File name: Pandora105s1_Helsinki_20171011_L2Fit_fwvt1c2d20170321p1-8.txt File generation date: 20251122T155718.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20170321.txt Level 1 file used: Pandora105s1_Helsinki_20171011_L1_smca1c2d20170321p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20171011 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1768 Nominal wavelengths inside fitting window [nm]: 492.0703 492.1911 492.3118 492.4326 492.5533 492.6740 492.7947 492.9154 493.0361 493.1567 493.2774 493.3980 493.5186 493.6392 493.7597 493.8803 494.0008 494.1213 494.2418 494.3623 494.4828 494.6032 494.7236 494.8441 494.9644 495.0848 495.2052 495.3255 495.4458 495.5662 495.6864 495.8067 495.9270 496.0472 496.1674 496.2876 496.4078 496.5280 496.6481 496.7683 496.8884 497.0085 497.1286 497.2486 497.3687 497.4887 497.6087 497.7287 497.8487 497.9687 498.0886 498.2085 498.3285 498.4483 498.5682 498.6881 498.8079 498.9277 499.0475 499.1673 499.2871 499.4069 499.5266 499.6463 499.7660 499.8857 500.0054 500.1250 500.2446 500.3642 500.4838 500.6034 500.7230 500.8425 500.9621 501.0816 501.2010 501.3205 501.4400 501.5594 501.6788 501.7982 501.9176 502.0370 502.1563 502.2757 502.3950 502.5143 502.6336 502.7528 502.8721 502.9913 503.1105 503.2297 503.3489 503.4680 503.5872 503.7063 503.8254 503.9445 504.0636 504.1826 504.3017 504.4207 504.5397 504.6587 504.7776 504.8966 505.0155 505.1344 505.2533 505.3722 505.4910 505.6099 505.7287 505.8475 505.9663 506.0851 506.2038 506.3226 506.4413 506.5600 506.6787 506.7973 506.9160 507.0346 507.1532 507.2718 507.3904 507.5089 507.6275 507.7460 507.8645 507.9830 508.1015 508.2199 508.3384 508.4568 508.5752 508.6936 508.8119 508.9303 509.0486 509.1669 509.2852 509.4035 509.5218 509.6400 509.7582 509.8764 509.9946 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171011T045752.0Z 6493.206852 1 1 32.00 2 89.91 104.55 46.27 219.17 0.00 1 0.00 1 0 47 2.314e-01 1.877e-01 1.171e-01 1.063e-01 2.038416e+04 8.307209e+03 6.964574e+02 -6.000000e+00 1.252529e+04 271.38 -2.00 20.00 -2.00 505.24 0.00e+00 6.809728e-03 2.985533e-03 1.968693e-04 -6.000000e+00 6.402466e-03 271.38 -2.00 20.00 -2.00 500.18 0.00e+00 -2.083760e+00 2.226996e+00 2.331922e-01 -6.000000e+00 4.650649e+00 223.71 -2.00 4.26 -2.00 501.76 0.00e+00 20.550 0.226 489.00 513.00 1 1.2726e+00 1.7043e-01 4.6971e-02 -6.0000e+00 3.5509e-01 1.8887e-01 4.2697e-02 4.8794e-03 -6.0000e+00 9.2427e-02 2.9854e-02 -1.0170e-02 8.9292e-03 8.2257e-05 -6.0000e+00 2.2213e-02 -1.2559e-01 9.5665e-04 12 9 9 12 4 4 -17.28 29.26 16.52 -0.12559 -0.19613 8 2 1 5 0 4000.000 32.28 15.02 29.26 -8809 9031 -18963 11159 962 28687 -24367 42056 -17747 -7315 13461 44939 -4037 -1821 -7893 -18531 15793 -2718 -5816 7186 2526 -6948 15332 13292 36214 28117 18145 -1607 -17489 20229 52271 43205 11974 16862 6801 8530 -5263 -17588 -16464 20841 -9952 -7943 -14716 46733 -9714 9637 -14976 -8748 21474 15848 -7573 -3349 16982 6153 -2621 -15440 9551 10396 10168 -12686 24569 -1032 29636 6418 23152 -28733 61338 44852 13025 12801 45325 37377 8468 22100 -19134 -18421 -31196 8148 433 44136 12457 24034 -21554 6536 -19646 35382 -616 -4886 25313 3437 -851 -11938 24661 -23292 6231 20067 -14792 -1602 22045 5696 23630 -24828 17701 -7193 20504 -13309 18538 13295 98796 4618 -8573 9140 -10899 -20731 38708 72909 5709 -16130 25199 24587 -7332 19390 -1151 -10874 30068 19506 1972 21763 -7105 7938 2760 -9472 28317 -15594 8672 2396 42659 -19677 3537 23442 42551 -17525 18977 -33482 -2887 -2056 30534 -8424 5123 695 900000 -9510 8221 -23322 10614 1034 24050 -34757 32020 -23966 -8864 13107 31659 -4493 -1951 -8886 -22922 14068 -2966 -6653 7391 2704 -8155 14515 12893 28145 23837 16852 -1808 -22448 17515 32118 28596 10886 15084 6916 8674 -6119 -22674 -20769 18271 -11693 -9233 -18576 32951 -12034 10012 -19760 -10764 19436 14894 -8700 -3592 14723 5896 -2802 -19269 9642 10582 10410 -16171 21748 -1178 25289 6877 20909 -42387 37340 31454 12317 11987 30529 27122 8119 18873 -24602 -23534 -44588 7751 438 29024 11017 19103 -26706 6202 -24072 25852 -636 -5224 19918 3303 -853 -13403 19832 -29942 5901 15928 -15802 -1457 15542 4601 15839 -26665 12890 -7022 16125 -14924 15355 11509 37173 4325 -9232 8390 -12250 -25758 26926 36639 5549 -19731 20812 20345 -8118 16107 -1139 -11777 21944 15952 1915 17482 -7484 7237 2638 -10000 20392 -16946 7440 2193 26965 -23038 3343 18498 28054 -20919 15901 -46693 -2977 -2088 22259 -8819 4587 642 900000 SO 20171011T045939.0Z 6493.208090 3 1 32.00 2 89.70 104.93 46.40 219.70 0.00 1 0.00 1 0 60 1.862e-01 1.530e-01 1.103e-01 1.026e-01 -1.259270e+04 5.935246e+03 3.032408e+02 -6.000000e+00 1.006817e+04 271.38 -2.00 20.00 -2.00 505.20 0.00e+00 -2.749721e-03 2.793342e-03 2.085545e-04 -6.000000e+00 5.149956e-03 271.38 -2.00 20.00 -2.00 499.86 0.00e+00 6.237033e+00 2.184929e+00 3.301161e-01 -6.000000e+00 3.756893e+00 223.71 -2.00 4.26 -2.00 501.51 0.00e+00 20.245 0.216 489.00 513.00 1 8.7912e-01 1.6734e-01 4.8707e-02 -6.0000e+00 2.8650e-01 8.2365e-02 4.3493e-02 5.5687e-03 -6.0000e+00 7.5139e-02 3.1056e-02 -7.9204e-03 9.3399e-03 6.1468e-05 -6.0000e+00 1.7675e-02 1.0206e-01 -1.5159e-03 12 9 9 12 12 4 93.69 29.28 10.94 0.10206 0.04712 8 2 1 5 0 4000.000 32.28 15.00 29.28 900000 2905 9391 10184 1744 4773 9857 28258 12495 -6625 27464 -11267 1888 -5699 -14700 -4990 28883 28751 14871 -14035 21062 -4949 41221 -15573 6473 189 8523 23941 -6393 7933 -6736 -22286 4736 -11505 14825 4922 -16152 11875 -8771 -2337 4700 -8073 276 -13009 18188 2700 12633 29092 -5366 -5963 23770 -4936 -7508 -1730 -9666 736 7142 -2856 19057 -1812 -14865 9875 9545 -9489 -3833 -1298 -1909 -7085 -7555 -11602 10605 33834 -4581 -10311 -21523 3500 -15226 -3746 -1852 58321 5352 3861 35943 -859 -13263 -13619 -8930 -25619 4381 -3698 45641 -3458 43471 3277 31079 -10161 21404 -1495 51333 16608 -17297 20182 31648 -11709 -38245 -4011 -1597 13857 10908 3994 -9264 32817 -2275 53414 -8200 -8892 22930 -16143 19774 18394 32775 15684 5232 -9354 10020 -5883 6313 -316 3570 29854 -11270 -5760 12614 7453 15257 -7456 -4217 -20390 -1995 5607 4739 69271 -5113 21735 -8602 36926 -4502 22133 -14355 16824 1162 900000 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9.867e-02 9.308e-02 1.650994e+04 7.017875e+03 2.124243e+02 -6.000000e+00 8.790856e+03 271.38 -2.00 20.00 -2.00 505.30 0.00e+00 -5.598395e-03 2.550320e-03 2.539068e-04 -6.000000e+00 4.499261e-03 271.38 -2.00 20.00 -2.00 500.21 0.00e+00 6.982986e-01 1.899390e+00 3.156898e-01 -6.000000e+00 3.275289e+00 223.71 -2.00 4.26 -2.00 501.86 0.00e+00 19.888 0.204 489.00 513.00 1 1.2209e+00 1.4522e-01 4.7203e-02 -6.0000e+00 2.4995e-01 9.7267e-02 3.6204e-02 5.6871e-03 -6.0000e+00 6.5339e-02 3.4534e-02 5.1111e-03 7.5654e-03 5.7239e-05 -6.0000e+00 1.5723e-02 1.4924e-02 -8.3680e-04 12 9 9 12 4 4 70.06 29.28 13.88 0.01492 0.05038 8 2 1 5 0 4000.000 32.28 15.00 29.28 900000 19058 19322 3677 1687 23427 -4599 -11018 -14397 739 -10408 20620 4143 4200 -14600 -19295 550 -1394 -2053 6156 16814 285 28394 -3380 3454 -14904 10066 9112 1933 -6911 13753 1243 -6952 -21039 16406 9685 13720 -13229 3341 9011 -107 -7218 6514 11532 8598 21249 -17590 5601 23453 5084 5743 29046 12342 -27986 14846 -10743 18589 -15533 13438 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