File name: Pandora105s1_Helsinki_20170626_L2Fit_fwvt1c2d20170321p1-8.txt File generation date: 20251122T151651.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20170321.txt Level 1 file used: Pandora105s1_Helsinki_20170626_L1_smca1c2d20170321p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20170626 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1768 Nominal wavelengths inside fitting window [nm]: 492.0703 492.1911 492.3118 492.4326 492.5533 492.6740 492.7947 492.9154 493.0361 493.1567 493.2774 493.3980 493.5186 493.6392 493.7597 493.8803 494.0008 494.1213 494.2418 494.3623 494.4828 494.6032 494.7236 494.8441 494.9644 495.0848 495.2052 495.3255 495.4458 495.5662 495.6864 495.8067 495.9270 496.0472 496.1674 496.2876 496.4078 496.5280 496.6481 496.7683 496.8884 497.0085 497.1286 497.2486 497.3687 497.4887 497.6087 497.7287 497.8487 497.9687 498.0886 498.2085 498.3285 498.4483 498.5682 498.6881 498.8079 498.9277 499.0475 499.1673 499.2871 499.4069 499.5266 499.6463 499.7660 499.8857 500.0054 500.1250 500.2446 500.3642 500.4838 500.6034 500.7230 500.8425 500.9621 501.0816 501.2010 501.3205 501.4400 501.5594 501.6788 501.7982 501.9176 502.0370 502.1563 502.2757 502.3950 502.5143 502.6336 502.7528 502.8721 502.9913 503.1105 503.2297 503.3489 503.4680 503.5872 503.7063 503.8254 503.9445 504.0636 504.1826 504.3017 504.4207 504.5397 504.6587 504.7776 504.8966 505.0155 505.1344 505.2533 505.3722 505.4910 505.6099 505.7287 505.8475 505.9663 506.0851 506.2038 506.3226 506.4413 506.5600 506.6787 506.7973 506.9160 507.0346 507.1532 507.2718 507.3904 507.5089 507.6275 507.7460 507.8645 507.9830 508.1015 508.2199 508.3384 508.4568 508.5752 508.6936 508.8119 508.9303 509.0486 509.1669 509.2852 509.4035 509.5218 509.6400 509.7582 509.8764 509.9946 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170626T010805.0Z 6386.047280 1 1 32.00 2 89.94 37.27 102.36 12.41 0.00 1 0.00 1 0 36 8.645e-02 8.229e-02 6.118e-02 5.931e-02 1.172988e+04 4.514854e+03 1.129460e+03 -6.000000e+00 4.816947e+03 278.65 -2.00 20.00 -2.00 505.24 0.00e+00 8.422248e-04 1.635106e-03 4.245189e-05 -6.000000e+00 2.427671e-03 278.65 -2.00 20.00 -2.00 499.75 0.00e+00 2.191827e+00 1.261017e+00 1.755197e-02 -6.000000e+00 1.746458e+00 234.52 -2.00 4.26 -2.00 501.42 0.00e+00 20.310 0.218 489.00 513.00 1 4.7857e-01 9.6511e-02 4.1976e-02 -6.0000e+00 1.3361e-01 1.4660e-01 2.4192e-02 2.4119e-03 -6.0000e+00 3.4640e-02 5.7234e-02 5.5219e-03 5.3134e-03 9.4839e-05 -6.0000e+00 8.2924e-03 4.1833e-02 -7.7566e-04 12 9 8 11 4 0 -36.88 25.66 8.28 0.04183 0.08014 8 2 1 5 0 4000.000 28.51 15.00 25.66 7657 12667 -8400 1021 25 -2024 -6020 -13864 5402 -7562 3664 1821 12739 -13544 -3532 -2517 -5737 -13338 5422 2084 3012 654 5842 -742 436 4281 -38 1133 -1892 10503 -5914 9327 3366 13263 9699 11143 -4180 8887 -10232 -226 9825 -3568 -11872 2522 12628 -6835 -986 -2510 10082 7113 2917 5702 -5647 1123 7772 4786 9654 -7724 -5814 20539 -5083 -1106 -5357 7347 -4646 2273 -7321 1618 -9781 -9212 2885 6688 5088 5399 1769 11303 3302 -721 -2318 -12802 28670 2493 -899 6615 -346 -5096 2574 -1258 6578 -3144 19947 7119 2039 188 3407 3692 9120 2942 -3194 -567 -4580 -7469 7225 13475 -20584 9444 -18456 20029 -8962 24912 3701 -2711 4347 1018 3281 -1348 -10597 6388 4927 1220 -4283 -6754 1282 -5491 -2364 2730 18038 8653 -1523 -14250 11485 118 5318 -2708 17043 -11469 8310 -1099 8818 -3894 -4108 15054 -10398 12638 -7414 -3141 -199 7800 -16163 7527 -7164 7110 11339 -9499 1087 28 -2309 -7282 -18358 5902 -9304 3967 1982 12259 -16594 -3914 -2761 -6527 -16769 5806 2343 3363 747 6334 -862 503 4759 -44 1285 -2147 10270 -6635 8955 3489 12888 10012 11478 -4980 9170 -12521 -250 9789 -4050 -14772 2746 12651 -8283 -1122 -2865 10060 7089 2945 5436 -5916 1099 7270 4762 9384 -8968 -6616 18009 -5696 -1195 -6066 7329 -5189 2335 -8065 1616 -10731 -9911 2736 6080 4729 5067 1729 10100 3115 -692 -2224 -13532 20126 2264 -850 5838 -328 -5122 2403 -1215 5835 -3057 15530 6308 1925 181 3127 3275 7401 2462 -2771 -470 -3904 -6551 5685 10458 -23138 8107 -20787 15266 -8937 17943 3307 -2600 3920 952 3001 -1294 -11165 5797 4564 1164 -4205 -6647 1145 -5231 -2197 2425 13875 7249 -1409 -14852 9300 106 4445 -2424 12489 -11202 6848 -1008 7442 -3782 -4014 12341 -10977 10722 -7642 -3093 -188 6679 -17089 6244 -6906 SO 20170626T011003.0Z 6386.048646 3 1 32.01 2 89.79 37.70 102.31 12.87 0.00 1 0.00 1 0 27 8.404e-02 7.759e-02 5.754e-02 5.606e-02 7.329981e+03 4.026065e+03 2.576260e+02 -6.000000e+00 4.685815e+03 278.65 -2.00 20.00 -2.00 505.26 0.00e+00 2.245830e-03 1.549106e-03 1.208039e-04 -6.000000e+00 2.359596e-03 278.65 -2.00 20.00 -2.00 499.92 0.00e+00 4.193400e+00 1.185218e+00 1.095787e-01 -6.000000e+00 1.703523e+00 234.52 -2.00 4.26 -2.00 501.57 0.00e+00 20.120 0.212 489.00 513.00 1 2.8649e-01 9.0960e-02 4.2139e-02 -6.0000e+00 1.3017e-01 9.3062e-02 2.2852e-02 2.9946e-03 -6.0000e+00 3.3952e-02 6.0724e-02 3.6934e-03 5.0466e-03 4.4230e-05 -6.0000e+00 8.0622e-03 5.6873e-03 -5.8606e-04 12 9 8 11 4 0 99.58 25.67 4.77 0.00569 0.03131 8 2 1 5 0 4000.000 28.51 14.99 25.67 900000 434 1036 -8430 -4686 15035 -9297 2277 7635 -3798 -3415 6594 927 -2098 -127 -8342 13478 -74 -3839 4292 -9910 -599 4219 -2161 3210 9683 -3237 -3950 -1051 -4580 4108 -2366 13405 -3336 -5132 -3505 3788 -9332 5960 10852 -2156 2070 3660 5447 581 11254 12432 8886 -12081 11886 -2514 3984 -4219 1988 -7344 2375 -4963 23835 1300 3004 -2768 14799 3240 -6283 -7444 2084 -9145 -9183 810 -4087 14726 8256 8291 -5108 2179 -26 14 -10756 -1291 -14498 -1812 8681 -3931 -2509 6906 -438 -6555 21678 7158 3241 6097 8794 -6581 -2860 -3816 -4833 -1998 5459 3363 2774 762 -3615 897 -9673 -3098 -4204 4976 1539 -2778 -1755 4462 -10291 12601 -9254 24769 638 26624 1777 8608 8122 -1265 -2907 1749 23762 -10086 1765 663 -8802 3040 -9554 6510 701 -1996 6139 21707 -11915 -3436 -914 -12251 16946 -1373 -2851 6618 16078 -13861 11558 -9211 -3822 -4908 -2359 12508 900000 426 1031 -9562 -5270 14182 -11314 2523 8041 -4408 -3888 6756 984 -2265 -133 -9490 12556 -80 -4399 4653 -12333 -679 4559 -2498 3538 10042 -3814 -4659 -1183 -5171 4129 -2520 12359 -3727 -6048 -4132 4132 -11461 6205 10735 -2402 2221 3903 5770 653 11442 12460 9131 -14956 11426 -2692 3912 -4367 1927 -7954 2409 -5567 20492 1390 3143 -3033 13743 3366 -7185 -8565 2149 -10361 -10231 806 -4211 12491 7359 7416 -5283 2121 -25 14 -11377 -1230 -15503 -1715 7418 -3798 -2401 6064 -418 -6614 16570 6288 2947 5390 7628 -6702 -2829 -3782 -4729 -1848 4558 2794 2267 625 -3102 752 -9329 -2914 -4083 4405 1391 -2585 -1612 3896 -10510 10462 -9573 18467 604 19705 1691 7687 7240 -1218 -2795 1582 17358 -10260 1607 612 -8936 2739 -9770 5670 641 -1846 5165 15664 -11933 -3222 -856 -13072 13795 -1348 -2863 6080 13518 -15674 10210 -9858 -3803 -4825 -2227 10270 SO 20170626T011158.0Z 6386.049977 5 1 32.01 2 89.64 38.11 102.26 13.31 0.00 1 0.00 1 0 32 8.563e-02 8.265e-02 5.603e-02 5.485e-02 4.944257e+03 3.748959e+03 5.507968e+02 -6.000000e+00 4.780758e+03 278.65 -2.00 20.00 -2.00 505.32 0.00e+00 5.809783e-03 1.517859e-03 2.680329e-04 -6.000000e+00 2.403475e-03 278.65 -2.00 20.00 -2.00 500.14 0.00e+00 3.565901e+00 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