File name: Pandora105s1_Helsinki_20180424_L2Fit_fwvt1c2d20180411p1-8.txt File generation date: 20251122T161509.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20180411.txt Level 1 file used: Pandora105s1_Helsinki_20180424_L1_smca1c2d20180411p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20180424 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1767 Nominal wavelengths inside fitting window [nm]: 492.0970 492.2178 492.3385 492.4593 492.5800 492.7007 492.8214 492.9421 493.0628 493.1834 493.3041 493.4247 493.5453 493.6659 493.7864 493.9070 494.0275 494.1480 494.2685 494.3890 494.5094 494.6299 494.7503 494.8707 494.9911 495.1115 495.2318 495.3522 495.4725 495.5928 495.7131 495.8334 495.9536 496.0738 496.1941 496.3143 496.4345 496.5546 496.6748 496.7949 496.9150 497.0351 497.1552 497.2753 497.3953 497.5153 497.6353 497.7553 497.8753 497.9953 498.1152 498.2351 498.3550 498.4749 498.5948 498.7147 498.8345 498.9543 499.0741 499.1939 499.3137 499.4334 499.5532 499.6729 499.7926 499.9123 500.0319 500.1516 500.2712 500.3908 500.5104 500.6300 500.7495 500.8691 500.9886 501.1081 501.2276 501.3471 501.4665 501.5859 501.7054 501.8248 501.9442 502.0635 502.1829 502.3022 502.4215 502.5408 502.6601 502.7793 502.8986 503.0178 503.1370 503.2562 503.3754 503.4945 503.6137 503.7328 503.8519 503.9710 504.0901 504.2091 504.3281 504.4472 504.5662 504.6851 504.8041 504.9230 505.0420 505.1609 505.2798 505.3986 505.5175 505.6363 505.7552 505.8740 505.9928 506.1115 506.2303 506.3490 506.4677 506.5864 506.7051 506.8238 506.9424 507.0610 507.1797 507.2983 507.4168 507.5354 507.6539 507.7725 507.8910 508.0094 508.1279 508.2464 508.3648 508.4832 508.6016 508.7200 508.8384 508.9567 509.0750 509.1934 509.3117 509.4299 509.5482 509.6664 509.7847 509.9029 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180424T024537.0Z 6688.115012 1 1 32.00 2 89.91 63.67 97.39 317.85 0.00 1 0.00 1 0 77 8.667e-01 4.985e-01 6.695e-01 4.576e-01 5.201983e+03 3.319817e+04 3.194820e+03 -6.000000e+00 4.643591e+04 268.72 -2.00 20.00 -2.00 505.02 0.00e+00 -1.944009e-02 1.259961e-02 2.798309e-04 -6.000000e+00 2.383277e-02 268.72 -2.00 20.00 -2.00 499.22 0.00e+00 2.750004e+00 1.023373e+01 2.598374e-01 -6.000000e+00 1.752837e+01 228.71 -2.00 4.26 -2.00 500.99 0.00e+00 20.572 0.226 489.00 513.00 1 2.7336e+00 7.8151e-01 4.8885e-02 -6.0000e+00 1.3370e+00 2.4111e-01 2.0667e-01 6.5456e-03 -6.0000e+00 3.4839e-01 5.8291e-03 -5.5034e-02 3.6701e-02 9.1762e-04 -6.0000e+00 8.4341e-02 8.5449e-02 -3.0872e-04 12 9 8 11 8 0 -52.18 17.82 30.32 0.08545 -0.29629 8 2 1 5 0 4000.000 20.77 14.96 17.82 184570 -20764 203450 4266 900000 -33683 146595 50363 25451 49648 55792 39630 92048 -19020 59815 -3671 79252 29764 122414 169049 -13449 96886 -61271 78214 -20775 67493 27403 79006 35211 87438 7796 19477 -4161 38766 47193 -7143 -5212 -24527 130295 -16410 136478 51509 257292 27088 94125 28479 41701 -25021 -22718 22989 27292 -32047 63410 27993 3584 21257 20273 8861 18525 24126 9701 -15858 95396 40107 -55510 80593 51019 85726 77504 -19257 341396 -51224 110962 51863 41690 -6648 2679 7916 42244 2710 -37995 85095 47875 -14730 93017 238106 -29384 116403 119210 110383 -485 43843 17407 -25828 -36220 -32081 -4081 40876 16820 222493 154086 -57697 37086 171573 87986 70779 124943 89793 181485 35135 46208 23981 85737 -44475 6411 42455 -31255 39830 26926 -30106 -4450 77922 5641 15388 22927 192920 -11505 112844 -39067 38356 -10283 -35951 15366 32166 -20038 35622 38759 -20258 10232 30646 334279 121459 72152 44413 -21741 161777 3424 -40470 53064 50451 82749 -32582 91213 5165 900000 -61546 65723 42999 27990 44133 47223 39517 55024 -32617 47855 -5339 51597 31250 54882 75790 -22963 58923 -171518 57737 -39490 55041 32315 56490 37860 56098 10544 22967 -5985 36528 41241 -10862 -7975 -45967 58415 -28030 61187 43838 115352 28064 50566 28540 36758 -41285 -36150 23298 25911 -52288 40092 23834 3736 18420 17873 8905 17303 21542 9967 -20455 42769 29767 -102759 40456 33638 40076 38608 -23778 153059 -83528 49748 30872 27644 -7085 2648 7538 28648 2599 -52752 38151 29039 -16322 41703 106750 -39309 52187 53446 49488 -517 30703 15800 -35294 -54952 -46370 -4397 27867 13969 99751 69082 -90535 23360 76921 39447 35964 56016 41599 81366 27278 31584 19842 38759 -69553 6142 28318 -41706 26713 20347 -39536 -4613 36379 5159 12574 16994 86492 -11667 50591 -51303 23767 -10025 -44673 11574 20468 -20656 21251 22282 -20667 8000 20115 149868 54454 33663 27239 -25511 72530 3203 -57503 30642 29495 SO 20180424T024735.0Z 6688.116377 3 1 31.99 2 89.69 64.10 97.55 318.28 0.00 1 0.00 1 0 82 8.920e-01 4.530e-01 5.914e-01 4.116e-01 -7.217860e+04 2.214673e+04 3.718482e+03 -6.000000e+00 4.899692e+04 268.72 -2.00 20.00 -2.00 505.29 0.00e+00 1.321968e-02 1.130748e-02 4.923169e-04 -6.000000e+00 2.453328e-02 268.72 -2.00 20.00 -2.00 499.90 0.00e+00 2.476823e+01 9.255593e+00 7.306867e-01 -6.000000e+00 1.823190e+01 228.71 -2.00 4.26 -2.00 501.69 0.00e+00 20.254 0.216 489.00 513.00 1 7.5176e-01 7.1202e-01 7.3623e-02 -6.0000e+00 1.3868e+00 -1.6975e-01 1.7519e-01 1.5626e-02 -6.0000e+00 3.6462e-01 6.6618e-03 -2.8623e-02 1.6252e-02 4.1012e-04 -6.0000e+00 8.8217e-02 9.4397e-02 -1.0832e-03 12 9 8 11 8 0 73.21 17.84 12.21 0.09440 -0.10415 8 2 1 5 0 4000.000 20.77 14.93 17.84 123443 24687 -32468 -26936 75967 108338 -19859 -10625 -2891 -9903 68165 14341 8444 86463 33399 49727 -30173 -4410 -18385 -9783 -11393 14058 -21656 31041 19306 3127 71582 -17391 118025 -2958 57939 -38989 13355 8711 356282 -22725 34185 72953 17845 37473 -28850 38907 -17464 127967 29556 127265 -5948 376175 30594 2763 36246 67946 104536 21581 33994 60497 -27102 76827 235268 29881 -1083 25314 27295 2406 207041 -54517 21446 19140 89705 -16133 126972 -34216 19738 -7288 108556 23074 -9790 51371 -2068 29156 1003 192617 -71351 52847 -19610 11308 35336 36348 19861 231818 54361 42760 41544 24976 109128 -11298 28727 21922 58385 -28681 270759 75784 900000 -12248 26087 -31651 193747 4507 -5222 -17604 8968 -6744 63013 76149 -43289 29462 -15172 -3395 5260 325671 16951 23277 43757 163503 50663 55579 37275 -23758 20183 10091 164269 47033 1039 -37456 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12068 -11607 37384 -75584 10520 SO 20180424T024930.0Z 6688.117708 5 1 32.00 2 89.47 64.51 97.71 318.70 0.00 1 0.00 1 0 61 5.213e-01 3.096e-01 4.439e-01 3.233e-01 -6.432827e+03 1.875092e+04 1.514277e+03 -6.000000e+00 2.793009e+04 268.72 -2.00 20.00 -2.00 505.22 0.00e+00 -1.013947e-04 8.901861e-03 9.829078e-05 -6.000000e+00 1.435338e-02 268.72 -2.00 20.00 -2.00 499.84 0.00e+00 7.734883e+00 6.657403e+00 1.759360e-01 -6.000000e+00 1.063465e+01 228.71 -2.00 4.26 -2.00 501.52 0.00e+00 19.871 0.204 489.00 513.00 1 1.8664e+00 5.1263e-01 4.1989e-02 -6.0000e+00 8.0991e-01 2.5526e-02 1.2826e-01 2.8376e-03 -6.0000e+00 2.1317e-01 9.0665e-03 2.0505e-02 2.9330e-02 1.6742e-04 -6.0000e+00 5.0844e-02 4.0815e-02 -7.9678e-04 12 8 8 10 0 0 93.27 17.85 13.95 0.04082 0.18304 8 2 1 5 0 4000.000 20.77 15.15 17.85 28973 33997 13867 21949 -32091 40768 -37214 2782 -10803 28114 57673 60163 -10483 9203 -14082 -22585 31822 53174 16384 -31206 57510 4712 108532 5696 43472 3624 20700 -5560 65765 43425 35459 13031 18141 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