File name: Pandora105s1_Helsinki_20170331_L2Fit_fwvt1c2d20170321p1-8.txt File generation date: 20251122T143920.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20170321.txt Level 1 file used: Pandora105s1_Helsinki_20170331_L1_smca1c2d20170321p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20170331 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1768 Nominal wavelengths inside fitting window [nm]: 492.0703 492.1911 492.3118 492.4326 492.5533 492.6740 492.7947 492.9154 493.0361 493.1567 493.2774 493.3980 493.5186 493.6392 493.7597 493.8803 494.0008 494.1213 494.2418 494.3623 494.4828 494.6032 494.7236 494.8441 494.9644 495.0848 495.2052 495.3255 495.4458 495.5662 495.6864 495.8067 495.9270 496.0472 496.1674 496.2876 496.4078 496.5280 496.6481 496.7683 496.8884 497.0085 497.1286 497.2486 497.3687 497.4887 497.6087 497.7287 497.8487 497.9687 498.0886 498.2085 498.3285 498.4483 498.5682 498.6881 498.8079 498.9277 499.0475 499.1673 499.2871 499.4069 499.5266 499.6463 499.7660 499.8857 500.0054 500.1250 500.2446 500.3642 500.4838 500.6034 500.7230 500.8425 500.9621 501.0816 501.2010 501.3205 501.4400 501.5594 501.6788 501.7982 501.9176 502.0370 502.1563 502.2757 502.3950 502.5143 502.6336 502.7528 502.8721 502.9913 503.1105 503.2297 503.3489 503.4680 503.5872 503.7063 503.8254 503.9445 504.0636 504.1826 504.3017 504.4207 504.5397 504.6587 504.7776 504.8966 505.0155 505.1344 505.2533 505.3722 505.4910 505.6099 505.7287 505.8475 505.9663 506.0851 506.2038 506.3226 506.4413 506.5600 506.6787 506.7973 506.9160 507.0346 507.1532 507.2718 507.3904 507.5089 507.6275 507.7460 507.8645 507.9830 508.1015 508.2199 508.3384 508.4568 508.5752 508.6936 508.8119 508.9303 509.0486 509.1669 509.2852 509.4035 509.5218 509.6400 509.7582 509.8764 509.9946 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170331T035540.0Z 6299.163657 1 1 32.00 2 89.90 81.68 100.26 40.72 0.00 1 0.00 1 0 15 1.388e-01 1.269e-01 1.220e-01 1.160e-01 5.523590e+03 7.552565e+03 5.498253e+02 -6.000000e+00 7.316973e+03 265.03 -2.00 20.00 -2.00 505.17 0.00e+00 1.952775e-03 3.129106e-03 2.096076e-05 -6.000000e+00 3.768693e-03 265.03 -2.00 20.00 -2.00 499.77 0.00e+00 -1.154768e+00 2.483229e+00 3.768795e-02 -6.000000e+00 2.780803e+00 225.94 -2.00 4.26 -2.00 501.46 0.00e+00 20.672 0.230 489.00 513.00 1 1.3917e+00 1.9009e-01 4.3663e-02 -6.0000e+00 2.1214e-01 2.4154e-01 4.8552e-02 2.5531e-03 -6.0000e+00 5.4621e-02 2.7472e-02 -1.0087e-02 1.0745e-02 6.6626e-05 -6.0000e+00 1.3178e-02 -3.6859e-02 2.5578e-04 12 8 8 10 0 0 -1373.22 17.58 11.80 -0.03686 -0.10682 8 2 1 5 0 4000.000 20.56 15.17 17.58 -17571 10999 -14790 -1579 -622 12232 -804 -1394 -6282 10208 -10967 -1166 13830 -1518 15686 -3949 4413 -2965 5456 -5473 -8513 -11305 13904 -3326 -4785 -5440 19931 116 -10395 5577 11113 -2073 -9761 20917 -7951 49 7587 11041 -7913 21685 -3013 13853 3863 -3179 20830 2030 5867 12269 -17288 -20213 -5242 14091 17346 16479 22982 3393 3740 -4083 12192 -11187 744 1882 3760 16676 -13072 -18647 17648 14796 3158 -5634 -10657 26696 5116 13089 2037 26587 8234 11785 -14955 9274 1705 8525 -12662 -6880 25818 -13990 24395 -1609 33110 -630 21273 -16713 24108 273 9735 363 2008 -11765 998 3233 1798 13032 -554 14579 -6130 22982 15947 18894 -1820 30689 -19674 -3782 439 -7803 -9642 14908 -15186 -20862 11300 -21036 15254 -1402 13012 -18859 21798 -5168 32286 -783 34263 -6021 8637 13831 1453 22814 -8328 -9193 -11509 -6563 -5006 12823 -23368 21219 -15403 22153 3657 24493 21775 10373 -7587 -16747 -5955 -21479 10232 -18120 -1753 -703 12516 -946 -1672 -7862 10819 -14001 -1338 13462 -1696 14576 -4409 4599 -3360 5832 -6646 -10607 -14451 13902 -3954 -5750 -6596 18852 132 -12885 5753 10500 -2192 -11259 18440 -9613 55 7973 11063 -9380 19217 -3348 13150 4089 -3620 19022 2233 6202 12047 -22296 -26307 -5763 12490 14557 13876 18438 3391 3803 -4564 11704 -13410 789 1979 3902 15242 -15900 -23689 15457 13120 3108 -5932 -11645 20266 4764 11488 2009 20747 7556 10218 -16534 8050 1594 7477 -13703 -7070 19451 -15729 18930 -1605 23422 -617 16910 -19282 19077 275 8880 354 1893 -12299 895 2790 1547 10010 -493 11693 -6240 17981 13258 15019 -1739 21400 -22385 -3757 423 -8245 -10337 12626 -17317 -25359 10048 -25212 12677 -1337 10653 -20819 16348 -5057 21881 -731 22587 -5877 7259 10910 1272 15964 -7755 -8648 -11246 -6225 -4744 10271 -26869 15921 -16450 16419 3265 17706 15987 8345 -7057 -16620 -5334 SO 20170331T035739.0Z 6299.165035 3 1 32.00 2 89.66 82.11 100.10 41.16 0.00 1 0.00 1 0 39 1.133e-01 1.047e-01 1.027e-01 9.852e-02 1.480899e+04 7.396537e+03 1.051976e+03 -6.000000e+00 5.981335e+03 265.03 -2.00 20.00 -2.00 505.22 0.00e+00 -3.641489e-04 2.641349e-03 8.669319e-05 -6.000000e+00 3.085147e-03 265.03 -2.00 20.00 -2.00 499.70 0.00e+00 4.946752e-01 2.086323e+00 6.777421e-02 -6.000000e+00 2.293668e+00 225.94 -2.00 4.26 -2.00 501.38 0.00e+00 20.305 0.218 489.00 513.00 1 1.1743e+00 1.5871e-01 4.2454e-02 -6.0000e+00 1.7467e-01 1.8350e-01 4.0324e-02 3.0450e-03 -6.0000e+00 4.5597e-02 3.2525e-02 1.4851e-02 8.3071e-03 9.6290e-05 -6.0000e+00 1.0914e-02 3.2401e-03 1.2956e-04 12 8 8 10 0 0 42.82 17.61 3.93 0.00324 0.10625 8 2 1 5 0 4000.000 20.56 14.80 17.61 -5009 4085 -3475 12519 -8201 -673 205 13851 -9077 4770 7564 -4365 -716 -6632 7479 -13267 11562 -9925 22909 -3206 4189 -8712 901 -16980 4287 9249 -465 -35 6177 1464 11213 13593 -186 -4870 -3142 15317 -2209 13643 -11091 15208 -7840 12270 5702 8101 -2781 -3013 -6259 -1310 20021 -10961 -9982 -19093 -2961 -8574 5349 3000 -1859 2326 10942 -488 10394 11851 2599 342 -1428 29363 8066 18063 -14111 19746 -6788 -8796 -11305 36059 -7977 18893 -7987 -603 3636 5194 -1991 -7360 4226 -8830 6825 -16772 18965 7535 20553 -2529 3297 3219 4017 -1066 8254 8733 -7978 3316 -15491 12262 -3951 34464 -2719 2107 -12071 -1596 -72 23070 270 500 21619 -9956 -11192 -7561 16584 -3841 16066 -5016 8735 -20641 999 9448 13792 -12403 10856 -12728 -949 20303 19343 183 -2112 -5539 3900 3307 -2174 10029 -26019 10409 -5864 24823 -16603 8949 -4200 6742 161 5326 -4349 3437 6891 6684 900000 -5442 4188 -3935 12465 -10156 -786 240 14083 -11363 5163 7858 -5036 -786 -7615 7545 -16597 11683 -12642 21407 -3860 4678 -10980 1043 -23397 4808 9821 -533 -39 6292 1533 10683 12940 -209 -5896 -3757 15060 -2553 13287 -13601 14432 -9342 12160 6046 8452 -3236 -3487 -7380 -1444 17519 -12478 -11039 -22629 -3033 -9472 5346 3110 -2036 2436 10546 -523 10033 11313 2718 362 -1515 22676 7539 15098 -15927 15854 -7053 -9421 -12597 25647 -8603 15372 -8256 -571 3283 4619 -1913 -7455 3880 -9283 6192 -19127 15280 6700 16107 -2485 3091 3047 3741 -1015 6885 6975 -7298 2648 -14571 8767 -3385 21167 -2523 1947 -12997 -1541 -67 17241 250 468 16663 -10468 -11793 -7720 13440 -3809 13349 -5123 7731 -23578 903 7794 10897 -12722 8924 -13041 -868 15091 14493 164 -1899 -5031 3225 2761 -1933 8129 -30310 8602 -5733 18329 -18414 7782 -4143 5950 151 4666 -4110 2949 5676 5564 900000 SO 20170331T035934.0Z 6299.166366 5 1 32.00 2 89.42 82.53 99.95 41.59 0.00 1 0.00 1 0 22 9.415e-02 8.834e-02 9.004e-02 8.711e-02 7.681270e+03 6.093272e+03 8.075140e+02 -6.000000e+00 4.967709e+03 265.03 -2.00 20.00 -2.00 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