File name: Pandora105s1_Helsinki_20180421_L2Fit_fwvt1c2d20180411p1-8.txt File generation date: 20251122T161509.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20180411.txt Level 1 file used: Pandora105s1_Helsinki_20180421_L1_smca1c2d20180411p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20180421 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1767 Nominal wavelengths inside fitting window [nm]: 492.0970 492.2178 492.3385 492.4593 492.5800 492.7007 492.8214 492.9421 493.0628 493.1834 493.3041 493.4247 493.5453 493.6659 493.7864 493.9070 494.0275 494.1480 494.2685 494.3890 494.5094 494.6299 494.7503 494.8707 494.9911 495.1115 495.2318 495.3522 495.4725 495.5928 495.7131 495.8334 495.9536 496.0738 496.1941 496.3143 496.4345 496.5546 496.6748 496.7949 496.9150 497.0351 497.1552 497.2753 497.3953 497.5153 497.6353 497.7553 497.8753 497.9953 498.1152 498.2351 498.3550 498.4749 498.5948 498.7147 498.8345 498.9543 499.0741 499.1939 499.3137 499.4334 499.5532 499.6729 499.7926 499.9123 500.0319 500.1516 500.2712 500.3908 500.5104 500.6300 500.7495 500.8691 500.9886 501.1081 501.2276 501.3471 501.4665 501.5859 501.7054 501.8248 501.9442 502.0635 502.1829 502.3022 502.4215 502.5408 502.6601 502.7793 502.8986 503.0178 503.1370 503.2562 503.3754 503.4945 503.6137 503.7328 503.8519 503.9710 504.0901 504.2091 504.3281 504.4472 504.5662 504.6851 504.8041 504.9230 505.0420 505.1609 505.2798 505.3986 505.5175 505.6363 505.7552 505.8740 505.9928 506.1115 506.2303 506.3490 506.4677 506.5864 506.7051 506.8238 506.9424 507.0610 507.1797 507.2983 507.4168 507.5354 507.6539 507.7725 507.8910 508.0094 508.1279 508.2464 508.3648 508.4832 508.6016 508.7200 508.8384 508.9567 509.0750 509.1934 509.3117 509.4299 509.5482 509.6664 509.7847 509.9029 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180421T025408.0Z 6685.120926 1 1 32.00 2 89.91 65.86 100.34 359.74 0.00 1 0.00 1 0 22 1.447e-01 1.317e-01 1.291e-01 1.227e-01 -3.530711e+03 6.792722e+03 2.261447e+02 -6.000000e+00 7.731847e+03 268.20 -2.00 20.00 -2.00 505.13 0.00e+00 2.834081e-03 3.279593e-03 1.666330e-04 -6.000000e+00 3.964054e-03 268.20 -2.00 20.00 -2.00 499.78 0.00e+00 2.927385e+00 2.566678e+00 4.811671e-02 -6.000000e+00 2.926332e+00 228.33 -2.00 4.26 -2.00 501.43 0.00e+00 20.584 0.227 489.00 513.00 1 1.1496e+00 1.9734e-01 4.3561e-02 -6.0000e+00 2.2302e-01 1.7119e-01 5.0777e-02 2.5400e-03 -6.0000e+00 5.8178e-02 2.6199e-02 8.6041e-03 1.1117e-02 6.5545e-05 -6.0000e+00 1.3871e-02 3.3472e-02 -1.2463e-04 12 9 8 11 8 0 94.17 17.97 10.04 0.03347 0.09315 8 2 1 5 0 4000.000 20.87 14.87 17.97 363 1756 -1663 -11052 -14439 3425 24370 -481 10292 40 10302 5516 10795 -1431 31855 -1681 -9002 -2237 -9900 16161 -12404 10732 -13755 14423 -13531 10825 -2644 13709 -699 37462 -8717 581 305 -2246 8415 6799 -8329 1290 11517 -14563 10767 -8665 22961 13838 -5445 -2045 24598 -13931 -413 -14714 -8465 9693 893 20846 -6817 23446 8346 19185 -12492 32609 2311 22017 -1260 13821 -27872 -4080 -11665 2537 2333 11307 -4253 -24300 3969 -14090 14920 -7089 41632 1867 9656 16 -16941 13311 -3122 18827 7368 11555 8116 10612 -9747 31404 -21384 1754 -2736 20316 891 18041 -11996 -444 -9344 6481 -21678 3116 16191 24261 15574 -5854 11681 -17689 28344 -20147 23398 -17365 -5587 -3910 1311 7486 -11192 11675 -5312 9085 20085 44325 -36 -1333 -12069 26582 -2887 12970 313 3298 -10369 10564 17625 14872 -3954 19387 4028 5 15939 12753 22347 -10466 7721 2535 -2158 -8076 -6329 -20615 4575 -12020 375 1849 -1874 -13909 -19162 3869 22725 -569 10785 46 10459 5786 10594 -1574 25333 -1877 -10979 -2614 -12641 16037 -16216 11225 -18146 14550 -17929 11293 -3126 13438 -765 27500 -9975 622 337 -2621 8905 7241 -10181 1415 11299 -18378 10700 -10482 20811 13766 -6534 -2358 21633 -17554 -444 -17714 -9304 8808 881 17396 -7678 20138 8349 17183 -15159 25555 2422 19164 -1371 12928 -38312 -4375 -13175 2474 2245 9818 -4298 -29972 3767 -16047 12753 -7351 26391 1725 8217 15 -18794 11046 -3040 14935 6544 9854 7153 9110 -10193 22224 -25360 1694 -2797 16647 874 14852 -12875 -417 -9274 5447 -24019 2769 12994 18276 12749 -5783 9562 -18888 19448 -22450 17494 -19610 -5700 -3964 1268 6821 -12159 10062 -5340 7788 15371 26722 -34 -1254 -12676 19244 -2758 10634 289 2952 -10426 8517 13104 11251 -3601 14360 3527 4 12688 10517 16756 -10759 6709 2330 -2057 -8037 -6022 -22018 3778 -11700 SO 20180421T025607.0Z 6685.122303 3 1 32.00 2 89.68 66.29 100.34 0.19 0.00 1 0.00 1 0 15 1.041e-01 9.896e-02 1.083e-01 1.047e-01 2.315130e+03 6.326948e+03 3.841948e+02 -6.000000e+00 5.563673e+03 268.20 -2.00 20.00 -2.00 505.19 0.00e+00 -3.239349e-03 2.806494e-03 2.546982e-04 -6.000000e+00 2.856346e-03 268.20 -2.00 20.00 -2.00 499.82 0.00e+00 2.341107e+00 2.171731e+00 3.755635e-02 -6.000000e+00 2.110779e+00 228.33 -2.00 4.26 -2.00 501.48 0.00e+00 20.256 0.216 489.00 513.00 1 1.1581e+00 1.6491e-01 4.2292e-02 -6.0000e+00 1.6086e-01 1.5209e-01 4.3624e-02 2.3420e-03 -6.0000e+00 4.2045e-02 3.0969e-02 -1.0495e-02 9.6253e-03 8.3725e-05 -6.0000e+00 1.0014e-02 9.6574e-03 -1.5640e-04 12 8 8 10 0 0 -854.93 18.00 6.07 0.00966 -0.06314 8 2 1 5 0 4000.000 20.87 15.11 18.00 -4262 -4719 4623 3194 10970 -1698 -9358 2654 -4135 6134 -4741 9266 -9980 6682 -11831 5827 10816 -5190 18926 -4451 7657 3951 18803 -13662 14092 -1165 14080 961 1302 -8781 3141 8067 -3262 -8958 2049 5316 9816 8794 -20888 9762 997 1444 -659 -1588 -2569 -8848 -7285 9665 -4446 -8405 32327 8621 -8534 9867 6349 -14059 7270 -6910 -4551 -6099 4430 -5086 3200 -8181 -7898 9282 -1644 20980 15721 17661 11015 8901 -6561 4915 14655 4161 -7574 14239 -21538 6588 945 4891 7593 -15225 11105 -2295 -4022 -1789 16264 -14906 14369 2563 -8325 -1044 18017 8572 -2697 5721 9712 -17933 -6752 -6478 24689 -4741 4173 -6324 2439 -4888 -10374 4317 -15594 15187 -1015 15949 -634 14879 3958 -2220 10515 -5540 12622 -4559 14182 -667 -58 -7384 15842 3193 -5769 -3563 19996 -15218 6249 -9382 -6104 17494 7058 -9607 12444 1861 4378 -19396 -9610 10652 877 4090 -1554 18454 -8283 21186 -4433 -4969 4556 3275 10792 -1921 -11557 2976 -4946 6634 -5596 9472 -12116 6831 -14303 5946 10616 -6069 18064 -5433 8329 4461 18290 -18250 14418 -1378 14347 1100 1458 -10544 3251 7948 -3615 -10758 2302 5878 10329 9225 -28836 9866 1083 1559 -730 -1789 -2945 -10745 -8737 9665 -5034 -9607 24261 7879 -9042 8643 5855 -16265 7035 -7750 -4985 -6746 4388 -5547 3225 -9170 -8782 8644 -1665 16937 13106 14259 9382 7698 -6606 4473 12374 3882 -7830 11672 -24439 5647 857 4292 6539 -16477 9410 -2234 -4012 -1748 13372 -16483 11987 2423 -8818 -1044 14798 7601 -2598 4985 7930 -18738 -6222 -5980 17247 -4597 3849 -6546 2303 -4885 -10764 3838 -16892 12437 -981 13214 -618 12433 3704 -2205 9263 -5629 10598 -4432 11366 -614 -53 -7335 12557 2842 -5551 -3351 14955 -15918 5226 -8961 -5596 12822 5808 -9495 10132 1707 3956 -22032 -10029 9207 834 3769 -1502 14419 -8125 15443 SO 20180421T025801.0Z 6685.123623 5 1 32.00 2 89.46 66.70 100.34 0.62 0.00 1 0.00 1 0 26 1.086e-01 1.007e-01 9.532e-02 9.199e-02 1.179789e+03 5.548888e+03 2.772365e+02 -6.000000e+00 5.803195e+03 268.20 -2.00 20.00 -2.00 505.23 0.00e+00 2.838514e-03 2.478490e-03 1.407727e-04 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