File name: Pandora105s1_Helsinki_20170504_L2Fit_fwvt1c2d20170321p1-8.txt File generation date: 20251122T145302.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20170321.txt Level 1 file used: Pandora105s1_Helsinki_20170504_L1_smca1c2d20170321p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20170504 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1768 Nominal wavelengths inside fitting window [nm]: 492.0703 492.1911 492.3118 492.4326 492.5533 492.6740 492.7947 492.9154 493.0361 493.1567 493.2774 493.3980 493.5186 493.6392 493.7597 493.8803 494.0008 494.1213 494.2418 494.3623 494.4828 494.6032 494.7236 494.8441 494.9644 495.0848 495.2052 495.3255 495.4458 495.5662 495.6864 495.8067 495.9270 496.0472 496.1674 496.2876 496.4078 496.5280 496.6481 496.7683 496.8884 497.0085 497.1286 497.2486 497.3687 497.4887 497.6087 497.7287 497.8487 497.9687 498.0886 498.2085 498.3285 498.4483 498.5682 498.6881 498.8079 498.9277 499.0475 499.1673 499.2871 499.4069 499.5266 499.6463 499.7660 499.8857 500.0054 500.1250 500.2446 500.3642 500.4838 500.6034 500.7230 500.8425 500.9621 501.0816 501.2010 501.3205 501.4400 501.5594 501.6788 501.7982 501.9176 502.0370 502.1563 502.2757 502.3950 502.5143 502.6336 502.7528 502.8721 502.9913 503.1105 503.2297 503.3489 503.4680 503.5872 503.7063 503.8254 503.9445 504.0636 504.1826 504.3017 504.4207 504.5397 504.6587 504.7776 504.8966 505.0155 505.1344 505.2533 505.3722 505.4910 505.6099 505.7287 505.8475 505.9663 506.0851 506.2038 506.3226 506.4413 506.5600 506.6787 506.7973 506.9160 507.0346 507.1532 507.2718 507.3904 507.5089 507.6275 507.7460 507.8645 507.9830 508.1015 508.2199 508.3384 508.4568 508.5752 508.6936 508.8119 508.9303 509.0486 509.1669 509.2852 509.4035 509.5218 509.6400 509.7582 509.8764 509.9946 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170504T021734.4Z 6333.095537 1 1 32.79 2 89.93 56.49 99.35 314.25 0.00 1 0.00 1 0 22 9.569e-03 9.210e-03 3.499e-04 3.465e-04 1.268567e+04 2.333252e+01 8.562633e+02 -6.000000e+00 5.161955e+02 270.43 -2.00 20.00 -2.00 505.50 0.00e+00 4.714330e-03 9.494994e-06 2.522206e-04 -6.000000e+00 2.637019e-04 270.43 -2.00 20.00 -2.00 501.33 0.00e+00 1.988953e+00 6.780613e-03 1.106640e-01 -6.000000e+00 1.932212e-01 229.99 -2.00 4.26 -2.00 502.79 0.00e+00 20.552 0.226 489.00 513.00 1 -6.4963e+00 5.1535e-04 4.4555e-02 -6.0000e+00 1.4758e-02 -8.1727e-02 1.2861e-04 3.4686e-03 -6.0000e+00 3.8178e-03 5.7351e+01 -4.5553e-03 3.0936e-05 1.4481e-04 -6.0000e+00 9.2746e-04 5.5136e-04 -3.6190e-04 12 9 9 12 4 4 20.02 34.30 4.63 0.00055 -0.03105 157 34 1 5 0 208.870 37.52 14.85 34.30 -3506 -3197 -2021 -1169 -272 362 777 1163 1158 718 350 -141 -641 -944 -1339 -1247 -1082 -291 154 567 694 597 699 808 949 1130 1030 985 -69 -683 -1379 -1625 -1016 -129 673 942 1053 623 455 138 229 150 644 767 1077 1201 1086 939 485 -54 -764 -1444 -2025 -1698 -1217 -408 175 657 722 777 843 1029 1154 1252 1068 913 459 154 -234 -606 -722 -950 -713 -364 -60 -110 -239 -609 -954 -1239 -933 -886 -756 -531 -378 -288 -212 -78 111 91 306 649 869 1141 1319 1413 959 645 -290 -1028 -1724 -1903 -1544 -763 -240 64 -118 -591 -776 -927 -675 -373 177 656 969 1399 1672 1683 1337 915 418 28 62 273 250 477 642 272 206 361 -119 76 -161 -788 -1206 -1051 -1009 -485 1 290 168 237 255 278 529 623 393 -298 -901 -1552 -1607 -2888 -2644 -1703 -1016 -242 329 687 1043 1047 650 314 -125 -567 -829 -1226 -1140 -952 -260 141 529 652 563 661 768 910 1093 1001 956 -67 -650 -1283 -1501 -944 -123 633 908 1016 599 434 131 219 144 625 757 1078 1216 1107 954 491 -54 -754 -1400 -1938 -1614 -1172 -403 178 652 722 778 843 1033 1169 1275 1091 926 461 154 -231 -597 -703 -923 -695 -359 -60 -111 -238 -599 -927 -1199 -899 -856 -735 -520 -373 -287 -213 -78 111 90 303 647 881 1170 1347 1410 932 611 -270 -988 -1644 -1816 -1438 -737 -243 64 -120 -601 -784 -937 -690 -389 187 696 1033 1494 1799 1773 1434 988 448 30 65 294 261 503 682 292 222 389 -129 82 -172 -837 -1282 -1124 -1101 -539 1 320 188 269 292 321 612 721 454 -342 -1021 -1746 -1812 SO 20170504T021912.4Z 6333.096671 3 1 32.71 2 89.76 56.84 99.50 314.61 0.00 1 0.00 1 0 22 8.300e-03 8.013e-03 2.940e-04 2.915e-04 1.241447e+04 1.953950e+01 8.375588e+02 -6.000000e+00 4.477134e+02 270.43 -2.00 20.00 -2.00 505.49 0.00e+00 4.168887e-03 7.957800e-06 2.237608e-04 -6.000000e+00 2.287792e-04 270.43 -2.00 20.00 -2.00 501.27 0.00e+00 1.989200e+00 5.710995e-03 1.070545e-01 -6.000000e+00 1.676276e-01 229.99 -2.00 4.26 -2.00 502.74 0.00e+00 20.321 0.218 489.00 513.00 1 -6.7805e+00 4.3388e-04 4.3431e-02 -6.0000e+00 1.2802e-02 -7.5929e-02 1.0893e-04 3.3790e-03 -6.0000e+00 3.3148e-03 7.9295e+01 -3.6617e-03 2.5993e-05 1.3997e-04 -6.0000e+00 8.0214e-04 -4.1297e-03 -3.8086e-04 12 9 9 12 4 4 21.12 34.38 3.98 -0.00413 -0.02953 208 44 1 5 0 157.280 37.52 15.10 34.38 -2979 -2673 -1661 -865 -138 418 777 1075 1012 620 383 -171 -498 -864 -1153 -1015 -836 -214 187 471 653 554 475 696 835 1015 920 796 -56 -605 -1240 -1431 -891 -14 628 769 912 546 283 84 126 132 428 683 922 971 936 789 467 -110 -684 -1378 -1761 -1518 -1110 -381 165 526 570 679 736 862 1020 1067 937 778 490 185 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-978 -971 -513 49 208 168 226 184 212 514 592 361 -289 -906 -1373 -1540 SO 20170504T022047.4Z 6333.097770 5 1 32.71 2 89.60 57.18 99.63 314.96 0.00 1 0.00 1 0 22 7.359e-03 7.108e-03 2.539e-04 2.519e-04 1.198165e+04 1.686994e+01 8.169124e+02 -6.000000e+00 3.968846e+02 270.43 -2.00 20.00 -2.00 505.48 0.00e+00 3.671921e-03 6.870961e-06 1.987460e-04 -6.000000e+00 2.028508e-04 270.43 -2.00 20.00 -2.00 501.24 0.00e+00 2.010709e+00 4.932512e-03 1.005358e-01 -6.000000e+00 1.486355e-01 229.99 -2.00 4.26 -2.00 502.71 0.00e+00 20.053 0.210 489.00 513.00 1 -7.0081e+00 3.7477e-04 4.2146e-02 -6.0000e+00 1.1351e-02 -7.0862e-02 9.4169e-05 3.2476e-03 -6.0000e+00 2.9405e-03 1.0397e+02 -3.5234e-03 2.2537e-05 1.3223e-04 -6.0000e+00 7.0973e-04 6.6998e-03 -4.6699e-04 12 9 9 12 4 4 22.15 34.48 3.50 0.00670 -0.01774 260 56 1 5 0 125.800 37.76 15.07 34.48 -2633 -2287 -1401 -735 -137 459 648 1068 854 616 382 -124 -499 -802 -997 -909 -722 -166 242 471 626 506 487 665 769 820 827 690 -51 -532 -1091 -1265 -777 59 506 704 717 422 193 73 24 145 381 625 786 875 790 624 410 -126 -647 -1222 -1622 -1363 -974 -427 148 501 448 531 617 710 887 942 845 663 401 195 -177 -520 -607 -760 -648 -229 -170 -115 -288 -467 -830 -939 -726 -665 -547 -264 -244 -176 -50 -52 77 113 294 586 738 829 1049 1052 686 507 -272 -916 -1253 -1528 -1250 -659 -384 -113 -208 -538 -682 -706 -574 -290 114 469 745 1096 1294 1414 1022 800 404 80 175 297 170 440 517 162 238 363 -16 64 18 -616 -845 -798 -771 -489 38 211 102 162 127 214 444 473 292 -209 -641 -1057 -1224 -2213 -1928 -1205 -654 -120 410 590 987 797 574 353 -114 -455 -724 -895 -814 -652 -152 228 453 582 472 456 625 729 784 793 662 -48 -498 -997 -1196 -708 55 490 699 714 418 190 71 23 143 380 605 773 871 790 623 406 -123 -624 -1202 -1570 -1310 -948 -411 146 505 455 540 626 724 912 974 875 682 408 196 -177 -517 -597 -745 -638 -228 -171 -117 -290 -464 -814 -915 -704 -648 -536 -260 -243 -177 -51 -50 78 114 296 592 729 830 1045 1026 677 487 -256 -854 -1155 -1411 -1176 -644 -379 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