File name: Pandora105s1_Helsinki_20171006_L2Fit_fwvt1c2d20170321p1-8.txt File generation date: 20251122T155709.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20170321.txt Level 1 file used: Pandora105s1_Helsinki_20171006_L1_smca1c2d20170321p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20171006 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1768 Nominal wavelengths inside fitting window [nm]: 492.0703 492.1911 492.3118 492.4326 492.5533 492.6740 492.7947 492.9154 493.0361 493.1567 493.2774 493.3980 493.5186 493.6392 493.7597 493.8803 494.0008 494.1213 494.2418 494.3623 494.4828 494.6032 494.7236 494.8441 494.9644 495.0848 495.2052 495.3255 495.4458 495.5662 495.6864 495.8067 495.9270 496.0472 496.1674 496.2876 496.4078 496.5280 496.6481 496.7683 496.8884 497.0085 497.1286 497.2486 497.3687 497.4887 497.6087 497.7287 497.8487 497.9687 498.0886 498.2085 498.3285 498.4483 498.5682 498.6881 498.8079 498.9277 499.0475 499.1673 499.2871 499.4069 499.5266 499.6463 499.7660 499.8857 500.0054 500.1250 500.2446 500.3642 500.4838 500.6034 500.7230 500.8425 500.9621 501.0816 501.2010 501.3205 501.4400 501.5594 501.6788 501.7982 501.9176 502.0370 502.1563 502.2757 502.3950 502.5143 502.6336 502.7528 502.8721 502.9913 503.1105 503.2297 503.3489 503.4680 503.5872 503.7063 503.8254 503.9445 504.0636 504.1826 504.3017 504.4207 504.5397 504.6587 504.7776 504.8966 505.0155 505.1344 505.2533 505.3722 505.4910 505.6099 505.7287 505.8475 505.9663 506.0851 506.2038 506.3226 506.4413 506.5600 506.6787 506.7973 506.9160 507.0346 507.1532 507.2718 507.3904 507.5089 507.6275 507.7460 507.8645 507.9830 508.1015 508.2199 508.3384 508.4568 508.5752 508.6936 508.8119 508.9303 509.0486 509.1669 509.2852 509.4035 509.5218 509.6400 509.7582 509.8764 509.9946 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171006T044532.0Z 6488.198287 1 1 32.00 2 89.91 100.64 89.33 273.94 0.00 1 0.00 1 0 29 9.381e-02 9.207e-02 5.889e-02 5.728e-02 -1.831137e+03 3.363126e+03 9.440727e+01 -6.000000e+00 5.094057e+03 272.24 -2.00 20.00 -2.00 505.22 0.00e+00 9.045927e-04 1.570288e-03 5.065228e-05 -6.000000e+00 2.600226e-03 272.24 -2.00 20.00 -2.00 499.88 0.00e+00 2.089450e+00 1.202930e+00 4.819154e-02 -6.000000e+00 1.888276e+00 224.58 -2.00 4.26 -2.00 501.55 0.00e+00 20.521 0.225 489.00 513.00 1 4.8014e-01 9.2059e-02 4.2977e-02 -6.0000e+00 1.4416e-01 1.6624e-01 2.3990e-02 2.4430e-03 -6.0000e+00 3.7572e-02 5.7564e-02 -8.3914e-03 5.4277e-03 2.0278e-05 -6.0000e+00 8.9608e-03 -1.0972e-01 8.0517e-04 12 9 9 12 12 4 77.96 29.53 14.03 -0.10972 -0.16793 8 2 1 5 0 4000.000 32.62 15.01 29.53 -8570 -7772 2905 -7315 3316 -228 5166 21794 -2600 11095 5359 -9393 775 -17881 -5350 -3607 10486 462 -7680 4880 3363 10349 -2522 6593 442 -2460 9150 17392 -6894 10969 6944 -4354 1852 1105 6426 12209 5629 -3630 -7764 -10398 -22064 667 5237 3577 6701 3315 2938 -5471 6663 -7741 -10501 6005 -5718 14751 965 6023 -470 -4190 -10359 6406 -11984 10893 6497 8662 10310 9419 8343 911 3799 -3738 -13219 6373 13057 -7047 3066 -6678 -9314 3775 -1433 -4768 674 -3731 6511 2495 13572 5612 3597 3612 6894 8682 -3565 14897 2196 -5592 -7344 19693 -7467 13649 -505 13037 7651 8405 -4061 -2434 -20218 23689 -1444 7031 3426 -3517 -3585 -14520 16423 -7090 10920 -518 7407 -9364 7581 -2223 18239 19805 2212 -11096 -15336 -961 -24287 -2440 -3469 18586 -11847 5010 4815 8395 -4018 12070 -68 25014 -13224 7020 -2707 4220 -6011 1868 2909 3977 -4214 -6652 14510 7190 900000 -9247 -8393 2902 -8377 3510 -255 5581 20205 -3058 11365 5721 -11367 835 -22902 -5985 -3959 10094 502 -9237 5309 3727 10684 -2936 7078 503 -2887 9530 16694 -8208 10573 6765 -4717 1911 1187 6774 12333 5989 -4181 -9199 -12508 -29472 718 5430 3809 6986 3590 3182 -6321 6763 -8808 -11934 5660 -5887 12437 945 5786 -495 -4638 -12098 6346 -14107 10310 6454 8424 9804 8911 7777 900 3601 -3770 -14460 5700 10985 -7344 2925 -6969 -9822 3446 -1358 -4609 623 -3595 5699 2286 11218 5068 3328 3342 6169 7640 -3534 12501 2110 -5878 -7862 16063 -7764 11360 -472 10389 6328 6912 -3831 -2335 -23603 18192 -1396 6123 3047 -3344 -3452 -15766 13423 -7379 9651 -511 6783 -10067 6884 -2196 14438 15339 2011 -11471 -16649 -907 -28673 -2327 -3332 14436 -12269 4370 4131 6826 -3660 9391 -61 17805 -13928 6104 -2608 3803 -6019 1739 2693 3639 -4100 -6471 11199 5875 900000 SO 20171006T044718.0Z 6488.199514 3 1 32.00 2 89.70 101.02 89.54 274.31 0.00 1 0.00 1 0 33 7.688e-02 7.745e-02 5.070e-02 4.971e-02 -1.913336e+03 2.843195e+03 5.012778e+02 -6.000000e+00 4.175157e+03 272.24 -2.00 20.00 -2.00 505.24 0.00e+00 1.421162e-03 1.349626e-03 4.773968e-05 -6.000000e+00 2.127146e-03 272.24 -2.00 20.00 -2.00 500.06 0.00e+00 3.617153e+00 1.007862e+00 6.445939e-02 -6.000000e+00 1.538454e+00 224.58 -2.00 4.26 -2.00 501.70 0.00e+00 20.215 0.215 489.00 513.00 1 2.5721e-01 7.6839e-02 4.1753e-02 -6.0000e+00 1.1765e-01 1.1153e-01 1.9835e-02 2.3866e-03 -6.0000e+00 3.0318e-02 6.6705e-02 -9.2474e-04 4.6917e-03 7.2466e-05 -6.0000e+00 7.4519e-03 -7.2546e-02 2.1446e-04 12 9 9 12 4 4 99.92 29.55 8.58 -0.07255 -0.07896 8 2 1 5 0 4000.000 32.62 15.01 29.55 15161 -5596 -6766 -11300 10426 -2452 -3200 5828 -2878 10545 -6869 6878 -11981 4802 -5992 11797 7199 2412 -6390 16777 -1562 -9046 12770 3042 2995 2719 -2404 16491 -1824 6031 6092 -3945 13810 7716 12021 -13552 1163 3156 5074 -3841 8044 -3002 -17118 -1892 -4429 -8203 -5204 11506 -9168 3704 -5347 1820 -14563 -2550 -1632 5072 -10117 -4334 -3380 4764 5977 8636 -1311 5441 9125 1381 6231 10554 7045 4932 8855 -4766 15775 1038 759 -8156 9432 -10411 1442 -2303 3281 -3090 4630 11315 10350 8067 -8145 1988 -8084 8924 -3961 4472 7344 -18308 -15256 12249 -640 -21 1073 -4226 3589 4660 -4773 10568 7248 -54 -12159 1299 -11053 8248 13048 -7337 1774 431 2957 6049 6710 578 434 2939 -122 -3845 6764 -540 1928 -3143 -6481 -6669 -202 2485 521 1673 6781 10035 -3674 4109 -12839 2645 8079 -10827 15549 1499 11179 3993 -4834 -2076 -3524 -4681 10105 143 -4674 12687 -5777 -7224 -13081 10070 -2729 -3658 6170 -3332 10575 -8008 6952 -14313 4825 -6593 10945 7069 2521 -7500 16021 -1784 -11040 12634 3327 3295 2985 -2772 15756 -2037 6077 5961 -4209 12619 7687 11873 -17411 1293 3395 5286 -4295 8025 -3332 -21913 -2119 -5142 -9858 -6095 11275 -10787 3779 -5803 1785 -16354 -2552 -1638 4953 -11715 -4800 -3707 4793 5920 8354 -1407 5460 8772 1404 5970 9526 6504 4587 7811 -4753 12978 994 739 -8605 8276 -10821 1321 -2178 2936 -2942 4136 9502 8771 7054 -8407 1854 -8266 7764 -3907 4127 6695 -21674 -17545 10689 -623 -20 982 -3978 3072 3951 -4535 8896 6476 -52 -12994 1190 -11293 6936 10673 -7390 1675 419 2832 5607 6205 569 426 2772 -117 -3774 5930 -511 1794 -3069 -6545 -6739 -191 2292 490 1541 5834 8218 -3417 3549 -13285 2418 7124 -11586 12965 1433 9737 3763 -4970 -2077 -3538 -4644 8484 129 -4458 SO 20171006T044901.0Z 6488.200706 5 1 32.00 2 89.49 101.40 89.74 274.67 0.00 1 0.00 1 0 35 7.834e-02 7.515e-02 4.471e-02 4.374e-02 6.302830e+03 2.987246e+03 8.835073e+02 -6.000000e+00 4.250621e+03 272.24 -2.00 20.00 -2.00 505.21 0.00e+00 1.978169e-03 1.195895e-03 1.004007e-04 -6.000000e+00 2.170698e-03 272.24 -2.00 20.00 -2.00 500.02 0.00e+00 8.168204e-01 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