File name: Pandora105s1_Helsinki_20170819_L2Fit_fwvt1c2d20170321p1-8.txt File generation date: 20251122T153834.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20170321.txt Level 1 file used: Pandora105s1_Helsinki_20170819_L1_smca1c2d20170321p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20170819 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1768 Nominal wavelengths inside fitting window [nm]: 492.0703 492.1911 492.3118 492.4326 492.5533 492.6740 492.7947 492.9154 493.0361 493.1567 493.2774 493.3980 493.5186 493.6392 493.7597 493.8803 494.0008 494.1213 494.2418 494.3623 494.4828 494.6032 494.7236 494.8441 494.9644 495.0848 495.2052 495.3255 495.4458 495.5662 495.6864 495.8067 495.9270 496.0472 496.1674 496.2876 496.4078 496.5280 496.6481 496.7683 496.8884 497.0085 497.1286 497.2486 497.3687 497.4887 497.6087 497.7287 497.8487 497.9687 498.0886 498.2085 498.3285 498.4483 498.5682 498.6881 498.8079 498.9277 499.0475 499.1673 499.2871 499.4069 499.5266 499.6463 499.7660 499.8857 500.0054 500.1250 500.2446 500.3642 500.4838 500.6034 500.7230 500.8425 500.9621 501.0816 501.2010 501.3205 501.4400 501.5594 501.6788 501.7982 501.9176 502.0370 502.1563 502.2757 502.3950 502.5143 502.6336 502.7528 502.8721 502.9913 503.1105 503.2297 503.3489 503.4680 503.5872 503.7063 503.8254 503.9445 504.0636 504.1826 504.3017 504.4207 504.5397 504.6587 504.7776 504.8966 505.0155 505.1344 505.2533 505.3722 505.4910 505.6099 505.7287 505.8475 505.9663 506.0851 506.2038 506.3226 506.4413 506.5600 506.6787 506.7973 506.9160 507.0346 507.1532 507.2718 507.3904 507.5089 507.6275 507.7460 507.8645 507.9830 508.1015 508.2199 508.3384 508.4568 508.5752 508.6936 508.8119 508.9303 509.0486 509.1669 509.2852 509.4035 509.5218 509.6400 509.7582 509.8764 509.9946 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170819T025136.0Z 6440.119167 1 1 32.00 2 89.92 63.82 67.96 91.80 0.00 1 0.00 1 0 29 1.313e-01 1.257e-01 7.602e-02 7.278e-02 1.444535e+04 5.499815e+03 8.814523e+02 -6.000000e+00 7.340337e+03 279.41 -2.00 20.00 -2.00 505.11 0.00e+00 -1.639177e-03 1.978984e-03 7.823905e-05 -6.000000e+00 3.697827e-03 279.41 -2.00 20.00 -2.00 499.83 0.00e+00 -1.533932e+00 1.508386e+00 1.119610e-01 -6.000000e+00 2.642900e+00 232.34 -2.00 4.26 -2.00 501.45 0.00e+00 20.285 0.217 489.00 513.00 1 1.0010e+00 1.1468e-01 4.2886e-02 -6.0000e+00 2.0245e-01 2.1542e-01 2.9467e-02 3.3499e-03 -6.0000e+00 5.2250e-02 4.5831e-02 5.0411e-03 6.1963e-03 1.1264e-04 -6.0000e+00 1.2674e-02 -1.0190e-01 2.7818e-04 12 9 9 12 4 4 87.23 30.69 14.59 -0.10190 -0.06693 8 2 1 5 0 4000.000 33.62 15.01 30.69 -9745 22768 2101 21912 -3416 17013 4565 6568 17609 -3302 -21857 -2217 -6946 11400 -12527 4376 27449 -451 -134 -9648 -11456 8127 7765 13537 10316 -5509 -10232 1853 2630 8836 17498 2526 13122 -9318 9245 12714 3906 -11897 22626 -12878 10502 16143 13522 -3100 -3560 -1006 -1477 -26591 -6901 16337 14976 1172 -5458 5461 -11155 -13135 17690 -5469 20339 -15115 -2376 5067 -2983 9159 -3692 -7566 23101 -3787 -21806 -4447 7641 2319 1854 29463 23934 -6381 -771 6663 14437 13658 -4275 131 8548 -4660 -12314 -16582 6906 10539 9083 -15751 5719 3641 -11420 -3420 -5112 -3834 -5955 15169 -2733 11671 -2087 -21916 11212 10910 -22323 14338 5459 -13819 3376 13933 -16593 -12154 12618 16117 16387 44494 5080 3436 -1444 23573 13370 30065 17304 6412 -9527 -9555 -9092 -1419 -166 17988 13442 8196 8493 10149 -27033 -1020 -444 -311 6499 16376 1058 25334 12075 -372 4997 10616 2119 2964 -11850 -26307 15217 -10853 18708 2170 19177 -3916 16342 5016 7156 17326 -3928 -30587 -2536 -8146 11066 -15189 4519 22980 -503 -153 -12309 -14792 8685 8321 13712 10822 -6711 -13001 2084 2870 8762 15510 2595 12340 -11266 9585 12869 4281 -14951 20185 -15950 10337 15060 13047 -3535 -4115 -1136 -1666 -37782 -7981 14746 13304 1152 -5629 5057 -12391 -15373 15721 -6146 17776 -18453 -2569 5108 -3275 8914 -4028 -8461 18987 -3952 -26963 -4567 6934 2199 1783 22007 19140 -6840 -768 6029 12007 11375 -4226 124 7540 -4705 -13609 -19223 6407 9405 8176 -17966 5315 3489 -12763 -3518 -5225 -3729 -5698 11473 -2397 8789 -1777 -23074 8877 9086 -27005 12413 5127 -15522 3149 11757 -18890 -13370 10958 13487 13624 28146 4774 3303 -1465 18584 11414 21165 13576 5543 -9703 -9763 -9167 -1330 -153 13782 10713 6776 6869 7984 -30360 -900 -397 -284 5605 12953 986 18667 10205 -355 4503 8990 1928 2619 -11802 -29937 11558 SO 20170819T025322.0Z 6440.120394 3 1 32.00 2 89.72 64.21 67.75 92.18 0.00 1 0.00 1 0 15 1.104e-01 1.052e-01 6.375e-02 6.165e-02 1.527668e+04 4.733422e+03 6.118245e+02 -6.000000e+00 6.170346e+03 279.41 -2.00 20.00 -2.00 505.24 0.00e+00 -7.428997e-04 1.711511e-03 1.272646e-04 -6.000000e+00 3.110130e-03 279.41 -2.00 20.00 -2.00 499.89 0.00e+00 1.573321e-01 1.286360e+00 1.822197e-01 -6.000000e+00 2.223272e+00 232.34 -2.00 4.26 -2.00 501.56 0.00e+00 20.020 0.209 489.00 513.00 1 7.3252e-01 9.8733e-02 4.3274e-02 -6.0000e+00 1.7026e-01 1.6454e-01 2.4718e-02 4.0350e-03 -6.0000e+00 4.4021e-02 5.4440e-02 -4.2972e-04 5.2307e-03 7.3353e-05 -6.0000e+00 1.0593e-02 -5.4080e-02 -1.0086e-04 12 9 9 12 4 4 93.58 30.71 5.64 -0.05408 -0.05706 8 2 1 5 0 4000.000 33.62 15.01 30.71 -4293 4347 -10616 803 -6132 26784 -5170 -11869 16294 7130 -6419 -10178 -8267 -9167 -10423 3036 5364 -4471 4512 1928 7658 5446 918 -3520 14205 597 15164 -15029 -8563 20379 -2625 -14359 13439 -5872 4492 -557 6442 15578 20138 -9539 -9607 10684 3836 1819 -3492 12500 21770 -8694 -5539 5816 4065 21025 -251 8684 -3321 -6908 6183 835 12176 8131 12799 2366 2738 -7447 26262 -3896 -11415 2400 18665 -796 11801 3648 10608 -1479 -23183 -13598 -12736 -7182 -860 -6 -1657 12327 964 5787 -11640 8920 17748 -1328 -8395 10625 -16385 12350 13356 8644 11946 545 -17202 1826 715 14536 -2598 -6564 12111 -3589 16995 -2771 252 -4228 -2171 -1487 9990 22297 452 15974 -7102 11551 -8458 13460 -10316 2158 7471 25047 577 270 -19044 12429 -18740 8112 -13035 -3545 -3680 14329 18738 20085 13001 395 6483 -4581 5738 -1010 -12036 14965 -2020 -2956 1507 -12399 27100 -11979 1210 8 -14941 -4405 4146 -11972 836 -7045 22800 -6076 -15144 15894 7571 -7630 -12392 -9747 -10754 -12253 3111 5415 -5084 4825 2160 8152 5924 1036 -4157 14222 681 15027 -19702 -10350 18180 -2834 -17115 12360 -6697 4828 -637 6857 15065 18366 -11476 -11498 10451 4046 1976 -4010 12401 19644 -10450 -6356 5883 4071 17238 -247 7819 -3399 -7561 6112 885 11555 8003 11976 2443 2833 -8552 21625 -4253 -13210 2380 15662 -796 10271 3423 9328 -1487 -28938 -15608 -14303 -7464 -824 -6 -1578 10321 903 5212 -12533 7988 14654 -1315 -8868 9290 -18602 10671 11565 7821 10378 509 -18310 1563 602 10551 -2194 -5789 9118 -3301 13537 -2767 247 -4288 -2125 -1436 8662 17306 437 13319 -7382 10025 -8887 11618 -11339 2106 6794 18782 536 249 -21237 10256 -20844 6942 -13737 -3390 -3516 11312 14005 14607 10033 348 5483 -4389 5037 -961 -12862 12428 -2001 -2947 1438 -13561 19939 -12716 1103 7 -15617 SO 20170819T025504.0Z 6440.121574 5 1 32.00 2 89.53 64.58 67.55 92.54 0.00 1 0.00 1 0 48 1.066e-01 1.007e-01 5.256e-02 5.110e-02 1.869650e+04 4.089385e+03 1.267465e+03 -6.000000e+00 5.959269e+03 279.41 -2.00 20.00 -2.00 505.31 0.00e+00 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