File name: Pandora105s1_Helsinki_20180425_L2Fit_fwvt1c2d20180411p1-8.txt File generation date: 20251122T161532.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20180411.txt Level 1 file used: Pandora105s1_Helsinki_20180425_L1_smca1c2d20180411p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20180425 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1767 Nominal wavelengths inside fitting window [nm]: 492.0970 492.2178 492.3385 492.4593 492.5800 492.7007 492.8214 492.9421 493.0628 493.1834 493.3041 493.4247 493.5453 493.6659 493.7864 493.9070 494.0275 494.1480 494.2685 494.3890 494.5094 494.6299 494.7503 494.8707 494.9911 495.1115 495.2318 495.3522 495.4725 495.5928 495.7131 495.8334 495.9536 496.0738 496.1941 496.3143 496.4345 496.5546 496.6748 496.7949 496.9150 497.0351 497.1552 497.2753 497.3953 497.5153 497.6353 497.7553 497.8753 497.9953 498.1152 498.2351 498.3550 498.4749 498.5948 498.7147 498.8345 498.9543 499.0741 499.1939 499.3137 499.4334 499.5532 499.6729 499.7926 499.9123 500.0319 500.1516 500.2712 500.3908 500.5104 500.6300 500.7495 500.8691 500.9886 501.1081 501.2276 501.3471 501.4665 501.5859 501.7054 501.8248 501.9442 502.0635 502.1829 502.3022 502.4215 502.5408 502.6601 502.7793 502.8986 503.0178 503.1370 503.2562 503.3754 503.4945 503.6137 503.7328 503.8519 503.9710 504.0901 504.2091 504.3281 504.4472 504.5662 504.6851 504.8041 504.9230 505.0420 505.1609 505.2798 505.3986 505.5175 505.6363 505.7552 505.8740 505.9928 506.1115 506.2303 506.3490 506.4677 506.5864 506.7051 506.8238 506.9424 507.0610 507.1797 507.2983 507.4168 507.5354 507.6539 507.7725 507.8910 508.0094 508.1279 508.2464 508.3648 508.4832 508.6016 508.7200 508.8384 508.9567 509.0750 509.1934 509.3117 509.4299 509.5482 509.6664 509.7847 509.9029 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180425T024248.0Z 6689.113056 1 1 32.00 2 89.91 62.95 95.67 304.26 0.00 1 0.00 1 0 39 3.240e-01 2.213e-01 2.851e-01 2.350e-01 -1.312664e+04 1.348782e+04 1.182428e+02 -6.000000e+00 1.738826e+04 268.89 -2.00 20.00 -2.00 505.11 0.00e+00 2.279213e-03 6.275996e-03 3.120697e-04 -6.000000e+00 8.914260e-03 268.89 -2.00 20.00 -2.00 499.58 0.00e+00 9.067980e+00 5.159059e+00 3.560925e-01 -6.000000e+00 6.594320e+00 228.84 -2.00 4.26 -2.00 501.26 0.00e+00 20.569 0.226 489.00 513.00 1 1.3654e+00 3.9403e-01 5.1377e-02 -6.0000e+00 5.0244e-01 5.2971e-02 1.0259e-01 6.2044e-03 -6.0000e+00 1.3169e-01 1.3015e-02 9.7714e-03 2.0772e-02 1.2021e-04 -6.0000e+00 3.0975e-02 -5.8353e-02 7.3354e-05 12 9 8 11 8 0 74.27 17.93 10.44 -0.05835 0.00943 8 2 1 5 0 4000.000 20.87 14.88 17.93 36061 3562 -3248 10684 -17120 34588 -7063 64126 177 8415 8456 32870 47519 -2776 -20100 23919 -10133 -20971 31946 3150 51319 -3505 -29794 -14915 5082 -2809 11355 -3243 43193 -15943 11308 23332 1294 37824 -9659 -534 -304 881 -23346 12508 5159 110702 27179 3837 20204 36687 9898 -13725 68983 -14040 5382 -36412 29093 -2398 52326 -265 -6871 -8980 3312 -15841 5588 30935 3970 21837 -33432 -19616 70585 8770 5227 8272 2596 -14306 -17922 7551 1292 6173 15979 64067 7056 -24570 41135 40405 27316 16555 -11843 115 19114 19746 22030 -25502 -10013 -11084 9813 23749 61505 6923 -9817 19771 -16420 36190 15158 -2258 -19743 -1826 24499 -11811 8167 35523 -2794 51286 3890 -3345 -31008 9688 -16085 35906 -21637 18294 4974 141688 19852 -26813 43319 -8072 81635 9549 33868 -15973 37305 -21759 88498 -9083 36519 -3729 13208 14459 18430 -5916 -9180 55268 10817 -32263 -6507 80085 19942 21387 80512 19340 -24431 76154 26687 3688 -3702 11020 -23459 29565 -9073 42029 214 9189 9103 27606 34312 -3202 -27278 21616 -12920 -30401 28323 3717 38036 -4387 -48251 -21115 5919 -3537 12447 -4016 33155 -20894 11342 20959 1480 31647 -12930 -651 -365 1031 -34121 12914 5746 45102 24727 4418 20022 31000 10636 -18224 40849 -17782 5482 -54067 22790 -2586 34157 -293 -8243 -11007 3567 -20370 5843 25368 4225 19461 -49798 -25152 37521 8241 5009 7558 2483 -16077 -20898 7012 1269 5732 13146 32799 6185 -29054 26166 25795 19733 13343 -12532 110 15121 15424 16884 -31121 -10632 -11998 8860 19119 34890 6668 -11054 16333 -18611 24201 12300 -2178 -22874 -1801 18537 -12325 6896 22578 -2553 28287 3442 -3250 -40575 8766 -18778 25593 -26370 15060 4555 34803 15515 -32725 27314 -8400 36234 8452 23705 -17996 25366 -26210 36979 -9476 24236 -3553 10657 11693 14706 -6120 -9876 32369 9657 -43733 -6932 37763 16744 17579 36934 15382 -29025 34656 SO 20180425T024447.0Z 6689.114433 3 1 31.99 2 89.69 63.38 95.87 304.69 0.00 1 0.00 1 0 47 2.989e-01 2.061e-01 2.836e-01 2.407e-01 1.412106e+04 1.785912e+04 2.837244e+02 -6.000000e+00 1.601275e+04 268.89 -2.00 20.00 -2.00 505.18 0.00e+00 4.477535e-03 6.480046e-03 2.800734e-04 -6.000000e+00 8.283315e-03 268.89 -2.00 20.00 -2.00 499.48 0.00e+00 9.439818e-01 5.194900e+00 2.049276e-01 -6.000000e+00 6.160433e+00 228.84 -2.00 4.26 -2.00 501.17 0.00e+00 20.251 0.216 489.00 513.00 1 1.9605e+00 3.9347e-01 4.5078e-02 -6.0000e+00 4.6709e-01 1.7704e-01 1.0427e-01 4.0887e-03 -6.0000e+00 1.2603e-01 1.2724e-02 9.4716e-03 2.1012e-02 7.1676e-05 -6.0000e+00 2.8600e-02 2.8199e-01 -3.4784e-03 12 9 8 11 8 0 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-17479 -5225 -20719 5596 21510 24998 -6989 -39506 -3597 -6624 692 18067 -1872 -18187 -14773 -1259 16164 -18562 29104 15970 34237 32080 -28557 -9255 3507 -26197 9864 -22887 -18153 11532 -7710 468 10676 11768 18897 39451 24238 14994 3095 643 -1139 11294 -9659 19278 -14054 -20517 38969 17733 11292 23288 9743 13732 8548 -49971 14063 -11056 16406 -12844 -15179 35477 19743 8030 -1199 14208 5657 -10668 -9793 39548 2323 6753 5415 -22707 13375 33982 -29387 -15543 3419 8826 -22050 -10835 -11709 21481 16748 17844 35222 13 31081 -19539 8201 4943 38682 29189 34884 -22310 -5611 -19313 5727 6810 12640 24514 4996 28193 -43084 33605 -26314 7560 28120 -14375 -8732 2847 -6795 -9115 19666 19799 32741 -9790 24829 -16034 6324 15603 30594 -24275 -4324 26576 -14233 -19002 4471 21267 -13775 12343 -6623 17961 -27153 30167 954 22369 -23176 23311 -18470 9744 28196 -19134 -33259 37058 14567 10968 SO 20180425T024641.0Z 6689.115752 5 1 32.00 2 89.48 63.79 96.06 305.09 0.00 1 0.00 1 0 53 3.493e-01 2.303e-01 3.109e-01 2.503e-01 -1.592533e+04 1.470062e+04 2.562477e+02 -6.000000e+00 1.873769e+04 268.89 -2.00 20.00 -2.00 505.14 0.00e+00 4.670523e-03 6.664526e-03 2.904583e-04 -6.000000e+00 9.618412e-03 268.89 -2.00 20.00 -2.00 499.31 0.00e+00 6.741438e+00 5.476261e+00 2.370033e-01 -6.000000e+00 7.119881e+00 228.84 -2.00 4.26 -2.00 501.03 0.00e+00 19.874 0.204 489.00 513.00 1 1.6742e+00 4.1341e-01 4.4385e-02 -6.0000e+00 5.4233e-01 1.4793e-01 1.0961e-01 4.4510e-03 -6.0000e+00 1.4251e-01 1.2111e-02 2.1982e-02 2.1182e-02 3.3181e-05 -6.0000e+00 3.3838e-02 -1.2932e-01 3.4986e-04 12 9 8 11 8 0 95.03 17.96 13.32 -0.12932 0.02316 8 2 1 5 0 4000.000 20.87 14.90 17.96 23624 -5335 15792 15346 -7265 36682 -10455 -23610 12440 9154 253 3908 16853 23880 -16001 -22910 36813 19467 -4990 -4866 -21841 71536 13988 -5122 9501 -348 6065 -28476 5100 20964 -4171 -17844 42450 148 23137 2453 24234 740 880 -2257 36627 67947 -17910 16016 -3110 4425 36302 -13949 28624 -9949 8647 56131 -10713 194473 14246 -47859 -34249 41519 -903 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