00 2.609967e+00 2.356263e+00 4.096869e-02 -6.000000e+00 2.131897e+00 218.57 -2.00 4.26 -2.00 501.59 0.00e+00 20.490 0.224 489.00 513.00 1 1.1683e+00 1.7967e-01 4.2815e-02 -6.0000e+00 1.6272e-01 1.2664e-01 4.6041e-02 2.4384e-03 -6.0000e+00 4.2024e-02 2.7579e-02 -7.3469e-04 1.0331e-02 1.0096e-04 -6.0000e+00 1.0305e-02 1.8711e-02 -2.4524e-04 12 9 8 11 8 0 9.64 17.96 6.97 0.01871 0.01362 8 2 1 5 0 4000.000 20.87 15.08 17.96 9797 14717 6922 11683 16158 1950 -2817 -4386 10068 -17785 -119 2051 16175 11234 23388 4534 77 6977 14432 -7901 15321 7457 -16507 -18888 -3040 5253 8083 1135 1226 -10844 -14683 2249 -14924 11057 -2355 2321 6019 -7148 -2373 -1224 8143 -481 10775 5461 28 4997 947 -6503 3475 -280 8300 7245 3094 -11856 5429 736 -1603 -7176 4513 8311 -3347 -4065 -16007 -967 8550 5496 13028 -645 -9927 -8076 -14239 2655 -2145 -203 -12550 10399 -3987 -5572 20295 -15421 -2335 9013 11389 179 -12295 14208 8065 6405 12930 2673 -9231 1237 3026 3025 -5828 15784 -1094 -5259 -484 7427 -3642 14249 -20736 9937 -6838 10022 -18246 22987 -12966 18820 -4976 82 12079 5775 2263 1392 -4251 1662 47989 985 -10290 -6706 20847 -18264 7566 -8577 16874 13999 -3407 -3475 7966 3807 112 14923 8722 -7225 -24162 2099 -4574 11135 -2949 2958 12381 817 769 5601 3857 -8036 12400 10836 14421 8673 12671 6591 10982 14919 2101 -3245 -5198 10339 -23693 -132 2197 14841 10690 19709 4577 82 7127 14065 -9705 14963 7873 -21976 -25829 -3565 5729 8543 1265 1338 -12926 -17702 2299 -18263 10800 -2720 2592 6435 -8535 -2668 -1346 8197 -525 10700 5732 32 5344 1050 -7677 3653 -299 7900 6766 2953 -13021 5163 757 -1719 -8238 4606 8129 -3667 -4501 -19898 -1043 8332 5443 11757 -657 -10868 -8564 -15853 2504 -2119 -199 -14116 9366 -4044 -5618 15678 -16642 -2226 7711 9572 168 -13204 11917 7220 5773 10959 2484 -9686 1180 2876 2894 -5987 12872 -1020 -4977 -429 5953 -3190 10571 -22066 8187 -6876 8736 -20864 17417 -13664 14508 -4883 77 10281 5274 2148 1337 -4318 1606 29929 952 -10936 -6748 15838 -20194 6559 -8785 13519 11440 -3281 -3349 6892 3398 101 11557 7151 -6945 -27856 1918 -4544 9579 -2928 2787 10755 795 752 5211 3614 -8247 10288 8931 11498 SO 20161118T064131.0Z 6166.278831 6 1 32.00 2 89.55 132.86 67.25 265.70 0.00 1 0.00 1 0 18 1.035e-01 9.511e-02 1.116e-01 1.084e-01 4.110019e+03 6.904823e+03 8.588149e+02 -6.000000e+00 5.446226e+03 264.75 -2.00 20.00 -2.00 505.27 0.00e+00 2.879447e-03 2.877311e-03 1.896769e-04 -6.000000e+00 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