File name: Pandora105s1_Helsinki_20170822_L2Fit_fwvt1c2d20170321p1-8.txt File generation date: 20251122T153752.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20170321.txt Level 1 file used: Pandora105s1_Helsinki_20170822_L1_smca1c2d20170321p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20170822 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1768 Nominal wavelengths inside fitting window [nm]: 492.0703 492.1911 492.3118 492.4326 492.5533 492.6740 492.7947 492.9154 493.0361 493.1567 493.2774 493.3980 493.5186 493.6392 493.7597 493.8803 494.0008 494.1213 494.2418 494.3623 494.4828 494.6032 494.7236 494.8441 494.9644 495.0848 495.2052 495.3255 495.4458 495.5662 495.6864 495.8067 495.9270 496.0472 496.1674 496.2876 496.4078 496.5280 496.6481 496.7683 496.8884 497.0085 497.1286 497.2486 497.3687 497.4887 497.6087 497.7287 497.8487 497.9687 498.0886 498.2085 498.3285 498.4483 498.5682 498.6881 498.8079 498.9277 499.0475 499.1673 499.2871 499.4069 499.5266 499.6463 499.7660 499.8857 500.0054 500.1250 500.2446 500.3642 500.4838 500.6034 500.7230 500.8425 500.9621 501.0816 501.2010 501.3205 501.4400 501.5594 501.6788 501.7982 501.9176 502.0370 502.1563 502.2757 502.3950 502.5143 502.6336 502.7528 502.8721 502.9913 503.1105 503.2297 503.3489 503.4680 503.5872 503.7063 503.8254 503.9445 504.0636 504.1826 504.3017 504.4207 504.5397 504.6587 504.7776 504.8966 505.0155 505.1344 505.2533 505.3722 505.4910 505.6099 505.7287 505.8475 505.9663 506.0851 506.2038 506.3226 506.4413 506.5600 506.6787 506.7973 506.9160 507.0346 507.1532 507.2718 507.3904 507.5089 507.6275 507.7460 507.8645 507.9830 508.1015 508.2199 508.3384 508.4568 508.5752 508.6936 508.8119 508.9303 509.0486 509.1669 509.2852 509.4035 509.5218 509.6400 509.7582 509.8764 509.9946 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170822T025850.0Z 6443.124190 1 1 32.00 2 89.91 66.01 93.75 62.29 0.00 1 0.00 1 0 64 1.141e-01 1.061e-01 1.073e-01 1.035e-01 2.904531e+03 6.728468e+03 4.529178e+02 -6.000000e+00 6.374570e+03 279.01 -2.00 20.00 -2.00 505.26 0.00e+00 3.143568e-03 2.828684e-03 7.076204e-05 -6.000000e+00 3.209622e-03 279.01 -2.00 20.00 -2.00 499.83 0.00e+00 3.947500e+00 2.125891e+00 2.677306e-02 -6.000000e+00 2.306315e+00 231.88 -2.00 4.26 -2.00 501.51 0.00e+00 20.285 0.217 489.00 513.00 1 9.1983e-01 1.6298e-01 4.1937e-02 -6.0000e+00 1.7633e-01 1.1607e-01 4.1054e-02 2.4202e-03 -6.0000e+00 4.5905e-02 3.1727e-02 4.2473e-02 9.8010e-03 4.8834e-05 -6.0000e+00 1.0994e-02 4.7947e-03 1.4348e-04 12 9 8 11 8 0 48.68 18.86 2.17 0.00479 0.29940 8 2 1 5 0 4000.000 21.69 15.00 18.86 -2600 10879 -2471 -371 16657 7986 -1505 9750 843 14515 2043 -4095 -2046 -7297 11274 -4034 -5321 -3487 -6212 -14213 -6203 -6981 3122 582 21233 -17861 11702 9051 -3905 -14237 18993 -950 8083 29674 308 12760 -5999 -1644 -2460 -2838 4517 -3537 3220 6848 -12906 29340 -9874 8844 -2968 -1514 5771 -4747 7567 -6597 5078 9156 -8344 8957 -11020 5220 9532 -7658 4569 6448 5519 -11759 10245 -14696 -2105 -4468 -6160 -2274 602 936 -127 -4323 -1546 14411 9974 11911 -11901 19967 -14821 29434 12340 20153 -23132 24610 6777 11557 -8966 4336 8 15026 -8521 3645 -4812 -2231 -1795 -11680 32400 4513 11105 -1884 -3400 -1033 -2071 -8813 7573 -14702 -11922 12907 -4146 34497 -5677 19270 1389 4595 -10994 6077 1920 7237 14636 494 -3233 3873 -7745 -17282 12678 14400 3489 -28643 8940 -15552 1042 14860 5720 11140 13413 -5510 3605 -6123 1762 -2645 -2591 1696 -9805 20969 18248 8546 900000 -2851 10720 -2818 -423 16316 8469 -1736 9886 921 13756 2147 -4533 -2217 -8354 11056 -4695 -6372 -4110 -7517 -18490 -7537 -8533 3490 666 19620 -23717 11276 8707 -4221 -17333 17300 -1084 8539 25292 345 12457 -6943 -1833 -2782 -3229 4872 -4149 3547 7248 -16326 24326 -11757 8486 -3112 -1535 5435 -5071 7377 -7544 5272 9120 -9776 8871 -13161 5364 9381 -8816 4621 6283 5338 -13237 9192 -16554 -2096 -4541 -6442 -2313 593 904 -121 -4235 -1462 11701 8500 9997 -12529 15633 -16295 21151 10403 15639 -27181 18272 6029 9959 -9499 4032 8 12176 -8398 3124 -4384 -1949 -1566 -11411 21469 4012 9330 -1786 -3218 -943 -1911 -8756 6559 -16053 -12813 10986 -4174 24128 -5831 15630 1322 4164 -11376 5294 1736 6305 11905 460 -3122 3481 -7769 -19049 10323 11323 3016 -33430 7327 -16485 956 12168 5154 9583 11333 -5607 3395 -6334 1682 -2606 -2492 1525 -9769 15559 14170 7414 900000 SO 20170822T030049.0Z 6443.125567 3 1 32.00 2 89.68 66.44 93.55 62.72 0.00 1 0.00 1 0 22 8.926e-02 8.400e-02 9.139e-02 8.851e-02 1.736198e+01 5.545118e+03 9.591898e+01 -6.000000e+00 4.982466e+03 279.01 -2.00 20.00 -2.00 505.22 0.00e+00 2.436791e-03 2.455471e-03 1.130506e-04 -6.000000e+00 2.507810e-03 279.01 -2.00 20.00 -2.00 499.72 0.00e+00 2.104707e+00 1.868652e+00 2.695444e-02 -6.000000e+00 1.788438e+00 231.88 -2.00 4.26 -2.00 501.42 0.00e+00 19.972 0.207 489.00 513.00 1 9.6000e-01 1.4342e-01 4.0653e-02 -6.0000e+00 1.3702e-01 1.8212e-01 3.7052e-02 2.2464e-03 -6.0000e+00 3.5206e-02 3.7385e-02 -7.9321e-04 8.1368e-03 4.2070e-05 -6.0000e+00 8.5049e-03 -1.0441e-02 2.7419e-05 12 9 8 11 8 0 87.30 18.88 6.22 -0.01044 -0.01594 8 2 1 5 0 4000.000 21.69 15.00 18.88 13860 2512 -17189 10997 3336 -860 -9309 -2351 3948 14164 3539 9608 690 3079 -12771 8029 -1983 -14069 159 6282 -8742 1514 -2689 5074 1294 -1621 2363 -4855 -286 -5387 -3163 -9724 11914 -6318 5969 2643 1547 -4043 5714 3184 -4940 14958 5406 7855 -3046 4877 -10139 -13772 9749 -3273 -4770 -1607 2340 -11927 26303 1512 19746 5485 6536 3259 4279 -5707 7073 6120 5211 4085 -1669 1466 -3016 -5956 8837 9490 10003 -3690 -11327 3418 237 -3668 11188 -311 -5063 8410 -8574 -2154 23381 7042 -9166 -2300 2668 -2884 18702 -9036 7730 -8257 6975 1712 14502 -10840 -2353 2640 21305 19694 5304 1266 9789 10368 1030 5482 -7946 3240 -1521 2518 5212 1095 672 2708 -4428 -8221 1444 4925 437 -10596 -7304 -10641 -15659 2279 -9101 -5941 7506 -14724 9367 -404 -4235 -13369 8130 6534 -4580 -16863 6931 -7187 1951 20641 -12207 6996 28676 9947 6880 7042 -2152 5332 2025 12422 2542 -21704 10918 3633 -995 -11926 -2835 4457 14239 3890 9795 757 3255 -15561 8020 -2199 -18036 181 6809 -11010 1717 -3182 5575 1484 -1915 2671 -5790 -317 -6086 -3439 -11195 11358 -7429 6393 2948 1727 -4709 5959 3376 -5632 14178 5695 8164 -3536 5242 -12587 -17359 9620 -3591 -5154 -1636 2254 -13300 20680 1560 17359 5610 6546 3356 4353 -6442 7050 6150 5237 4085 -1736 1455 -3091 -6146 7829 8329 8800 -3743 -12517 3240 228 -3584 9380 -289 -4937 7208 -8680 -2055 17549 6267 -9528 -2227 2452 -2803 14829 -9423 6982 -8755 6371 1625 11900 -11115 -2159 2269 15103 14159 4511 1150 8359 8811 947 4729 -7687 2832 -1405 2275 4659 1032 641 2540 -4445 -8573 1368 4436 404 -10720 -7104 -10744 -16607 2040 -9117 -5750 6337 -15413 7734 -363 -3846 -13090 6422 5282 -4189 -17661 5847 -7046 1754 15539 -12610 6040 20145 8327 5841 5812 -1884 4313 1692 SO 20170822T030243.0Z 6443.126887 5 1 32.00 2 89.47 66.85 93.35 63.12 0.00 1 0.00 1 0 34 8.695e-02 8.463e-02 8.244e-02 7.987e-02 1.598071e+04 6.508689e+03 1.692065e+03 -6.000000e+00 4.855233e+03 279.01 -2.00 20.00 -2.00 505.28 0.00e+00 1.197327e-03 2.227257e-03 7.740283e-05 -6.000000e+00 2.443877e-03 279.01 -2.00 20.00 -2.00 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