File name: Pandora105s1_Helsinki_20170910_L2Fit_fwvt1c2d20170321p1-8.txt File generation date: 20251122T153855.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20170321.txt Level 1 file used: Pandora105s1_Helsinki_20170910_L1_smca1c2d20170321p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20170910 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1768 Nominal wavelengths inside fitting window [nm]: 492.0703 492.1911 492.3118 492.4326 492.5533 492.6740 492.7947 492.9154 493.0361 493.1567 493.2774 493.3980 493.5186 493.6392 493.7597 493.8803 494.0008 494.1213 494.2418 494.3623 494.4828 494.6032 494.7236 494.8441 494.9644 495.0848 495.2052 495.3255 495.4458 495.5662 495.6864 495.8067 495.9270 496.0472 496.1674 496.2876 496.4078 496.5280 496.6481 496.7683 496.8884 497.0085 497.1286 497.2486 497.3687 497.4887 497.6087 497.7287 497.8487 497.9687 498.0886 498.2085 498.3285 498.4483 498.5682 498.6881 498.8079 498.9277 499.0475 499.1673 499.2871 499.4069 499.5266 499.6463 499.7660 499.8857 500.0054 500.1250 500.2446 500.3642 500.4838 500.6034 500.7230 500.8425 500.9621 501.0816 501.2010 501.3205 501.4400 501.5594 501.6788 501.7982 501.9176 502.0370 502.1563 502.2757 502.3950 502.5143 502.6336 502.7528 502.8721 502.9913 503.1105 503.2297 503.3489 503.4680 503.5872 503.7063 503.8254 503.9445 504.0636 504.1826 504.3017 504.4207 504.5397 504.6587 504.7776 504.8966 505.0155 505.1344 505.2533 505.3722 505.4910 505.6099 505.7287 505.8475 505.9663 506.0851 506.2038 506.3226 506.4413 506.5600 506.6787 506.7973 506.9160 507.0346 507.1532 507.2718 507.3904 507.5089 507.6275 507.7460 507.8645 507.9830 508.1015 508.2199 508.3384 508.4568 508.5752 508.6936 508.8119 508.9303 509.0486 509.1669 509.2852 509.4035 509.5218 509.6400 509.7582 509.8764 509.9946 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170910T034337.0Z 6462.155289 1 1 32.00 2 89.91 80.30 58.03 221.41 0.00 1 0.00 1 0 63 5.326e-01 2.713e-01 2.423e-01 1.575e-01 -1.745250e+04 8.729650e+03 6.757177e+02 -6.000000e+00 2.947148e+04 276.49 -2.00 20.00 -2.00 505.25 0.00e+00 3.923030e-03 4.303581e-03 1.294297e-04 -6.000000e+00 1.489623e-02 276.49 -2.00 20.00 -2.00 499.83 0.00e+00 4.156313e+00 3.232301e+00 1.977298e-01 -6.000000e+00 1.069321e+01 228.99 -2.00 4.26 -2.00 501.54 0.00e+00 20.381 0.220 489.00 513.00 1 1.2742e+00 2.4653e-01 4.5075e-02 -6.0000e+00 8.1826e-01 1.3374e-01 6.3563e-02 4.2906e-03 -6.0000e+00 2.1126e-01 1.9675e-02 5.4410e-02 1.3170e-02 8.0385e-05 -6.0000e+00 5.1430e-02 -1.1162e-01 1.2956e-03 12 9 9 12 4 4 97.47 30.02 37.76 -0.11162 0.26580 8 2 1 5 0 4000.000 32.96 14.99 30.02 53696 -16585 8353 -7483 31282 -28301 -653 -28827 52925 24537 35096 -3846 22153 18922 94996 23236 27284 38152 19294 23497 8586 6049 -27141 31373 -32904 5348 1398 32640 -14442 4154 -32623 16732 -144 10279 -26042 54871 5126 16002 76728 18855 -11662 29314 36560 397 -9199 5217 10458 -13609 -15707 -8972 30195 -27430 20886 -26715 345 108977 31023 -7619 14098 61407 5618 12423 -7519 14523 35777 -6014 36645 37475 -12328 48641 -15746 7742 40304 22018 5098 -20506 18545 74834 99366 -22521 -23994 64042 46118 47572 24820 11310 14205 -11374 151398 178163 144131 -18845 16467 57817 9492 -14507 10316 17322 -20686 67252 90069 44630 -38552 33857 1415 162537 18311 -34355 11114 108002 27691 2782 15391 11115 22031 16359 15109 -38130 13051 -13047 131027 16931 11145 -34333 99038 -29071 34993 -20667 54139 -18445 -4181 30581 -27841 27147 84745 8645 22086 6671 17850 66509 7699 11300 -541 60815 -24347 52861 -13122 305508 -4781 133639 900000 37289 -23334 9324 -9893 28275 -45082 -782 -44707 36308 22051 28128 -4473 20256 18275 44726 22352 25228 31598 19145 22634 9582 6943 -42950 27649 -53049 5777 1530 26060 -18633 4608 -53537 17080 -172 10948 -39078 36951 5628 15869 42628 18604 -15656 26438 30523 466 -11692 5610 10366 -16547 -19177 -10345 24292 -39874 19339 -39579 392 42670 26000 -9359 13984 38528 6006 12214 -8790 13520 26799 -6630 26437 26706 -14323 31613 -19362 7494 27889 17949 4833 -24890 15431 36336 38210 -28411 -30827 34830 30076 30668 20040 10459 12874 -13406 37345 34481 39784 -25993 16397 38046 9689 -18102 9915 15471 -27010 37695 39920 30119 -56497 24010 1362 32425 15264 -49155 10519 40935 23336 3005 14678 10854 18832 14516 13461 -57033 11881 -15472 38500 15090 10506 -50153 39665 -40480 26038 -26124 32441 -21940 -4239 22097 -36242 21207 38110 8231 18326 6431 15426 35963 7446 10516 -555 33176 -29489 29912 -14175 47147 -4947 35930 900000 SO 20170910T034524.0Z 6462.156528 3 1 32.00 2 89.70 80.68 58.17 221.89 0.00 1 0.00 1 0 64 2.757e-01 2.163e-01 1.581e-01 1.387e-01 -2.419461e+04 7.889396e+03 1.587388e+03 -6.000000e+00 1.523318e+04 276.49 -2.00 20.00 -2.00 505.33 0.00e+00 1.102458e-02 3.826708e-03 5.219534e-04 -6.000000e+00 7.711056e-03 276.49 -2.00 20.00 -2.00 499.78 0.00e+00 9.231225e+00 2.848248e+00 1.399365e-01 -6.000000e+00 5.536213e+00 228.99 -2.00 4.26 -2.00 501.57 0.00e+00 20.077 0.210 489.00 513.00 1 7.7392e-01 2.1828e-01 4.3709e-02 -6.0000e+00 4.2379e-01 5.3751e-02 5.4718e-02 2.5343e-03 -6.0000e+00 1.0932e-01 2.2829e-02 4.3394e-02 1.0393e-02 2.6667e-04 -6.0000e+00 2.6630e-02 -1.2466e-01 4.6120e-04 12 9 9 12 12 4 35.12 30.03 15.40 -0.12466 0.17634 8 2 1 5 0 4000.000 32.96 15.00 30.03 9747 15616 4588 3924 -17915 -20319 6454 -11762 25014 20217 -28016 -10616 38282 3346 -13919 -21439 7785 -13047 -21656 10307 2837 16093 24223 11829 468 3010 5352 34557 -9541 -4524 -13083 23808 -7004 -24274 31004 19085 -11928 4960 12936 19882 1079 22586 104959 -5671 37153 -4837 37243 2307 -7130 -4917 2957 20378 47956 9739 13098 -2205 43667 -12719 52448 76743 -20690 -21706 46521 45116 -3379 51353 38271 4098 30518 2518 -1672 -30726 44273 30641 -15562 -4296 -26639 45471 5607 17278 21672 29896 -1281 -3600 12608 -31031 7914 -2559 24461 -5522 14177 -5894 66178 -8951 -1932 10137 27635 -8580 20492 42010 36715 25050 18811 -3415 -17957 29265 -13822 9542 19343 19809 -3258 -7587 33357 6035 8256 -13283 36728 34937 86925 16041 -13273 11582 61846 -14688 9978 -22001 -25961 -49259 -15077 -10536 16030 -12405 -19353 36737 16706 -7830 -9166 41497 7315 24362 42585 66771 -18000 35726 -15445 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81.05 58.30 222.34 0.00 1 0.00 1 0 46 3.272e-01 2.351e-01 1.543e-01 1.283e-01 2.485795e+03 8.285308e+03 2.527292e+02 -6.000000e+00 1.807037e+04 276.49 -2.00 20.00 -2.00 505.25 0.00e+00 -1.299792e-02 3.470831e-03 5.033021e-04 -6.000000e+00 9.157390e-03 276.49 -2.00 20.00 -2.00 499.81 0.00e+00 6.766618e+00 2.684773e+00 1.002618e-01 -6.000000e+00 6.609996e+00 228.99 -2.00 4.26 -2.00 501.51 0.00e+00 19.719 0.199 489.00 513.00 1 1.2069e+00 2.0637e-01 4.1911e-02 -6.0000e+00 5.0504e-01 2.6584e-02 5.3406e-02 2.6805e-03 -6.0000e+00 1.3183e-01 2.4547e-02 -7.3889e-03 1.1218e-02 1.4027e-04 -6.0000e+00 3.1602e-02 1.8563e-03 -7.0972e-04 12 9 9 12 12 4 27.49 30.03 13.73 0.00186 -0.04940 8 2 1 5 0 4000.000 32.96 15.05 30.03 900000 70033 9234 47640 41048 19775 2092 -36781 31886 16419 -4997 86592 24656 7038 20801 12435 26835 570 76438 31563 3724 -37175 89677 5553 -33518 667 1701 -5879 -5425 -3048 3769 40150 -12915 45571 -15472 -5222 28103 13465 -24716 71629 -15650 6893 34375 27034 21185 7121 29747 -813 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