File name: Pandora105s1_Helsinki_20171021_L2Fit_fwvt1c2d20170321p1-8.txt File generation date: 20251122T155637.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20170321.txt Level 1 file used: Pandora105s1_Helsinki_20171021_L1_smca1c2d20170321p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20171021 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1768 Nominal wavelengths inside fitting window [nm]: 492.0703 492.1911 492.3118 492.4326 492.5533 492.6740 492.7947 492.9154 493.0361 493.1567 493.2774 493.3980 493.5186 493.6392 493.7597 493.8803 494.0008 494.1213 494.2418 494.3623 494.4828 494.6032 494.7236 494.8441 494.9644 495.0848 495.2052 495.3255 495.4458 495.5662 495.6864 495.8067 495.9270 496.0472 496.1674 496.2876 496.4078 496.5280 496.6481 496.7683 496.8884 497.0085 497.1286 497.2486 497.3687 497.4887 497.6087 497.7287 497.8487 497.9687 498.0886 498.2085 498.3285 498.4483 498.5682 498.6881 498.8079 498.9277 499.0475 499.1673 499.2871 499.4069 499.5266 499.6463 499.7660 499.8857 500.0054 500.1250 500.2446 500.3642 500.4838 500.6034 500.7230 500.8425 500.9621 501.0816 501.2010 501.3205 501.4400 501.5594 501.6788 501.7982 501.9176 502.0370 502.1563 502.2757 502.3950 502.5143 502.6336 502.7528 502.8721 502.9913 503.1105 503.2297 503.3489 503.4680 503.5872 503.7063 503.8254 503.9445 504.0636 504.1826 504.3017 504.4207 504.5397 504.6587 504.7776 504.8966 505.0155 505.1344 505.2533 505.3722 505.4910 505.6099 505.7287 505.8475 505.9663 506.0851 506.2038 506.3226 506.4413 506.5600 506.6787 506.7973 506.9160 507.0346 507.1532 507.2718 507.3904 507.5089 507.6275 507.7460 507.8645 507.9830 508.1015 508.2199 508.3384 508.4568 508.5752 508.6936 508.8119 508.9303 509.0486 509.1669 509.2852 509.4035 509.5218 509.6400 509.7582 509.8764 509.9946 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171021T052314.0Z 6503.224468 1 1 31.99 2 89.91 112.26 99.72 97.57 0.00 1 0.00 1 0 27 9.969e-02 9.567e-02 5.865e-02 5.688e-02 4.194103e+03 3.646227e+03 5.480800e+02 -6.000000e+00 5.349326e+03 269.62 -2.00 20.00 -2.00 505.24 0.00e+00 4.447073e-03 1.519614e-03 1.800740e-04 -6.000000e+00 2.746245e-03 269.62 -2.00 20.00 -2.00 499.90 0.00e+00 3.054237e+00 1.172305e+00 5.668863e-02 -6.000000e+00 2.005680e+00 222.16 -2.00 4.26 -2.00 501.55 0.00e+00 20.597 0.227 489.00 513.00 1 3.3661e-01 8.9329e-02 4.3508e-02 -6.0000e+00 1.5298e-01 1.3135e-01 2.2900e-02 2.4190e-03 -6.0000e+00 4.0004e-02 5.7370e-02 1.7822e-02 5.1764e-03 9.3213e-05 -6.0000e+00 9.6012e-03 -1.2119e-02 -6.7132e-04 12 9 8 11 4 0 -84.01 26.21 10.54 -0.01212 0.11150 8 2 1 5 0 4000.000 29.36 15.02 26.21 900000 10916 -7366 -13244 5195 -6286 29023 1645 3743 -700 8283 6025 -2776 -9480 8436 -3744 19236 -1791 -9160 22365 449 5182 -12432 2747 -8248 12713 5372 -1339 -7352 -995 -3726 -8342 -930 -5129 2512 11100 7215 -7225 10342 5687 -2916 -4546 1314 2345 13243 -327 -285 1634 5302 -8380 -2664 -3716 -9051 -1551 -3542 2819 -8759 4435 -13884 -2899 13646 1236 -7500 19094 -6283 -15094 -463 18124 881 9116 339 6071 -2439 16899 10193 -11054 9 -16173 7371 2457 10059 3943 13320 5176 12773 -11229 18745 14922 17600 20390 8190 4368 164 -5663 782 111 -10179 1218 -1912 -283 -3758 5385 8357 29418 -20049 1680 -7684 3519 3121 157 -27471 -5618 3868 6808 110 -12685 16302 -14358 5153 -7945 15188 17084 13369 933 3667 -9984 3117 2610 -14543 10388 19749 15342 -6157 -1072 9 6540 -2795 11306 -6890 11873 -2650 4754 -5560 5968 -14788 8449 6710 161 -6803 8191 1877 900000 9901 -8246 -16244 5423 -7503 24932 1855 4110 -791 8413 6171 -3035 -10946 8159 -4073 17022 -1990 -11113 20273 502 5524 -15710 3024 -10119 12764 5739 -1511 -8571 -1051 -3974 -9360 -994 -5928 2761 11238 7508 -8513 10191 5841 -3248 -5196 1434 2568 13133 -372 -322 1788 5495 -9639 -2810 -3864 -9812 -1574 -3775 2907 -10277 4626 -17214 -3232 12898 1320 -8765 17200 -7163 -18480 -481 15521 878 8242 331 5589 -2465 14258 9261 -12212 8 -18039 6474 2256 8565 3584 11060 4648 10710 -11938 14973 12224 13958 15707 7166 4028 159 -5844 748 105 -10392 1082 -1707 -243 -3308 4366 6769 20203 -22623 1542 -7650 3082 2724 143 -33139 -5551 3555 6137 106 -13952 13628 -16140 4781 -8283 12346 13523 10840 862 3323 -10339 2834 2383 -15749 8845 15243 12195 -5918 -968 8 5521 -2626 9475 -6971 10133 -2612 4368 -5688 5467 -16579 7523 5977 148 -6567 6810 1668 SO 20171021T052513.0Z 6503.225845 3 1 32.00 2 89.68 112.69 99.49 97.99 0.00 1 0.00 1 0 15 7.375e-02 7.076e-02 5.052e-02 4.929e-02 -2.539034e+03 2.855794e+03 4.552053e+02 -6.000000e+00 3.959257e+03 269.62 -2.00 20.00 -2.00 505.21 0.00e+00 3.741102e-04 1.349771e-03 2.154678e-05 -6.000000e+00 2.027020e-03 269.62 -2.00 20.00 -2.00 499.87 0.00e+00 3.677725e+00 1.019140e+00 3.303057e-02 -6.000000e+00 1.467495e+00 222.16 -2.00 4.26 -2.00 501.55 0.00e+00 20.265 0.216 489.00 513.00 1 2.6657e-01 7.8168e-02 4.1756e-02 -6.0000e+00 1.1219e-01 1.3690e-01 1.9986e-02 2.3066e-03 -6.0000e+00 2.8827e-02 6.6567e-02 -4.7664e-03 4.6409e-03 6.2493e-05 -6.0000e+00 7.0201e-03 -3.9182e-02 2.2842e-04 12 9 8 11 4 0 -178.47 26.23 5.65 -0.03918 -0.07224 8 2 1 5 0 4000.000 29.36 14.98 26.23 -5284 2118 8182 3537 -3461 -326 -3168 -6039 -1933 -7660 15300 -4920 -4148 -1839 -2850 -8015 19268 -2799 -3218 2053 17922 4910 -425 3221 255 -1174 -11486 3234 6327 11165 -8280 15003 -10897 3405 2998 3784 -7896 5288 5242 8172 6008 4571 -7073 2718 -4883 -11626 -5830 -1237 -2318 -11561 3085 -3645 13831 -2057 198 1849 10942 955 12502 2698 13617 5827 -3214 -4454 -2123 13790 -6089 -940 4663 6959 -1120 -1206 -9746 13000 3523 20050 16602 -2264 -3385 -3551 -3108 -4922 2189 362 -2986 3787 4673 -5095 502 3721 1886 -9323 -2200 -6059 2113 -10934 -1555 11147 -3752 8549 3243 13949 -13878 7673 2 13665 1631 7413 -800 7000 -5749 -2211 2636 2218 -531 -1478 3587 -10268 -1009 -3603 -9586 -6243 -1563 7255 5795 2342 11752 7073 6376 -1586 3144 -413 14092 -4405 -1950 -5258 -3746 -940 -4675 -4135 -853 -9116 -2572 12828 840 3678 -14188 -6324 2147 14158 10261 -5548 2090 7830 3642 -3926 -366 -3727 -7347 -2261 -9393 14803 -5704 -4708 -2013 -3123 -9247 17257 -3176 -3769 2318 17319 5400 -489 3583 293 -1373 -14838 3578 6649 10900 -9475 13647 -12840 3626 3313 4204 -9710 5667 5546 8304 6167 4774 -8367 2944 -5759 -14599 -6873 -1376 -2562 -13695 3089 -3757 11821 -2057 196 1857 10291 1004 11693 2768 12475 5785 -3478 -4879 -2255 12402 -6508 -939 4347 6298 -1076 -1153 -10211 10988 3313 15955 13440 -2166 -3227 -3372 -2941 -4736 1973 334 -2871 3431 4212 -5026 471 3390 1758 -9743 -2175 -6294 2023 -11733 -1512 9360 -3566 7010 2760 10697 -14247 6612 2 11399 1501 6310 -729 5885 -5557 -2101 2431 2084 -514 -1451 3358 -10954 -981 -3546 -9784 -6132 -1455 6210 5069 2127 9708 6111 5536 -1482 2800 -377 10935 -4044 -1730 -4844 -3440 -859 -4516 -4017 -807 -9327 -2493 10733 797 3391 -15331 -6164 1887 10865 8217 SO 20171021T052708.0Z 6503.227176 5 1 31.99 2 89.46 113.11 99.26 98.39 0.00 1 0.00 1 0 36 7.140e-02 6.933e-02 4.274e-02 4.180e-02 1.834782e+04 3.178310e+03 1.397675e+02 -6.000000e+00 3.833648e+03 269.62 -2.00 20.00 -2.00 505.13 0.00e+00 5.865877e-03 1.121874e-03 4.482189e-04 -6.000000e+00 1.965628e-03 269.62 -2.00 20.00 -2.00 499.94 0.00e+00 -2.387810e+00 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