File name: Pandora105s1_Helsinki_20171121_L2Fit_fwvt1c2d20170321p1-8.txt File generation date: 20251122T161243.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20170321.txt Level 1 file used: Pandora105s1_Helsinki_20171121_L1_smca1c2d20170321p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20171121 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1768 Nominal wavelengths inside fitting window [nm]: 492.0703 492.1911 492.3118 492.4326 492.5533 492.6740 492.7947 492.9154 493.0361 493.1567 493.2774 493.3980 493.5186 493.6392 493.7597 493.8803 494.0008 494.1213 494.2418 494.3623 494.4828 494.6032 494.7236 494.8441 494.9644 495.0848 495.2052 495.3255 495.4458 495.5662 495.6864 495.8067 495.9270 496.0472 496.1674 496.2876 496.4078 496.5280 496.6481 496.7683 496.8884 497.0085 497.1286 497.2486 497.3687 497.4887 497.6087 497.7287 497.8487 497.9687 498.0886 498.2085 498.3285 498.4483 498.5682 498.6881 498.8079 498.9277 499.0475 499.1673 499.2871 499.4069 499.5266 499.6463 499.7660 499.8857 500.0054 500.1250 500.2446 500.3642 500.4838 500.6034 500.7230 500.8425 500.9621 501.0816 501.2010 501.3205 501.4400 501.5594 501.6788 501.7982 501.9176 502.0370 502.1563 502.2757 502.3950 502.5143 502.6336 502.7528 502.8721 502.9913 503.1105 503.2297 503.3489 503.4680 503.5872 503.7063 503.8254 503.9445 504.0636 504.1826 504.3017 504.4207 504.5397 504.6587 504.7776 504.8966 505.0155 505.1344 505.2533 505.3722 505.4910 505.6099 505.7287 505.8475 505.9663 506.0851 506.2038 506.3226 506.4413 506.5600 506.6787 506.7973 506.9160 507.0346 507.1532 507.2718 507.3904 507.5089 507.6275 507.7460 507.8645 507.9830 508.1015 508.2199 508.3384 508.4568 508.5752 508.6936 508.8119 508.9303 509.0486 509.1669 509.2852 509.4035 509.5218 509.6400 509.7582 509.8764 509.9946 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171121T064425.0Z 6534.280845 1 1 32.00 2 89.93 133.59 104.60 105.75 0.00 1 0.00 1 0 15 1.423e-01 1.280e-01 9.943e-02 9.475e-02 -2.142379e+03 5.162992e+03 3.927213e+02 -6.000000e+00 7.477109e+03 264.55 -2.00 20.00 -2.00 505.18 0.00e+00 2.216313e-03 2.532740e-03 4.165485e-05 -6.000000e+00 3.872387e-03 264.55 -2.00 20.00 -2.00 499.83 0.00e+00 2.521144e+00 1.947698e+00 6.293258e-02 -6.000000e+00 2.841802e+00 218.49 -2.00 4.26 -2.00 501.51 0.00e+00 20.771 0.233 489.00 513.00 1 9.3529e-01 1.4919e-01 4.4124e-02 -6.0000e+00 2.1691e-01 1.6537e-01 3.8701e-02 2.4992e-03 -6.0000e+00 5.6105e-02 3.3213e-02 -1.3901e-02 8.9914e-03 8.5717e-05 -6.0000e+00 1.3727e-02 -2.4567e-02 -2.5041e-04 12 9 8 11 4 0 -192.64 27.10 14.00 -0.02457 -0.12099 8 2 1 5 0 4000.000 30.21 15.01 27.10 -12127 3993 -9487 18634 -11224 1338 6074 9253 13258 1575 5378 21429 -12192 -310 -460 -12855 -4628 7598 -21508 -8362 8574 -8289 22984 -10136 -8225 1208 10687 9076 10658 6291 4294 7946 21694 39630 16730 -9155 -6915 -10785 9354 15058 11967 -2238 18907 -31070 -9655 6754 -776 3337 11437 -4727 -14631 20539 3547 476 27675 5616 4900 3939 19491 13902 7160 20059 4409 -13074 -7752 -15559 9285 -1567 28189 15990 2472 -10564 17002 -12139 -6512 -3499 9271 536 -7954 -5050 -12740 -11711 -10295 4942 9960 -3544 -10585 2347 19286 10594 6212 27890 1155 -3717 22131 -2149 625 2267 -7322 -21731 26310 4716 2123 14490 5552 4272 -8677 43434 -3940 -22223 -9975 16308 -6405 6582 45860 -8120 -1220 -10010 5963 5138 -3228 13200 31116 12302 1082 14219 -16977 -1101 -557 27256 3812 -10150 224 -5680 235 -12697 24964 38573 3240 -12995 -8375 -9890 17127 -14774 -8618 6805 3238 4099 24383 7663 -14106 -14015 3867 -10556 16273 -13565 1464 6467 9718 13531 1807 5869 19749 -15251 -342 -501 -15585 -5163 7645 -29134 -10276 9030 -10350 21131 -12767 -10193 1381 11133 9578 10982 6630 4464 7744 18342 28684 15623 -11353 -8492 -13555 9561 14354 11650 -2485 17216 -46342 -11849 7109 -885 3634 11350 -5424 -17984 17533 3457 469 20931 5365 4866 4052 17374 13095 7123 17627 4510 -15867 -8921 -19224 8889 -1642 21756 13657 2383 -11354 13908 -13259 -6808 -3592 8364 519 -8206 -4989 -13515 -12207 -10642 4445 8556 -3481 -11241 2196 15341 9107 5584 20432 1108 -3810 17879 -2183 613 2157 -7526 -24958 18513 4047 1857 11499 4931 3936 -9055 26939 -3788 -25286 -10032 12877 -6423 5910 28676 -8598 -1212 -10898 5575 4807 -3212 11050 21658 10184 998 11669 -18809 -1048 -527 19604 3442 -10446 206 -5430 210 -12646 17234 23832 2870 -13663 -8495 -10240 13662 -16132 -8899 6053 2981 3694 17632 6324 -14124 SO 20171121T064624.0Z 6534.282222 3 1 32.00 2 89.75 134.02 104.37 106.15 0.00 1 0.00 1 0 39 1.437e-01 1.334e-01 9.277e-02 8.820e-02 7.008406e+03 5.972309e+03 6.057844e+02 -6.000000e+00 7.558266e+03 264.55 -2.00 20.00 -2.00 505.19 0.00e+00 -3.619827e-03 2.357372e-03 3.391663e-04 -6.000000e+00 3.909062e-03 264.55 -2.00 20.00 -2.00 499.84 0.00e+00 2.980141e+00 1.814220e+00 7.253060e-02 -6.000000e+00 2.882158e+00 218.49 -2.00 4.26 -2.00 501.49 0.00e+00 20.520 0.225 489.00 513.00 1 9.2836e-01 1.3810e-01 4.3897e-02 -6.0000e+00 2.1960e-01 1.2938e-01 3.5055e-02 2.7345e-03 -6.0000e+00 5.7275e-02 3.5626e-02 7.6983e-03 7.7139e-03 1.1899e-04 -6.0000e+00 1.3783e-02 -5.1931e-02 -2.7163e-04 12 9 8 11 4 0 -135.35 27.12 4.60 -0.05193 0.00147 8 2 1 5 0 4000.000 30.21 15.01 27.12 900000 -13129 -8450 -5721 11598 -16530 4034 116 -1836 629 -14104 29063 -3817 30976 14779 26716 25217 803 22988 6906 2145 4989 -21643 11783 -7328 10981 -5578 -2754 3233 13318 -5593 27760 -7241 23521 22875 -8183 5281 10623 3926 -14739 -9261 -11025 31173 -10957 4053 -8736 5363 11100 2791 -30403 -704 11918 -4427 4962 -15913 5773 -17349 41186 23990 -6741 -4544 8097 61 38076 -4196 18371 -9704 3022 10280 141 13968 -6873 13725 14902 12162 -555 -14947 3041 5969 -10435 21607 -249 830 -9600 31946 -4459 -3738 -8749 -1226 -3918 -5528 21113 1946 -16969 -1255 -5896 4352 12916 -5677 19704 -6460 18175 -20428 2517 -7289 2211 16733 -18342 18695 -16191 2938 8392 18038 -931 -460 -2959 -2991 6510 10824 14874 -4054 -5289 109 16881 19247 11326 6480 5434 5938 6952 -21200 35830 -173 -4935 7811 35138 -24479 -3536 6592 -9935 15522 13259 8491 7125 -16197 12023 6775 15079 9775 -20574 -10021 900000 -15052 -9523 -6491 11365 -21737 4442 133 -2166 718 -18284 24590 -4397 25086 13967 22437 21793 902 21313 7659 2486 5622 -31576 12422 -9305 11697 -6923 -3322 3601 12989 -6417 22916 -8485 21133 21385 -10490 5875 11053 4306 -19087 -11280 -13667 25871 -13738 4441 -10806 5770 11126 2965 -43608 -734 10689 -4540 4656 -18475 5609 -21607 29343 20259 -7574 -4972 7883 64 27776 -4568 15852 -10805 2916 9112 137 11722 -6967 11493 12509 10633 -546 -16703 2797 5246 -10649 16125 -231 768 -9867 22279 -4462 -3736 -9194 -1192 -3908 -5616 16688 1869 -19575 -1229 -5885 3804 10071 -5198 13832 -5787 12952 -21787 2241 -7483 2109 13782 -20977 14638 -17737 2699 7384 14525 -902 -444 -2928 -2982 5960 9523 12458 -4000 -5178 99 13119 14695 9398 5600 4735 5132 5945 -23804 22839 -154 -4527 6337 22078 -27921 -3375 5790 -10366 12799 11280 7632 6536 -18565 10537 6152 12452 8267 -23088 -10145 SO 20171121T064813.0Z 6534.283484 5 1 32.00 2 89.59 134.42 104.16 106.52 0.00 1 0.00 1 0 43 1.497e-01 1.348e-01 9.475e-02 8.923e-02 1.742810e+04 7.038881e+03 8.115925e+02 -6.000000e+00 7.864510e+03 264.55 -2.00 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