File name: Pandora105s1_Helsinki_20171123_L2Fit_fwvt1c2d20170321p1-8.txt File generation date: 20251122T161258.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20170321.txt Level 1 file used: Pandora105s1_Helsinki_20171123_L1_smca1c2d20170321p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20171123 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1768 Nominal wavelengths inside fitting window [nm]: 492.0703 492.1911 492.3118 492.4326 492.5533 492.6740 492.7947 492.9154 493.0361 493.1567 493.2774 493.3980 493.5186 493.6392 493.7597 493.8803 494.0008 494.1213 494.2418 494.3623 494.4828 494.6032 494.7236 494.8441 494.9644 495.0848 495.2052 495.3255 495.4458 495.5662 495.6864 495.8067 495.9270 496.0472 496.1674 496.2876 496.4078 496.5280 496.6481 496.7683 496.8884 497.0085 497.1286 497.2486 497.3687 497.4887 497.6087 497.7287 497.8487 497.9687 498.0886 498.2085 498.3285 498.4483 498.5682 498.6881 498.8079 498.9277 499.0475 499.1673 499.2871 499.4069 499.5266 499.6463 499.7660 499.8857 500.0054 500.1250 500.2446 500.3642 500.4838 500.6034 500.7230 500.8425 500.9621 501.0816 501.2010 501.3205 501.4400 501.5594 501.6788 501.7982 501.9176 502.0370 502.1563 502.2757 502.3950 502.5143 502.6336 502.7528 502.8721 502.9913 503.1105 503.2297 503.3489 503.4680 503.5872 503.7063 503.8254 503.9445 504.0636 504.1826 504.3017 504.4207 504.5397 504.6587 504.7776 504.8966 505.0155 505.1344 505.2533 505.3722 505.4910 505.6099 505.7287 505.8475 505.9663 506.0851 506.2038 506.3226 506.4413 506.5600 506.6787 506.7973 506.9160 507.0346 507.1532 507.2718 507.3904 507.5089 507.6275 507.7460 507.8645 507.9830 508.1015 508.2199 508.3384 508.4568 508.5752 508.6936 508.8119 508.9303 509.0486 509.1669 509.2852 509.4035 509.5218 509.6400 509.7582 509.8764 509.9946 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171123T064923.0Z 6536.284294 1 1 32.00 2 89.92 134.72 115.00 86.90 0.00 1 0.00 1 0 19 7.359e-01 3.339e-01 3.764e-01 2.535e-01 3.005017e+04 2.039636e+04 1.514209e+03 -6.000000e+00 3.867499e+04 264.36 -2.00 20.00 -2.00 505.33 0.00e+00 -6.078911e-03 7.195763e-03 6.358336e-04 -6.000000e+00 2.002551e-02 264.36 -2.00 20.00 -2.00 499.95 0.00e+00 1.235112e+00 5.116865e+00 3.449768e-01 -6.000000e+00 1.474709e+01 218.41 -2.00 4.26 -2.00 501.64 0.00e+00 20.776 0.233 489.00 513.00 1 2.0116e+00 3.9684e-01 5.3995e-02 -6.0000e+00 1.1261e+00 7.0049e-02 9.7908e-02 7.2995e-03 -6.0000e+00 2.9255e-01 1.1262e-02 4.5956e-03 1.9913e-02 2.0702e-04 -6.0000e+00 7.1344e-02 -4.3731e-02 7.7865e-04 12 9 8 11 4 0 99.87 27.13 37.75 -0.04373 -0.01185 8 2 1 5 0 4000.000 30.21 15.01 27.13 -25125 47041 98866 11137 9096 14713 -138 -9750 27854 -4862 -37252 107542 -23893 42670 23222 -1209 38382 2005 17169 -12388 40370 -18836 48033 1642 -11903 2226 42300 -31435 19254 564325 54784 27182 893 -8655 56985 59072 -22094 38456 -26799 -8413 42520 -3741 5376 9093 4913 -27269 22754 1180 -10632 -14486 128989 40 45790 17211 113607 32235 21201 107202 29122 14005 6182 74860 73857 -17935 226413 20437 43599 83276 -21600 28970 10393 -30955 5828 -23079 -23618 40228 36833 96674 -7127 53262 1736 -14368 -43632 67501 -28363 -15611 38680 37100 7175 24581 -18451 45044 228489 25229 52554 18148 8733 -22108 227273 -11788 -36815 15406 115795 81205 28922 39780 37357 -190 17926 -6730 -25040 26277 -23006 6666 45633 81485 31586 23367 84789 12126 2399 -6323 47606 34041 -31346 29797 19729 -19588 79560 178020 32720 20321 -9094 130716 900000 -58429 77907 14327 69749 42194 39756 -22173 8943 11 54988 -35341 65607 40703 61678 26529 900000 -32692 31481 41128 11155 9506 14858 -163 -12726 25016 -5947 -61445 43367 -34044 31611 21000 -1409 31294 2387 18040 -17308 33886 -28141 37459 2025 -16654 2714 34551 -51307 18655 140136 37072 24344 1070 -11699 41400 41704 -33848 32250 -41969 -10901 33667 -4652 6148 10088 5687 -42905 21775 1366 -13521 -18418 39505 43 31223 15751 42317 27073 19912 43561 25078 13995 6656 41750 41642 -24355 56224 18473 31083 40172 -28479 23207 9951 -44608 5961 -31679 -32464 29090 26927 38840 -7824 32426 1752 -17081 -70089 37580 -40553 -19746 28739 27712 7113 20637 -23625 31160 56740 19939 29964 13663 6881 -23075 56438 -11000 -45002 12050 36871 39040 24148 30180 28779 -207 16380 -7863 -34965 22124 -30762 6596 30809 39827 25598 20962 41613 11812 2470 -6921 30663 25097 -44089 23173 16846 -24544 38113 44207 24124 16614 -9912 37097 900000 -108712 39600 13660 39609 31998 31440 -32168 9606 13 37603 -57437 39602 30940 38172 23157 900000 SO 20171123T065121.0Z 6536.285660 3 1 32.01 2 89.75 135.14 114.77 87.32 0.00 1 0.00 1 0 47 5.872e-01 3.347e-01 3.596e-01 2.407e-01 -1.312799e+04 1.291136e+04 3.259685e+02 -6.000000e+00 3.089192e+04 264.36 -2.00 20.00 -2.00 504.98 0.00e+00 2.422368e-03 6.549168e-03 1.850710e-04 -6.000000e+00 1.602957e-02 264.36 -2.00 20.00 -2.00 499.88 0.00e+00 -5.185962e-01 5.052135e+00 3.182197e-01 -6.000000e+00 1.171912e+01 218.41 -2.00 4.26 -2.00 501.45 0.00e+00 20.532 0.225 489.00 513.00 1 2.0886e+00 3.8489e-01 4.9091e-02 -6.0000e+00 8.9396e-01 3.0729e-01 1.0237e-01 5.4567e-03 -6.0000e+00 2.3084e-01 1.1733e-02 -4.9773e-02 2.1038e-02 9.2232e-05 -6.0000e+00 5.6928e-02 -1.7908e-01 1.7450e-03 12 9 8 11 12 0 64.98 27.16 23.70 -0.17908 -0.52432 8 2 1 5 0 4000.000 30.32 14.97 27.16 12312 -17265 -23354 -11879 41829 13881 66200 81746 143806 75957 -30394 -8816 46506 50853 43805 95395 -25549 900000 50484 18357 71067 9193 23089 79653 5938 31507 -46960 13844 52425 32461 18126 48136 24837 47407 3243 6544 43103 -19366 104039 -45425 22394 68883 119273 -28386 -8961 9714 -11227 -17112 9599 54763 24696 52504 72313 14758 -26861 138028 -8139 14714 -32663 -22199 19448 236329 -11124 107279 63192 40105 4691 -2991 14275 -25578 33122 39177 96787 60199 35909 17869 -5813 -39659 75974 1928 109074 -1327 73996 37635 -46850 92664 228705 62586 34029 1196 27974 -9457 -6754 33352 -13509 5806 40370 8595 -31477 59702 81703 -24764 13977 42437 25880 -18282 9493 -4676 48585 -17411 103404 26243 53089 -23736 -5777 20852 23352 -33266 5041 12096 101088 -39621 23958 14383 184598 3338 62632 186240 11268 22330 19899 44859 33702 49346 40 50276 -19830 35587 69441 48448 23 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20171123T065316.0Z 6536.286991 5 1 32.00 2 89.59 135.56 114.54 87.73 0.00 1 0.00 1 0 39 5.346e-01 3.030e-01 2.982e-01 2.083e-01 -1.888046e+03 1.103379e+04 3.104099e+02 -6.000000e+00 2.807602e+04 264.36 -2.00 20.00 -2.00 505.25 0.00e+00 -1.601988e-03 5.596343e-03 2.141090e-04 -6.000000e+00 1.453864e-02 264.36 -2.00 20.00 -2.00 500.49 0.00e+00 -2.085107e+00 4.037050e+00 1.360919e-01 -6.000000e+00 1.069872e+01 218.41 -2.00 4.26 -2.00 502.06 0.00e+00 20.249 0.216 489.00 513.00 1 2.1288e+00 3.0113e-01 4.3001e-02 -6.0000e+00 8.1575e-01 1.8623e-01 8.2185e-02 2.9671e-03 -6.0000e+00 2.1210e-01 1.3937e-02 8.7654e-04 1.9042e-02 8.1919e-05 -6.0000e+00 5.1182e-02 -6.4130e-02 7.1888e-04 12 9 8 11 4 0 66.19 27.17 16.78 -0.06413 -0.05805 8 2 1 5 0 4000.000 30.32 14.98 27.17 53467 -8886 1051 44723 -16393 -2214 33169 -14619 14428 -9141 -1351 142 -15832 -14302 -14630 61647 75027 46476 -17890 61247 66555 29749 41488 86832 6624 79260 -22693 -13479 51839 22235 23497 -7418 30353 -40199 123358 3426 77351 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