File name: Pandora105s1_Helsinki_20180503_L2Fit_fwvt1c2d20180411p1-8.txt File generation date: 20251122T161546.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20180411.txt Level 1 file used: Pandora105s1_Helsinki_20180503_L1_smca1c2d20180411p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20180503 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1767 Nominal wavelengths inside fitting window [nm]: 492.0970 492.2178 492.3385 492.4593 492.5800 492.7007 492.8214 492.9421 493.0628 493.1834 493.3041 493.4247 493.5453 493.6659 493.7864 493.9070 494.0275 494.1480 494.2685 494.3890 494.5094 494.6299 494.7503 494.8707 494.9911 495.1115 495.2318 495.3522 495.4725 495.5928 495.7131 495.8334 495.9536 496.0738 496.1941 496.3143 496.4345 496.5546 496.6748 496.7949 496.9150 497.0351 497.1552 497.2753 497.3953 497.5153 497.6353 497.7553 497.8753 497.9953 498.1152 498.2351 498.3550 498.4749 498.5948 498.7147 498.8345 498.9543 499.0741 499.1939 499.3137 499.4334 499.5532 499.6729 499.7926 499.9123 500.0319 500.1516 500.2712 500.3908 500.5104 500.6300 500.7495 500.8691 500.9886 501.1081 501.2276 501.3471 501.4665 501.5859 501.7054 501.8248 501.9442 502.0635 502.1829 502.3022 502.4215 502.5408 502.6601 502.7793 502.8986 503.0178 503.1370 503.2562 503.3754 503.4945 503.6137 503.7328 503.8519 503.9710 504.0901 504.2091 504.3281 504.4472 504.5662 504.6851 504.8041 504.9230 505.0420 505.1609 505.2798 505.3986 505.5175 505.6363 505.7552 505.8740 505.9928 506.1115 506.2303 506.3490 506.4677 506.5864 506.7051 506.8238 506.9424 507.0610 507.1797 507.2983 507.4168 507.5354 507.6539 507.7725 507.8910 508.0094 508.1279 508.2464 508.3648 508.4832 508.6016 508.7200 508.8384 508.9567 509.0750 509.1934 509.3117 509.4299 509.5482 509.6664 509.7847 509.9029 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180503T022100.0Z 6697.097917 1 1 31.99 2 89.91 57.36 82.41 202.66 0.00 1 0.00 1 0 47 1.743e-01 1.560e-01 1.365e-01 1.275e-01 9.708023e+03 9.096679e+03 2.195670e+02 -6.000000e+00 9.370638e+03 270.26 -2.00 20.00 -2.00 505.15 0.00e+00 -1.075189e-03 3.441659e-03 1.547258e-04 -6.000000e+00 4.792534e-03 270.26 -2.00 20.00 -2.00 499.73 0.00e+00 1.566036e+00 2.734134e+00 1.197761e-01 -6.000000e+00 3.535069e+00 229.86 -2.00 4.26 -2.00 501.39 0.00e+00 20.535 0.225 489.00 513.00 1 1.3128e+00 2.0795e-01 4.4130e-02 -6.0000e+00 2.6930e-01 1.7256e-01 5.4784e-02 3.1226e-03 -6.0000e+00 7.0769e-02 2.5273e-02 -1.6773e-02 1.1507e-02 4.5796e-05 -6.0000e+00 1.6892e-02 9.4413e-01 -6.0781e-03 12 9 8 11 768 0 -23.50 20.50 16.18 0.94413 0.82779 8 2 1 5 0 4000.000 23.43 15.25 20.50 17437 26889 -13320 -704 -10749 27892 1100 6476 12268 27081 7930 -6861 28335 -6847 31953 -13105 9933 -22586 941 -27313 -16744 12480 9972 1460 -8324 5393 12637 -3004 -6821 16824 29948 22150 -6888 13147 22422 44694 -5360 12010 -16431 -4224 2909 9655 -4704 -6489 19963 -9421 10354 -7041 38811 12519 11262 -26919 -3854 -14447 23590 -15774 8832 -8649 11424 -662 -6056 14332 -13955 2505 10981 -2893 -5111 9209 -642 29338 -10339 24910 -21746 13137 10201 -10533 1790 13912 19081 -11374 8503 -11282 21436 -76 9388 5908 5701 -17236 -10577 -23699 30331 -14262 23914 -14194 -1654 3102 15438 30256 -22280 10789 -12527 11060 -4688 5239 10473 25281 10388 40389 -26724 27874 -1240 34142 10324 -2656 -1056 -4669 -3121 20076 13012 -14175 11626 -5058 -8370 9330 -7751 -8478 17021 8475 20180 -9457 3310 14563 787 -13496 -11692 14573 736 44597 -3226 15042 -22150 47317 10946 31579 -23632 45792 -10828 -1646 16355 998 15118 21565 -16217 -781 -13501 24471 1274 7187 12843 24370 8447 -8367 24164 -8062 25744 -16328 10046 -31911 1089 -42164 -23306 13061 10698 1709 -10695 6090 13212 -3611 -8336 15827 24267 19187 -8046 13110 21049 34265 -6567 12300 -21890 -4964 3168 9850 -5535 -7840 18830 -11860 10728 -8508 29632 12058 10668 -35660 -4000 -16481 19045 -19174 8685 -10182 11087 -715 -6879 13411 -17130 2631 10540 -3147 -5541 8576 -652 21956 -11178 19112 -26107 11447 9280 -11727 1736 11780 15068 -11975 7376 -11786 16506 -72 8235 5431 5284 -19772 -11387 -28734 21753 -15826 18621 -16037 -1645 2865 12197 20134 -24017 8242 -11807 8299 -4180 4419 8804 19068 9092 26122 -32518 19917 -1172 23304 8967 -2618 -1025 -4697 -3104 16124 11227 -15894 9998 -4991 -8363 7793 -7642 -8471 13307 7153 15219 -9422 2922 11409 696 -13447 -11342 10976 641 26022 -3048 12098 -25766 28376 9364 22260 -28401 28120 -11475 -1568 12825 887 SO 20180503T022259.0Z 6697.099294 3 1 31.99 2 89.70 57.79 82.50 203.11 0.00 1 0.00 1 0 39 1.510e-01 1.363e-01 1.210e-01 1.142e-01 5.165937e+03 7.659600e+03 1.901266e+02 -6.000000e+00 8.136453e+03 270.26 -2.00 20.00 -2.00 505.12 0.00e+00 2.636536e-03 3.084330e-03 1.494433e-04 -6.000000e+00 4.160520e-03 270.26 -2.00 20.00 -2.00 499.64 0.00e+00 2.920291e-01 2.429515e+00 6.787955e-02 -6.000000e+00 3.067662e+00 229.87 -2.00 4.26 -2.00 501.29 0.00e+00 20.240 0.215 489.00 513.00 1 1.2964e+00 1.8563e-01 4.2216e-02 -6.0000e+00 2.3376e-01 2.2141e-01 4.7698e-02 2.5891e-03 -6.0000e+00 6.1264e-02 2.8348e-02 1.2309e-02 1.0591e-02 4.5428e-05 -6.0000e+00 1.4411e-02 6.2874e-02 -5.9505e-04 12 8 8 10 0 0 99.47 20.52 9.75 0.06287 0.14826 8 2 1 5 0 4000.000 23.43 14.78 20.52 -8488 18930 -3290 5681 4976 -4602 -9468 -9015 20102 -11209 -9886 -8293 13724 2568 26582 583 44009 -5005 10817 -17024 33600 10351 4069 -13087 3399 21600 -9725 28249 -5898 9263 -9867 -3487 -3692 -3130 -15228 17338 4002 4058 -4438 19324 3955 -16279 1869 7579 32481 -4596 15039 -13474 17048 -13242 8656 -4565 -8797 -15499 16770 -5783 25839 16880 5036 908 -2357 22916 -9796 -2422 -15663 1534 -3018 18959 -868 -8693 1056 -2229 6575 11574 -5793 4624 -20 8434 10328 13604 -9712 7076 4703 -17441 14660 -19483 25316 -7057 23132 -11698 25124 -7552 6473 -5505 6078 18428 -20339 32960 -8194 -3845 13813 5894 7790 30690 -30068 -1341 35456 8981 3786 8208 -11739 30942 -25909 19591 -7705 11823 2783 16884 3442 4894 22208 -12989 27012 -1302 25428 -17836 5638 -8204 16700 14030 -5559 3198 -3979 23496 -10386 -4824 -9967 22838 -7780 26029 2620 -15379 -2273 -7136 -12626 11335 -3735 23536 -9328 23970 -9712 17115 -3810 6167 5543 -5739 -12417 -11748 19482 -14475 -12408 -10083 13300 2754 22583 638 32426 -6072 11353 -23419 28250 10882 4567 -17378 3864 20390 -12343 24372 -6805 9005 -11474 -3866 -4243 -3694 -20345 16720 4350 4353 -5091 17589 4221 -21313 2063 7990 27015 -5470 14652 -16903 15656 -15741 8094 -4783 -9544 -18383 14992 -6592 21897 15634 5186 972 -2618 20015 -11682 -2664 -19383 1582 -3182 15973 -873 -9325 1023 -2246 6145 10491 -6184 4370 -19 7399 8833 11341 -10109 6307 4317 -19827 12383 -22841 19199 -7302 17787 -12578 19186 -7996 6047 -5705 5535 14462 -22733 21396 -7724 -3417 10405 4924 6593 21537 -38333 -1283 23455 7577 3362 7061 -12434 21840 -32057 15680 -8001 10234 2633 13962 3192 4422 16548 -13475 18920 -1208 18269 -19437 4882 -8064 12976 11069 -5224 2720 -3551 16052 -9857 -4407 -9772 16478 -7584 18492 2343 -16376 -2129 -7028 -13082 9183 -3408 16056 -8637 16067 SO 20180503T022453.0Z 6697.100613 5 1 31.99 2 89.50 58.20 82.60 203.54 0.00 1 0.00 1 0 50 1.293e-01 1.166e-01 1.030e-01 9.856e-02 -6.726321e+02 5.714100e+03 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