File name: Pandora105s1_Helsinki_20170528_L2Fit_fwvt1c2d20170321p1-8.txt File generation date: 20251122T145440.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20170321.txt Level 1 file used: Pandora105s1_Helsinki_20170528_L1_smca1c2d20170321p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20170528 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1768 Nominal wavelengths inside fitting window [nm]: 492.0703 492.1911 492.3118 492.4326 492.5533 492.6740 492.7947 492.9154 493.0361 493.1567 493.2774 493.3980 493.5186 493.6392 493.7597 493.8803 494.0008 494.1213 494.2418 494.3623 494.4828 494.6032 494.7236 494.8441 494.9644 495.0848 495.2052 495.3255 495.4458 495.5662 495.6864 495.8067 495.9270 496.0472 496.1674 496.2876 496.4078 496.5280 496.6481 496.7683 496.8884 497.0085 497.1286 497.2486 497.3687 497.4887 497.6087 497.7287 497.8487 497.9687 498.0886 498.2085 498.3285 498.4483 498.5682 498.6881 498.8079 498.9277 499.0475 499.1673 499.2871 499.4069 499.5266 499.6463 499.7660 499.8857 500.0054 500.1250 500.2446 500.3642 500.4838 500.6034 500.7230 500.8425 500.9621 501.0816 501.2010 501.3205 501.4400 501.5594 501.6788 501.7982 501.9176 502.0370 502.1563 502.2757 502.3950 502.5143 502.6336 502.7528 502.8721 502.9913 503.1105 503.2297 503.3489 503.4680 503.5872 503.7063 503.8254 503.9445 504.0636 504.1826 504.3017 504.4207 504.5397 504.6587 504.7776 504.8966 505.0155 505.1344 505.2533 505.3722 505.4910 505.6099 505.7287 505.8475 505.9663 506.0851 506.2038 506.3226 506.4413 506.5600 506.6787 506.7973 506.9160 507.0346 507.1532 507.2718 507.3904 507.5089 507.6275 507.7460 507.8645 507.9830 508.1015 508.2199 508.3384 508.4568 508.5752 508.6936 508.8119 508.9303 509.0486 509.1669 509.2852 509.4035 509.5218 509.6400 509.7582 509.8764 509.9946 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170528T012449.0Z 6357.058900 1 1 32.00 2 89.93 42.76 100.77 12.19 0.00 1 0.00 1 0 15 7.275e-02 7.128e-02 8.544e-02 8.346e-02 1.257597e+04 6.256305e+03 7.570883e+02 -6.000000e+00 3.991281e+03 274.51 -2.00 20.00 -2.00 505.24 0.00e+00 -1.292287e-03 2.277470e-03 1.243146e-04 -6.000000e+00 2.021591e-03 274.51 -2.00 20.00 -2.00 499.86 0.00e+00 -7.096198e-01 1.759630e+00 9.357238e-02 -6.000000e+00 1.464209e+00 232.64 -2.00 4.26 -2.00 501.54 0.00e+00 20.429 0.222 489.00 513.00 1 1.0634e+00 1.3477e-01 4.3351e-02 -6.0000e+00 1.1199e-01 2.0107e-01 3.4151e-02 3.1334e-03 -6.0000e+00 2.8840e-02 4.0001e-02 -1.9505e-03 7.1510e-03 7.5953e-05 -6.0000e+00 6.9137e-03 3.2239e-02 -2.8265e-04 12 8 8 10 0 0 42.17 18.70 7.32 0.03224 0.01871 8 2 1 5 0 4000.000 21.48 14.96 18.70 -4228 -4089 5522 3161 -5374 -2238 -3269 6676 -9438 3467 8424 7250 -1796 3386 -1189 2541 619 4303 2417 1545 -2261 -6489 -3284 6304 -7959 12771 -3111 12306 -4831 -13304 4510 -13712 -4082 -8304 -6960 2354 1706 -7244 7990 -3011 5046 8970 13682 6632 2656 10131 5138 4734 -4168 9778 -2603 6247 388 -2588 1498 3864 4260 -282 -1511 -3111 3730 -726 221 -1291 -2510 -1225 7621 3957 -5000 8430 6212 24719 1478 -14057 13894 -5233 -14183 -678 -4143 -17190 822 -1474 -3131 8629 -2297 7392 -5252 -2836 13099 1295 6402 11701 -3597 4846 -1649 -215 2243 5261 712 3209 4435 -137 9371 756 -10986 13354 5039 5451 1431 -94 3895 -2120 -2047 -10798 5204 -6889 6558 -749 2299 7314 -1087 2786 1263 -2685 -12591 3073 -7122 13682 -3021 432 3440 -10919 -17734 8212 3461 -14687 541 9375 2677 3647 2343 5947 13628 -7890 -5342 -7604 11055 -6693 12392 13967 -4013 -4383 -4293 5431 3289 -6193 -2548 -3829 7218 -11890 3796 8716 7432 -1987 3509 -1279 2636 663 4558 2680 1739 -2648 -7919 -3878 6777 -9900 12902 -3666 12311 -5608 -16123 4497 -16253 -4511 -9838 -8394 2612 1890 -8657 8091 -3367 5189 8897 13046 6849 2879 10213 5413 4944 -4641 9324 -2706 5819 374 -2572 1464 3807 4286 -300 -1613 -3357 3781 -767 232 -1379 -2694 -1280 7163 3802 -5198 7568 5640 18769 1417 -15865 12100 -5461 -15899 -650 -4053 -19040 761 -1403 -3055 7561 -2258 6725 -5402 -2841 11212 1234 5808 10246 -3684 4555 -1619 -201 1975 4359 603 2605 3527 -116 7452 686 -11743 11447 4691 4982 1343 -89 3594 -2084 -2022 -11634 4766 -7124 5981 -745 2227 6671 -1047 2539 1148 -2512 -13070 2736 -7016 10995 -2835 391 3004 -10763 -18368 6535 2884 -14729 476 7748 2381 3252 2139 5278 11254 -8045 -5308 -7689 9224 -6484 9780 10724 -3674 SO 20170528T012648.0Z 6357.060278 3 1 32.00 2 89.76 43.19 100.72 12.64 0.00 1 0.00 1 0 42 8.036e-02 7.614e-02 7.997e-02 7.813e-02 1.348427e+03 4.612164e+03 2.279838e+02 -6.000000e+00 4.411127e+03 274.51 -2.00 20.00 -2.00 505.20 0.00e+00 3.946440e-03 2.118171e-03 2.097671e-04 -6.000000e+00 2.232576e-03 274.51 -2.00 20.00 -2.00 499.94 0.00e+00 3.929212e+00 1.598527e+00 9.923288e-02 -6.000000e+00 1.621481e+00 232.64 -2.00 4.26 -2.00 501.57 0.00e+00 20.205 0.214 489.00 513.00 1 6.2793e-01 1.2255e-01 4.2502e-02 -6.0000e+00 1.2397e-01 1.1404e-01 3.1291e-02 2.7032e-03 -6.0000e+00 3.1986e-02 4.2791e-02 5.7068e-03 7.1628e-03 9.2181e-05 -6.0000e+00 7.7353e-03 8.3033e-03 -2.6059e-04 12 8 8 10 0 0 6.96 18.72 3.00 0.00830 0.04789 8 2 1 5 0 4000.000 21.48 15.03 18.72 4579 9906 -13879 -6414 16107 1901 -2276 -181 -2443 19511 2099 -3718 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6323 -7111 -7048 3907 2340 -108 2016 -2864 2406 -9455 2344 -362 -8063 5581 -11775 -562 6842 -6732 6015 -4195 -561 11320 3208 11710 -2020 1469 6999 3354 -5857 -11278 -2030 -1821 522 -15232 3417 1806 -5027 12310 2721 -6749 4753 -5102 2063 -1090 89 -2043 9212 5550 -10648 -7324 369 -2308 14544 2268 -4961 -15266 -749 -16204 330 6272 1530 9699 9944 2175 15268 -18654 6213 -20221 7457 -10848 -5767 -1134 11299 8340 8389 -3775 2853 7633 -3771 17093 -5730 4134 42 9332 6574 -1553 1846 6974 8497 -8115 -7 -1895 13145 8642 4698 -1466 3527 -12663 914 -9527 9650 5885 3994 501 4445 -4262 -770 -15560 -2292 SO 20170528T012842.0Z 6357.061597 5 1 32.00 2 89.60 43.60 100.67 13.07 0.00 1 0.00 1 0 28 6.624e-02 6.391e-02 6.576e-02 6.435e-02 1.207496e+04 4.685722e+03 7.785578e+02 -6.000000e+00 3.634636e+03 274.51 -2.00 20.00 -2.00 505.15 0.00e+00 -1.018373e-03 1.744544e-03 6.583206e-05 -6.000000e+00 1.844911e-03 274.51 -2.00 20.00 -2.00 499.84 0.00e+00 -1.268911e+00 1.360208e+00 9.352311e-02 -6.000000e+00 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