File name: Pandora105s1_Helsinki_20170720_L2Fit_fwvt1c2d20170321p1-8.txt File generation date: 20251122T151545.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20170321.txt Level 1 file used: Pandora105s1_Helsinki_20170720_L1_smca1c2d20170321p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20170720 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1768 Nominal wavelengths inside fitting window [nm]: 492.0703 492.1911 492.3118 492.4326 492.5533 492.6740 492.7947 492.9154 493.0361 493.1567 493.2774 493.3980 493.5186 493.6392 493.7597 493.8803 494.0008 494.1213 494.2418 494.3623 494.4828 494.6032 494.7236 494.8441 494.9644 495.0848 495.2052 495.3255 495.4458 495.5662 495.6864 495.8067 495.9270 496.0472 496.1674 496.2876 496.4078 496.5280 496.6481 496.7683 496.8884 497.0085 497.1286 497.2486 497.3687 497.4887 497.6087 497.7287 497.8487 497.9687 498.0886 498.2085 498.3285 498.4483 498.5682 498.6881 498.8079 498.9277 499.0475 499.1673 499.2871 499.4069 499.5266 499.6463 499.7660 499.8857 500.0054 500.1250 500.2446 500.3642 500.4838 500.6034 500.7230 500.8425 500.9621 501.0816 501.2010 501.3205 501.4400 501.5594 501.6788 501.7982 501.9176 502.0370 502.1563 502.2757 502.3950 502.5143 502.6336 502.7528 502.8721 502.9913 503.1105 503.2297 503.3489 503.4680 503.5872 503.7063 503.8254 503.9445 504.0636 504.1826 504.3017 504.4207 504.5397 504.6587 504.7776 504.8966 505.0155 505.1344 505.2533 505.3722 505.4910 505.6099 505.7287 505.8475 505.9663 506.0851 506.2038 506.3226 506.4413 506.5600 506.6787 506.7973 506.9160 507.0346 507.1532 507.2718 507.3904 507.5089 507.6275 507.7460 507.8645 507.9830 508.1015 508.2199 508.3384 508.4568 508.5752 508.6936 508.8119 508.9303 509.0486 509.1669 509.2852 509.4035 509.5218 509.6400 509.7582 509.8764 509.9946 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170720T014243.0Z 6410.071331 1 1 32.01 2 89.94 44.97 71.98 88.44 0.00 1 0.00 1 0 105 1.569e-01 1.445e-01 1.041e-01 9.839e-02 8.965874e+02 5.949355e+03 2.031096e+02 -6.000000e+00 8.813623e+03 280.51 -2.00 20.00 -2.00 505.28 0.00e+00 3.975547e-04 2.719300e-03 2.077575e-04 -6.000000e+00 4.433542e-03 280.51 -2.00 20.00 -2.00 499.96 0.00e+00 5.827737e+00 1.996749e+00 1.942711e-01 -6.000000e+00 3.195933e+00 234.59 -2.00 4.26 -2.00 501.61 0.00e+00 20.255 0.216 489.00 513.00 1 7.5156e-01 1.5323e-01 4.4531e-02 -6.0000e+00 2.4419e-01 5.2824e-02 3.8541e-02 3.9669e-03 -6.0000e+00 6.4075e-02 3.3689e-02 3.1912e-02 8.8947e-03 5.1035e-05 -6.0000e+00 1.4993e-02 5.3039e-02 -1.2649e-03 12 9 8 11 4 0 -44.50 28.11 10.53 0.05304 0.27440 8 2 1 5 0 4000.000 30.99 14.97 28.11 900000 -4152 -3765 -26910 11781 23953 -5223 67 9455 19079 2847 6660 -14710 3819 -16095 18893 -8088 -2869 -22 -3716 14133 6644 6330 20757 3415 7299 7491 12169 2486 18496 27817 -8742 3776 -25371 -4389 5589 43 -2814 29174 -12719 7381 9149 5419 -957 -9747 -4025 -16333 20566 -12300 7100 9651 2872 2318 2496 -17611 2647 -11317 -539 2383 21028 21042 11608 -16840 -2835 13543 -7577 10786 -5876 -940 -1302 33362 12279 -6016 548 33333 -23320 3751 5630 35859 7975 -4668 1474 -5562 14415 17495 16062 10348 48827 -2035 8794 4512 -6444 5811 -3616 -19057 1237 -14044 -3262 14640 418 7566 6244 32130 17623 14003 -14510 34217 -24424 36414 8518 -39547 -5918 11442 -17478 4464 10681 -5777 20463 527 -5652 -16671 17587 4222 35525 11136 12413 4208 4328 -4900 23671 -2712 -16029 34739 -13556 4540 -880 40294 7617 19944 22259 1544 15080 1014 -13927 20115 -12556 -23691 6642 12370 -7351 -4959 900000 -4357 -4078 -37446 11468 21063 -6180 76 9662 17465 3006 6684 -17923 3872 -19797 16880 -9556 -3310 -25 -4410 14151 7122 6834 19670 3827 7847 7978 12116 2640 16449 22490 -10206 4030 -37167 -5319 6084 49 -3248 24410 -15881 7629 9372 5821 -1098 -12244 -4751 -21366 18582 -14966 6909 8956 2775 2250 2471 -21817 2767 -13646 -583 2487 18292 18352 11076 -21179 -3101 12382 -8334 9788 -6217 -933 -1280 23246 10542 -6231 538 23884 -28255 3417 4956 23543 6865 -4548 1358 -5527 11827 14041 13118 8939 28866 -1970 7662 4142 -6699 5391 -3670 -22073 1157 -14851 -3020 11160 362 6127 5246 21801 14153 11685 -15831 22886 -28521 23465 7290 -54891 -6012 9893 -20193 4195 9493 -6038 16543 511 -5739 -18644 13961 3816 24050 9532 10509 3867 3971 -4907 18099 -2637 -17538 22908 -14189 3995 -835 26366 6942 16299 17950 1530 13235 1026 -16347 17075 -14426 -29806 6070 10529 -7596 -5093 SO 20170720T014429.0Z 6410.072558 3 1 32.00 2 89.78 45.35 71.76 88.80 0.00 1 0.00 1 0 53 1.584e-01 1.436e-01 9.362e-02 8.830e-02 3.655931e+04 8.011603e+03 2.283491e+03 -6.000000e+00 8.903684e+03 280.51 -2.00 20.00 -2.00 505.25 0.00e+00 1.087574e-03 2.447252e-03 1.285658e-04 -6.000000e+00 4.478929e-03 280.51 -2.00 20.00 -2.00 499.89 0.00e+00 -4.169260e+00 1.874969e+00 1.969772e-01 -6.000000e+00 3.229921e+00 234.59 -2.00 4.26 -2.00 501.52 0.00e+00 20.057 0.210 489.00 513.00 1 1.3402e+00 1.4272e-01 4.4345e-02 -6.0000e+00 2.4677e-01 2.2674e-01 3.6027e-02 5.4527e-03 -6.0000e+00 6.4767e-02 3.7619e-02 6.6879e-03 6.4792e-03 1.3908e-04 -6.0000e+00 1.5272e-02 -2.4033e-02 -8.3424e-04 12 9 8 11 12 0 -266.32 28.13 7.62 -0.02403 0.02236 8 2 1 5 0 4000.000 31.10 15.00 28.13 900000 3499 8632 -8684 4187 -3954 7933 -15228 12079 -17703 -12316 7345 -8162 -3985 22265 18129 -4943 21626 -15062 3807 -7873 9595 27354 14569 12857 24390 -10672 -19224 2318 -9753 133 20751 18240 26324 -2196 -3460 36918 -21145 2201 -10449 3241 -13499 6925 6776 17909 -3013 6803 9429 12809 12774 -17367 9642 12605 -7081 -23081 4871 2507 33681 -7469 21563 -59 17716 -10430 2521 1122 11864 12737 10126 8264 -14397 -8463 -23123 29167 -16249 10023 -3237 39306 -7480 8137 -10025 25048 -1788 24123 -11286 50179 14640 717 4179 13172 18177 28513 -4978 -15436 3062 -17539 6011 -3302 21947 -2474 9610 -10992 6155 1530 5642 5413 13164 -15833 -9908 21078 30617 2222 -21012 -6824 -4508 3122 10681 41109 -17930 458 8149 1149 19631 25092 -408 10029 -24661 -16952 5748 7665 11585 9781 -2571 -16291 22220 28538 29679 -15849 13130 -9341 -1175 12330 -4179 -13189 -12981 11661 28123 -4901 -9126 3780 -11718 20470 900000 3406 8160 -10014 4376 -4582 8313 -20267 12405 -24149 -15676 7620 -9671 -4460 19076 16088 -5505 18921 -19214 4145 -9627 9922 23646 14318 12903 21894 -13476 -26099 2523 -11645 139 17507 15881 21699 -2460 -4023 29205 -28869 2369 -12620 3393 -16605 7057 6993 16738 -3476 7183 9635 12495 12252 -21798 9044 11206 -7533 -28930 4800 2613 26477 -8785 19092 -64 16296 -12709 2714 1225 11537 12095 9711 7975 -17121 -9378 -29453 22434 -19616 9524 -3515 28081 -8223 7547 -10908 19167 -1771 18653 -12358 30863 12870 727 4084 11711 15121 21176 -5142 -17765 2960 -20197 5228 -2952 14503 -2002 6837 -9444 4493 1194 4494 4672 11232 -18435 -10950 17047 22484 2161 -25693 -7324 -4689 2967 9310 26904 -21184 464 7808 1159 16064 18846 -379 8402 -28983 -18555 5062 6611 9638 8184 -2405 -16975 15740 18953 19691 -16636 10587 -9463 -1108 10327 -4168 -14564 -14343 10096 20608 -4873 -9347 3352 -11971 15204 SO 20170720T014612.0Z 6410.073750 5 1 32.01 2 89.63 45.72 71.55 89.16 0.00 1 0.00 1 0 15 1.517e-01 1.294e-01 8.317e-02 7.860e-02 -1.131025e+03 5.023796e+03 3.173976e+02 -6.000000e+00 8.529978e+03 280.51 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