File name: Pandora105s1_Helsinki_20170714_L2Fit_fwvt1c2d20170321p1-8.txt File generation date: 20251122T151559.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20170321.txt Level 1 file used: Pandora105s1_Helsinki_20170714_L1_smca1c2d20170321p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20170714 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1768 Nominal wavelengths inside fitting window [nm]: 492.0703 492.1911 492.3118 492.4326 492.5533 492.6740 492.7947 492.9154 493.0361 493.1567 493.2774 493.3980 493.5186 493.6392 493.7597 493.8803 494.0008 494.1213 494.2418 494.3623 494.4828 494.6032 494.7236 494.8441 494.9644 495.0848 495.2052 495.3255 495.4458 495.5662 495.6864 495.8067 495.9270 496.0472 496.1674 496.2876 496.4078 496.5280 496.6481 496.7683 496.8884 497.0085 497.1286 497.2486 497.3687 497.4887 497.6087 497.7287 497.8487 497.9687 498.0886 498.2085 498.3285 498.4483 498.5682 498.6881 498.8079 498.9277 499.0475 499.1673 499.2871 499.4069 499.5266 499.6463 499.7660 499.8857 500.0054 500.1250 500.2446 500.3642 500.4838 500.6034 500.7230 500.8425 500.9621 501.0816 501.2010 501.3205 501.4400 501.5594 501.6788 501.7982 501.9176 502.0370 502.1563 502.2757 502.3950 502.5143 502.6336 502.7528 502.8721 502.9913 503.1105 503.2297 503.3489 503.4680 503.5872 503.7063 503.8254 503.9445 504.0636 504.1826 504.3017 504.4207 504.5397 504.6587 504.7776 504.8966 505.0155 505.1344 505.2533 505.3722 505.4910 505.6099 505.7287 505.8475 505.9663 506.0851 506.2038 506.3226 506.4413 506.5600 506.6787 506.7973 506.9160 507.0346 507.1532 507.2718 507.3904 507.5089 507.6275 507.7460 507.8645 507.9830 508.1015 508.2199 508.3384 508.4568 508.5752 508.6936 508.8119 508.9303 509.0486 509.1669 509.2852 509.4035 509.5218 509.6400 509.7582 509.8764 509.9946 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170714T013112.0Z 6404.063333 1 1 32.01 2 89.93 42.20 68.25 169.50 0.00 1 0.00 1 0 26 1.970e-01 1.706e-01 1.579e-01 1.444e-01 3.078443e+03 9.933881e+03 8.687619e+02 -6.000000e+00 1.106151e+04 280.42 -2.00 20.00 -2.00 505.16 0.00e+00 2.248777e-05 4.022059e-03 1.994013e-04 -6.000000e+00 5.564387e-03 280.42 -2.00 20.00 -2.00 499.48 0.00e+00 2.250433e+00 3.110941e+00 2.750309e-01 -6.000000e+00 4.001294e+00 234.82 -2.00 4.26 -2.00 501.20 0.00e+00 20.248 0.216 489.00 513.00 1 1.4158e+00 2.3925e-01 4.6525e-02 -6.0000e+00 3.0595e-01 1.8120e-01 6.0720e-02 4.2057e-03 -6.0000e+00 7.9888e-02 2.2392e-02 1.2615e-02 1.3105e-02 1.2961e-04 -6.0000e+00 1.8907e-02 2.4749e-02 -1.1250e-04 12 8 8 10 0 0 -253.42 22.87 6.40 0.02475 0.11225 8 2 1 5 0 4000.000 25.79 14.93 22.87 2208 -6756 1569 8540 26766 7821 -5893 7932 -10346 -15588 2381 1245 1565 5605 -10064 -5023 -18376 -2590 27099 -14015 10443 -4170 -42 -20384 5733 16328 2599 21576 -25246 6650 19297 4254 10385 3340 9770 -7013 11850 -12473 4593 19966 -3421 33761 -3075 -7158 15482 20950 2331 26859 11665 51768 -1452 -14202 53015 17944 -727 -32159 41240 2909 -2206 2120 -3551 9011 16954 15013 26063 7600 -7400 11375 4285 -6696 -7598 -7313 -21139 10942 -2205 -28056 15044 8649 -6627 17836 -10433 1449 9363 29276 10145 11579 11538 250 -6275 -15944 2667 -30991 21516 -24888 8846 26148 15489 -16140 17533 16769 7601 3756 33722 1264 28604 -5359 -1704 24376 2672 29686 -16458 57845 3266 22853 13026 -4590 34557 13766 -2855 29003 60578 931 17551 -24087 32393 -37875 -2759 -7186 -277 6453 46029 -31132 28321 -16056 -2583 34142 26672 -17859 -830 -9672 25083 23718 -15564 -12672 42183 -12873 -10530 28474 24781 8956 900000 2298 -7864 1738 9045 24289 8661 -7506 8868 -13614 -21277 2701 1408 1726 5936 -12372 -5946 -25261 -3148 25025 -19234 11299 -5177 -50 -29693 6484 16673 2991 20239 -35962 6822 17402 4501 10698 3809 10551 -8803 12249 -16088 4981 18506 -3987 27800 -3634 -8886 15481 19710 2586 23088 11301 33121 -1511 -16339 31935 15571 -771 -47481 30236 3071 -2437 2236 -3976 8927 15500 13879 21412 7313 -8077 10243 4084 -6974 -7957 -7692 -25667 9903 -2249 -36083 12500 7491 -6648 14128 -10938 1356 8152 21251 8925 10069 10020 240 -6435 -17927 2534 -41153 17393 -30958 7819 19155 12213 -16890 12919 12299 6156 3248 22679 1195 20916 -5362 -1614 17825 2406 20807 -18147 31699 3041 17700 11076 -4643 24107 11689 -2803 20653 31413 847 13545 -27928 21912 -50084 -2600 -7056 -254 5508 26519 -36930 18695 -16169 -2292 21744 18697 -19391 -775 -9854 18410 17720 -17051 -13526 26333 -13532 -10558 19149 17074 7205 900000 SO 20170714T013311.0Z 6404.064711 3 1 32.01 2 89.76 42.63 68.20 170.01 0.00 1 0.00 1 0 49 1.910e-01 1.557e-01 1.433e-01 1.304e-01 4.084298e+04 1.238840e+04 1.143972e+03 -6.000000e+00 1.072557e+04 280.42 -2.00 20.00 -2.00 505.11 0.00e+00 -5.913478e-03 3.508939e-03 2.022642e-04 -6.000000e+00 5.392227e-03 280.42 -2.00 20.00 -2.00 499.72 0.00e+00 -6.653425e+00 2.779654e+00 3.406249e-01 -6.000000e+00 3.857439e+00 234.82 -2.00 4.26 -2.00 501.33 0.00e+00 20.033 0.209 489.00 513.00 1 2.0252e+00 2.0975e-01 4.8933e-02 -6.0000e+00 2.9552e-01 2.8664e-01 5.4421e-02 6.5367e-03 -6.0000e+00 7.6321e-02 2.4959e-02 -1.8012e-02 8.3633e-03 8.3156e-05 -6.0000e+00 1.8534e-02 1.4589e-02 -4.5967e-04 12 8 8 10 0 0 -170.73 22.92 6.41 0.01459 -0.11035 8 2 1 5 0 4000.000 25.79 15.06 22.92 25029 -16069 15052 -1462 4520 12950 27 -8381 10360 5026 27121 5531 -2097 -15262 20281 -5784 12239 31432 -18612 3817 -9410 12731 -15865 7818 1905 -1975 -4608 3725 6383 5754 26916 17255 -169 -9704 -4734 -1158 2519 15857 -14913 -12700 4686 26097 11108 -4519 8693 -3662 -2997 6909 10692 26234 14506 -20216 -8263 4300 24318 -2222 -3712 -3814 -6696 -7248 -16486 20680 -29724 -8056 -8113 -11719 -14333 39181 8807 3459 6510 -9962 8542 -1590 8498 17145 25793 40798 5028 1718 -7850 5283 37691 -18756 29532 -2893 3358 5680 10394 -25764 21963 -11405 17198 31311 -23676 22862 -24720 1695 11678 45595 -8185 13009 579 29944 -271 -5753 -17375 -293 4911 -15742 7842 -6989 16698 6421 39209 -20801 12764 17850 31949 -6788 17296 22923 813 -16110 1228 1012 -22959 24873 -18028 93263 -1763 -3066 33946 28978 1027 45782 22572 20597 2236 -18474 15336 -9887 28421 5469 7406 -13303 25072 -25758 215 8504 41234 20732 -19349 13478 -1571 4721 12754 31 -10522 11030 5667 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-6.000000e+00 1.065833e+04 280.42 -2.00 20.00 -2.00 505.20 0.00e+00 2.146383e-03 3.356220e-03 1.172736e-04 -6.000000e+00 5.349887e-03 280.42 -2.00 20.00 -2.00 499.68 0.00e+00 1.860322e+00 2.590075e+00 4.860311e-02 -6.000000e+00 3.844256e+00 234.82 -2.00 4.26 -2.00 501.36 0.00e+00 19.784 0.201 489.00 513.00 1 1.2812e+00 1.9934e-01 4.0002e-02 -6.0000e+00 2.9393e-01 1.7016e-01 5.0414e-02 2.2112e-03 -6.0000e+00 7.6558e-02 2.7285e-02 1.4184e-02 1.1079e-02 7.4729e-05 -6.0000e+00 1.8236e-02 2.5723e-02 2.8835e-05 12 9 8 11 8 0 -17.84 22.96 10.80 0.02572 0.12411 8 2 1 5 0 4000.000 25.90 14.94 22.96 3651 16009 -10303 14678 -12305 47612 -4509 -1450 -1863 -12396 18675 15935 -142 5452 -6651 -5884 -2679 -13723 28009 -17276 4587 8251 -5511 -5735 10268 -5443 11420 16687 -3049 22452 -10010 55034 -11026 8611 -11671 -2034 15183 19076 -23575 145 -11256 27521 -921 1277 7239 13009 -6355 -5614 -1865 -2441 20173 2308 17395 28693 16060 -12228 -2117 12712 10973 -12283 11011 -3282 -3065 15628 -20862 6792 -13202 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