File name: Pandora105s1_Helsinki_20161130_L2Fit_fwvt1c2d20161104p1-8.txt File generation date: 20251122T143821.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20150702.txt Instrument calibration file used: Pandora105s1_CF_v2d20161104.txt Level 1 file used: Pandora105s1_Helsinki_20161130_L1_smca1c2d20161104p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20161130 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1622 1772 Nominal wavelengths inside fitting window [nm]: 492.0569 492.1776 492.2983 492.4190 492.5397 492.6603 492.7810 492.9016 493.0222 493.1428 493.2633 493.3839 493.5044 493.6249 493.7454 493.8659 493.9864 494.1069 494.2273 494.3477 494.4681 494.5885 494.7088 494.8292 494.9495 495.0698 495.1901 495.3104 495.4307 495.5509 495.6711 495.7914 495.9115 496.0317 496.1519 496.2720 496.3921 496.5122 496.6323 496.7524 496.8725 496.9925 497.1125 497.2325 497.3525 497.4725 497.5924 497.7123 497.8323 497.9522 498.0720 498.1919 498.3117 498.4316 498.5514 498.6712 498.7910 498.9107 499.0305 499.1502 499.2699 499.3896 499.5092 499.6289 499.7485 499.8682 499.9878 500.1073 500.2269 500.3464 500.4660 500.5855 500.7050 500.8245 500.9439 501.0634 501.1828 501.3022 501.4216 501.5410 501.6603 501.7797 501.8990 502.0183 502.1376 502.2568 502.3761 502.4953 502.6145 502.7337 502.8529 502.9721 503.0912 503.2104 503.3295 503.4486 503.5676 503.6867 503.8057 503.9248 504.0438 504.1628 504.2817 504.4007 504.5196 504.6385 504.7574 504.8763 504.9952 505.1140 505.2328 505.3517 505.4705 505.5892 505.7080 505.8267 505.9454 506.0642 506.1828 506.3015 506.4202 506.5388 506.6574 506.7760 506.8946 507.0132 507.1317 507.2502 507.3688 507.4873 507.6057 507.7242 507.8426 507.9611 508.0795 508.1978 508.3162 508.4346 508.5529 508.6712 508.7895 508.9078 509.0261 509.1443 509.2626 509.3808 509.4990 509.6171 509.7353 509.8535 509.9716 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20161130T070610.0Z 6178.295949 2 1 32.01 2 89.93 138.34 90.82 128.45 0.00 1 0.00 1 0 32 1.543e-01 1.327e-01 1.515e-01 1.428e-01 -3.403277e+03 8.046164e+03 3.933770e+02 -6.000000e+00 8.081000e+03 263.58 -2.00 20.00 -2.00 505.21 0.00e+00 7.439034e-03 3.801188e-03 2.974162e-04 -6.000000e+00 4.185674e-03 263.58 -2.00 20.00 -2.00 499.76 0.00e+00 5.193514e+00 2.994593e+00 4.127172e-02 -6.000000e+00 3.092438e+00 218.09 -2.00 4.26 -2.00 501.42 0.00e+00 20.804 0.234 489.00 513.00 1 1.0927e+00 2.2827e-01 4.4736e-02 -6.0000e+00 2.3556e-01 1.3055e-01 5.8858e-02 2.4882e-03 -6.0000e+00 6.1413e-02 2.1520e-02 -7.9984e-03 1.2922e-02 1.1828e-04 -6.0000e+00 1.4781e-02 -1.4878e-02 4.4131e-04 12 8 8 10 0 0 68.72 17.71 11.16 -0.01488 -0.07036 8 2 1 5 0 4000.000 20.67 15.18 17.71 -3574 -4514 18182 1674 5449 -11876 -4326 702 -11200 -14200 -3924 -4851 -16105 6179 4721 24043 18336 44647 -20675 22477 -12493 -9045 8019 -6437 1678 11157 50187 6055 15069 -10354 24735 -14695 13239 -3045 3076 7358 8772 6942 19701 -534 -13439 -3636 -10503 -3572 2217 4821 -13553 21907 23060 22280 -2332 14054 -11457 1851 -3441 10065 990 1298 -1046 5220 19741 -10312 5869 -5069 11184 -1244 4554 12087 14056 -19893 10871 2629 -11147 4974 9664 -21844 29515 -15994 -8408 19028 5938 1108 18828 49954 -3001 8090 -18167 -5531 -3222 1213 19167 -2077 6638 -1703 5227 -1843 8760 -2873 16030 -16249 32236 -14040 235 2378 12460 -8110 -15294 10241 -779 4144 6270 9441 -10088 10690 -6482 43989 -70 34600 13410 11000 5229 7111 -9728 -10524 16710 -11705 17812 -7040 1280 -25376 3114 -429 11393 -6445 53181 7141 21530 -12653 -6247 -8524 -3317 -25103 26886 -9292 15360 24996 -7235 -1685 714 -2215 900000 -3776 -4894 16383 1828 5883 -15419 -5297 824 -14758 -18832 -4644 -5702 -20687 6314 4851 20521 16745 32277 -28681 20641 -16132 -11261 8426 -7862 1905 11573 35755 6540 14525 -12323 20519 -17754 12418 -3454 3386 7835 9125 7260 18079 -592 -16839 -4206 -13091 -4213 2499 5323 -17916 20236 20708 19708 -2544 12762 -13109 1859 -3731 9838 1086 1422 -1171 5465 17982 -12637 6138 -5905 10969 -1359 4602 11136 12517 -24275 9680 2527 -12250 4736 8850 -26829 21769 -17908 -8605 14826 5227 1026 14732 28855 -2904 7024 -20302 -5419 -3093 1112 14755 -1988 5942 -1683 4843 -1823 7718 -2790 12637 -16934 20585 -13982 208 2103 10098 -7963 -15824 8111 -676 3449 5211 7796 -10304 9127 -6614 27729 -68 23988 11204 9272 4603 6086 -9758 -10724 13193 -12249 14006 -7047 1179 -30390 2823 -398 9229 -6130 27998 5891 15780 -13129 -6173 -8692 -3222 -30100 19499 -9589 12543 18632 -7217 -1547 627 -1964 900000 SO 20161130T070813.0Z 6178.297373 4 1 32.01 2 89.76 138.78 90.62 128.88 0.00 1 0.00 1 0 45 1.521e-01 1.408e-01 1.415e-01 1.335e-01 2.564753e+03 8.303616e+03 1.056888e+03 -6.000000e+00 7.958890e+03 263.58 -2.00 20.00 -2.00 505.22 0.00e+00 -9.852080e-04 3.611257e-03 6.522222e-05 -6.000000e+00 4.128526e-03 263.58 -2.00 20.00 -2.00 499.64 0.00e+00 3.637010e+00 2.831473e+00 1.173025e-01 -6.000000e+00 3.040879e+00 218.09 -2.00 4.26 -2.00 501.34 0.00e+00 20.567 0.226 489.00 513.00 1 1.2796e+00 2.1782e-01 4.3739e-02 -6.0000e+00 2.3201e-01 1.4467e-01 5.5616e-02 2.5491e-03 -6.0000e+00 6.0085e-02 2.3011e-02 -1.1208e-02 1.2262e-02 9.4704e-05 -6.0000e+00 1.4764e-02 7.7946e-02 -7.7696e-04 12 8 8 10 0 0 -274.96 17.73 5.77 0.07795 0.00020 8 2 1 5 0 4000.000 20.67 14.86 17.73 13243 2376 9853 9296 5881 24312 7933 3641 418 -2200 -18574 2613 -1342 -7593 -5874 -5058 -2954 -21068 -1405 11711 135 18940 23826 7331 -16135 -7684 28521 2718 5474 2935 43203 -21283 -270 -15054 15783 713 -14558 -14362 11355 21499 -15260 4222 2153 19950 8132 1414 10312 15460 -7847 -1376 1068 3979 3578 28632 16669 36861 18931 -1293 460 13748 6278 -24025 -2269 -3056 43028 -11310 -11617 -24478 130 407 -12800 21373 -566 15544 -5459 11406 -2439 12357 -4637 3242 -13552 6263 -24153 18335 15254 15840 -984 -16124 -20703 -2983 42016 2249 16543 7736 13592 21824 12742 -7567 31491 2299 9427 1060 -13142 -24195 10373 18062 -2999 -238 21044 19766 -9553 957 11687 -978 21879 -2797 -10340 -2314 425 -9586 6235 12782 19921 1558 -35478 15057 -14996 18913 27900 -8673 619 -8133 3959 18320 21086 -7822 -10971 18955 -8968 -2378 23490 -6777 33978 -3510 -3352 5931 -6610 14942 -10682 11510 6749 11984 2382 9332 9071 6136 21791 8473 4135 492 -2651 -25847 2924 -1543 -9166 -6885 -5842 -3352 -28873 -1637 12294 160 18755 22451 8082 -22374 -9906 25784 3140 6086 3266 31594 -28311 -294 -19221 15469 830 -19725 -19221 11775 19869 -19836 4538 2370 18668 8570 1605 10717 15144 -9492 -1531 1131 3998 3505 21628 14113 26327 16543 -1403 494 12890 6303 -32044 -2462 -3349 30171 -13316 -13499 -31497 129 400 -14147 16710 -545 12943 -5640 10057 -2457 10526 -4545 2918 -14238 5445 -28192 14297 12350 12874 -947 -17970 -24124 -2926 26697 2101 13526 6998 11641 17040 10679 -7536 21020 1973 7429 891 -12749 -26977 8595 14306 -2937 -224 15878 14893 -9565 872 9715 -934 16885 -2732 -10925 -2269 408 -10052 5554 10560 15075 1392 -45330 11955 -15888 14373 19485 -8578 558 -7988 3406 13520 14930 -7302 -10586 14064 -8866 -2239 17414 -6806 23175 -3449 -3310 5361 -6712 12169 -10908 9261 5623 SO 20161130T071012.0Z 6178.298750 6 1 32.01 2 89.60 139.21 90.44 129.30 0.00 1 0.00 1 0 71 1.164e-01 1.120e-01 1.251e-01 1.207e-01 9.822463e+03 8.174758e+03 5.761280e+02 -6.000000e+00 6.095424e+03 263.58 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