File name: Pandora105s1_Helsinki_20170908_L2Fit_fwvt1c2d20170321p1-8.txt File generation date: 20251122T153811.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20170321.txt Level 1 file used: Pandora105s1_Helsinki_20170908_L1_smca1c2d20170321p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20170908 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1768 Nominal wavelengths inside fitting window [nm]: 492.0703 492.1911 492.3118 492.4326 492.5533 492.6740 492.7947 492.9154 493.0361 493.1567 493.2774 493.3980 493.5186 493.6392 493.7597 493.8803 494.0008 494.1213 494.2418 494.3623 494.4828 494.6032 494.7236 494.8441 494.9644 495.0848 495.2052 495.3255 495.4458 495.5662 495.6864 495.8067 495.9270 496.0472 496.1674 496.2876 496.4078 496.5280 496.6481 496.7683 496.8884 497.0085 497.1286 497.2486 497.3687 497.4887 497.6087 497.7287 497.8487 497.9687 498.0886 498.2085 498.3285 498.4483 498.5682 498.6881 498.8079 498.9277 499.0475 499.1673 499.2871 499.4069 499.5266 499.6463 499.7660 499.8857 500.0054 500.1250 500.2446 500.3642 500.4838 500.6034 500.7230 500.8425 500.9621 501.0816 501.2010 501.3205 501.4400 501.5594 501.6788 501.7982 501.9176 502.0370 502.1563 502.2757 502.3950 502.5143 502.6336 502.7528 502.8721 502.9913 503.1105 503.2297 503.3489 503.4680 503.5872 503.7063 503.8254 503.9445 504.0636 504.1826 504.3017 504.4207 504.5397 504.6587 504.7776 504.8966 505.0155 505.1344 505.2533 505.3722 505.4910 505.6099 505.7287 505.8475 505.9663 506.0851 506.2038 506.3226 506.4413 506.5600 506.6787 506.7973 506.9160 507.0346 507.1532 507.2718 507.3904 507.5089 507.6275 507.7460 507.8645 507.9830 508.1015 508.2199 508.3384 508.4568 508.5752 508.6936 508.8119 508.9303 509.0486 509.1669 509.2852 509.4035 509.5218 509.6400 509.7582 509.8764 509.9946 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170908T033901.0Z 6460.152095 1 1 32.00 2 89.90 78.78 75.36 241.13 0.00 1 0.00 1 0 22 1.305e-01 1.171e-01 8.076e-02 7.731e-02 9.316807e+03 5.555282e+03 5.195906e+02 -6.000000e+00 7.215210e+03 276.76 -2.00 20.00 -2.00 505.24 0.00e+00 3.357618e-03 2.135214e-03 6.328975e-05 -6.000000e+00 3.653936e-03 276.76 -2.00 20.00 -2.00 499.86 0.00e+00 1.437499e-01 1.615638e+00 9.488595e-02 -6.000000e+00 2.623050e+00 229.29 -2.00 4.26 -2.00 501.54 0.00e+00 20.357 0.219 489.00 513.00 1 8.7862e-01 1.2388e-01 4.2820e-02 -6.0000e+00 2.0077e-01 1.8739e-01 3.1359e-02 3.0008e-03 -6.0000e+00 5.1905e-02 4.2664e-02 3.7409e-03 7.0528e-03 5.9830e-05 -6.0000e+00 1.2572e-02 -1.1503e-02 -3.5396e-04 12 9 8 11 4 0 73.23 27.36 13.01 -0.01150 0.01445 8 2 1 5 0 4000.000 30.32 14.96 27.36 -6142 -5567 -6499 11193 3632 -11718 -556 -9280 9741 -4827 7326 5164 -1595 -4043 -2717 -9080 7362 2445 19634 -22623 -1153 30330 7735 6358 -2348 5423 -5118 -14894 -2778 6758 6192 5614 -2772 2656 -230 12314 -208 -18485 16052 10619 -8511 31029 -3282 -10559 120 4507 29097 1401 -8551 17846 15596 -330 18654 -9624 9740 -10080 -2723 26345 -12570 -5484 10138 -8307 6450 16569 -7531 10446 -11023 18546 11193 19505 15674 11976 -3082 2195 -5028 4564 -15141 -18520 -10915 2811 6844 8990 18849 -7461 5064 -8738 21581 13954 20416 4913 11481 -3124 39210 -4966 2217 -2276 -9426 14917 -16939 28916 7823 -4697 2250 14708 16330 4087 -8774 21431 -12011 20126 4840 -2070 -14102 -17446 -8930 4757 -3565 5936 2184 -15704 -3083 1973 52487 -2310 11439 -15943 15559 -4145 3068 9184 -1677 668 25451 -2006 -10896 7393 -21048 4753 8845 -6594 -14926 9017 -1892 7112 1142 -14008 20078 1473 -2910 -6006 16177 -6503 -5932 -7208 10856 3868 -14717 -641 -11700 10229 -5744 7647 5426 -1751 -4485 -2945 -10475 7338 2595 18143 -31833 -1321 25521 8090 6763 -2718 5872 -6092 -19393 -3137 6760 6056 5498 -2975 2795 -258 12317 -234 -24458 14976 10368 -9972 24835 -3714 -13011 134 4860 24658 1537 -10123 16008 13914 -336 15410 -10469 8996 -11637 -2999 22163 -15365 -6272 9900 -9723 6600 15342 -8752 10081 -12856 15969 10250 16220 13373 10556 -3153 2158 -5378 4430 -17458 -21617 -11629 2613 6100 7873 15033 -7728 4670 -9335 17200 11860 16156 4519 9908 -3128 26525 -5177 2126 -2224 -9600 11663 -17618 18758 6177 -4188 1921 11584 13168 3766 -9168 16450 -12620 15449 4352 -2028 -15650 -20149 -9497 4458 -3630 5555 2129 -17991 -3078 1832 29408 -2200 9560 -17478 12552 -4035 2791 7850 -1580 606 17840 -1810 -10688 6081 -23248 4166 7544 -6584 -16341 7813 -1834 6320 1078 -15206 15417 1333 -2686 -5592 12192 SO 20170908T034100.0Z 6460.153472 3 1 32.00 2 89.66 79.21 75.57 241.58 0.00 1 0.00 1 0 29 1.216e-01 1.116e-01 7.413e-02 7.105e-02 1.069322e+04 5.186033e+03 1.348584e+03 -6.000000e+00 6.725066e+03 276.76 -2.00 20.00 -2.00 505.24 0.00e+00 -4.236654e-03 1.936325e-03 2.541917e-04 -6.000000e+00 3.401416e-03 276.76 -2.00 20.00 -2.00 499.73 0.00e+00 2.192337e+00 1.482434e+00 3.560003e-02 -6.000000e+00 2.442125e+00 229.29 -2.00 4.26 -2.00 501.41 0.00e+00 20.011 0.208 489.00 513.00 1 7.9885e-01 1.1321e-01 4.1218e-02 -6.0000e+00 1.8694e-01 1.4603e-01 2.9060e-02 2.5658e-03 -6.0000e+00 4.8225e-02 4.6504e-02 -1.0506e-02 5.9350e-03 1.4413e-04 -6.0000e+00 1.1779e-02 -3.6702e-02 -8.3058e-05 12 9 8 11 12 0 84.69 27.38 7.82 -0.03670 -0.10957 8 2 1 5 0 4000.000 30.32 14.99 27.38 -2477 2205 -14344 -9691 -566 28491 3671 -5649 6930 4421 29332 -6738 13800 -15972 -5129 -16525 21942 -431 -240 -6522 23961 7334 -6762 6774 8058 -2300 8074 3649 3663 7617 -17398 -3359 -4695 4862 10328 582 -4575 6642 -7208 2798 10142 -6044 -5388 -6297 -2671 17882 6200 29535 -2343 -4592 -10279 476 1456 1550 5250 -11054 17079 -2209 -3921 39680 -6125 1492 1776 -1574 9129 -17500 -7015 2508 -21304 3878 2723 17284 -5201 22118 -6774 -3710 1805 3349 12581 8880 11264 3 15571 -906 4987 -12862 12139 -21860 24826 3061 -7731 2211 25604 3566 6524 7300 29158 -1314 1897 -11362 -8939 -7319 24562 -11852 -11375 -1288 15794 9427 -21401 8311 -4540 6566 -17989 25567 8474 3945 12301 -5395 2760 -7958 9475 3142 4426 1304 31785 -2449 -6980 1550 3270 3912 601 -3381 -4900 141 6026 1670 -10861 8000 -9007 -11280 -7977 2253 -1651 25765 20534 12701 -9479 9438 -21002 2923 16503 -2565 2167 -16799 -11185 -616 24131 4000 -6888 7536 4930 25444 -8211 13545 -20671 -5934 -21136 19350 -479 -275 -8166 22596 8120 -8550 7539 8868 -2791 8877 4169 4105 8071 -22724 -3736 -5306 5105 10648 681 -5622 7276 -8873 3097 10310 -7130 -6324 -7499 -3089 17071 6591 24840 -2649 -5209 -12024 484 1424 1489 4883 -12313 14920 -2371 -4310 28533 -6810 1533 1826 -1678 8729 -21465 -7624 2453 -25853 3644 2554 13872 -5186 17085 -7037 -3778 1728 3093 10449 7551 9300 3 12323 -852 4474 -13877 10399 -26003 18770 2844 -7987 2074 19331 3357 5923 6418 20063 -1176 1596 -10595 -8009 -6433 16246 -11585 -11684 -1249 13136 8315 -25092 7193 -4428 5783 -20277 18992 7400 3596 10330 -5421 2605 -8315 8279 2864 3896 1159 21142 -2272 -6792 1383 2860 3388 538 -3108 -4507 123 4885 1418 -10530 6629 -8968 -11587 -8041 2090 -1595 19193 16199 10851 -9919 8130 -23862 2583 12725 SO 20170908T034255.0Z 6460.154803 5 1 31.99 2 89.43 79.62 75.76 242.02 0.00 1 0.00 1 0 15 1.229e-01 1.147e-01 6.609e-02 6.355e-02 5.259949e+03 4.390030e+03 4.718424e+02 -6.000000e+00 6.793660e+03 276.76 -2.00 20.00 -2.00 505.29 0.00e+00 3.656655e-03 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