File name: Pandora105s1_Helsinki_20180531_L2Fit_fwvt1c2d20180411p1-8.txt File generation date: 20251122T163437.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20180411.txt Level 1 file used: Pandora105s1_Helsinki_20180531_L1_smca1c2d20180411p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20180531 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1767 Nominal wavelengths inside fitting window [nm]: 492.0970 492.2178 492.3385 492.4593 492.5800 492.7007 492.8214 492.9421 493.0628 493.1834 493.3041 493.4247 493.5453 493.6659 493.7864 493.9070 494.0275 494.1480 494.2685 494.3890 494.5094 494.6299 494.7503 494.8707 494.9911 495.1115 495.2318 495.3522 495.4725 495.5928 495.7131 495.8334 495.9536 496.0738 496.1941 496.3143 496.4345 496.5546 496.6748 496.7949 496.9150 497.0351 497.1552 497.2753 497.3953 497.5153 497.6353 497.7553 497.8753 497.9953 498.1152 498.2351 498.3550 498.4749 498.5948 498.7147 498.8345 498.9543 499.0741 499.1939 499.3137 499.4334 499.5532 499.6729 499.7926 499.9123 500.0319 500.1516 500.2712 500.3908 500.5104 500.6300 500.7495 500.8691 500.9886 501.1081 501.2276 501.3471 501.4665 501.5859 501.7054 501.8248 501.9442 502.0635 502.1829 502.3022 502.4215 502.5408 502.6601 502.7793 502.8986 503.0178 503.1370 503.2562 503.3754 503.4945 503.6137 503.7328 503.8519 503.9710 504.0901 504.2091 504.3281 504.4472 504.5662 504.6851 504.8041 504.9230 505.0420 505.1609 505.2798 505.3986 505.5175 505.6363 505.7552 505.8740 505.9928 506.1115 506.2303 506.3490 506.4677 506.5864 506.7051 506.8238 506.9424 507.0610 507.1797 507.2983 507.4168 507.5354 507.6539 507.7725 507.8910 508.0094 508.1279 508.2464 508.3648 508.4832 508.6016 508.7200 508.8384 508.9567 509.0750 509.1934 509.3117 509.4299 509.5482 509.6664 509.7847 509.9029 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180531T012020.4Z 6725.055792 1 1 32.90 2 89.94 41.56 84.27 206.22 0.00 1 0.00 1 0 29 1.015e-02 9.844e-03 3.791e-04 3.758e-04 1.747498e+04 2.691918e+01 1.198375e+03 -6.000000e+00 5.579931e+02 275.01 -2.00 20.00 -2.00 505.51 0.00e+00 3.331413e-03 1.041378e-05 1.766096e-04 -6.000000e+00 2.824754e-04 275.01 -2.00 20.00 -2.00 501.29 0.00e+00 2.059522e+00 7.374492e-03 1.220109e-01 -6.000000e+00 2.057791e-01 232.92 -2.00 4.26 -2.00 502.75 0.00e+00 20.429 0.222 489.00 513.00 1 -6.3218e+00 5.6122e-04 4.4049e-02 -6.0000e+00 1.5708e-02 -8.6949e-02 1.4004e-04 3.8600e-03 -6.0000e+00 4.0949e-03 4.9486e+01 2.2139e-03 3.2067e-05 1.5979e-04 -6.0000e+00 9.7324e-04 2.8272e-03 4.1388e-05 12 8 8 10 0 0 21.75 18.77 4.60 0.00283 0.01818 139 30 1 5 0 236.670 21.58 15.00 18.77 -3609 -2411 -1313 -263 245 705 1198 1101 796 188 -328 -675 -1086 -1527 -1435 -1218 -349 143 779 708 603 479 752 898 1130 1103 720 65 -817 -1714 -1942 -964 -109 922 1321 1083 485 333 63 22 150 492 885 1151 1243 1065 977 441 -100 -877 -1694 -2255 -2023 -1361 -176 500 861 762 746 850 989 1302 1371 1188 787 496 -37 -302 -668 -876 -1153 -780 -281 30 -14 -379 -953 -1302 -1354 -1156 -864 -647 -294 -368 11 -49 -151 -81 343 373 998 1397 1601 1708 1289 1002 436 -495 -1332 -1866 -2257 -1535 -676 73 418 30 -675 -1041 -1192 -699 -261 226 609 812 1389 1611 1751 1513 927 141 -437 -375 19 334 749 641 438 423 202 -40 -152 -547 -1142 -1115 -1156 -855 -148 369 312 547 419 293 465 700 697 380 -272 -1111 -1662 -1678 -3098 -2010 -1127 -231 220 644 1108 1027 741 174 -302 -617 -986 -1383 -1300 -1113 -324 130 719 660 564 450 710 855 1082 1060 694 62 -768 -1581 -1784 -890 -104 900 1315 1035 462 330 62 22 143 473 861 1136 1240 1068 975 438 -98 -848 -1611 -2117 -1892 -1291 -171 498 873 778 762 868 1015 1344 1423 1183 814 507 -37 -304 -669 -870 -1145 -777 -283 31 -14 -386 -957 -1292 -1334 -1134 -849 -639 -292 -371 10 -48 -148 -79 331 360 967 1373 1585 1669 1279 960 406 -454 -1213 -1690 -2062 -1434 -660 71 426 31 -702 -1077 -1235 -732 -266 233 629 839 1433 1678 1862 1640 1013 153 -468 -394 20 351 793 685 471 456 219 -44 -165 -587 -1221 -1194 -1254 -910 -160 405 348 621 483 329 525 792 788 429 -305 -1237 -1841 -1869 SO 20180531T012205.5Z 6725.057008 3 1 32.98 2 89.80 41.94 84.36 206.61 0.00 1 0.00 1 0 29 9.453e-03 9.197e-03 3.530e-04 3.501e-04 1.726476e+04 2.495875e+01 1.189780e+03 -6.000000e+00 5.196853e+02 275.01 -2.00 20.00 -2.00 505.50 0.00e+00 3.177211e-03 9.739864e-06 1.708904e-04 -6.000000e+00 2.630666e-04 275.01 -2.00 20.00 -2.00 501.27 0.00e+00 2.056069e+00 6.876950e-03 1.193148e-01 -6.000000e+00 1.916777e-01 232.92 -2.00 4.26 -2.00 502.74 0.00e+00 20.242 0.216 489.00 513.00 1 -6.4298e+00 5.2398e-04 4.3206e-02 -6.0000e+00 1.4630e-02 -8.3332e-02 1.3046e-04 3.7954e-03 -6.0000e+00 3.8153e-03 5.6730e+01 2.2297e-03 2.9872e-05 1.5875e-04 -6.0000e+00 9.0613e-04 2.2500e-02 -9.4947e-05 12 8 8 10 0 0 -29.50 18.80 4.19 0.02250 0.03797 155 33 1 5 0 212.750 21.58 15.01 18.80 -3263 -2217 -1109 -173 390 657 1122 948 733 179 -258 -655 -1130 -1382 -1376 -1044 -417 214 595 665 421 520 618 829 1016 1053 721 50 -681 -1628 -1787 -1013 -58 837 1365 950 523 199 25 -73 170 478 822 1049 1215 1097 827 385 -132 -787 -1663 -2078 -1905 -1179 -221 502 806 784 646 789 832 1152 1271 1179 718 424 59 -321 -662 -949 -1036 -779 -229 -82 68 -321 -866 -1284 -1229 -1064 -773 -547 -283 -289 -101 -47 -244 -45 200 403 826 1305 1527 1659 1196 939 377 -472 -1213 -1802 -2018 -1525 -703 3 414 -77 -647 -960 -1067 -791 -275 139 544 739 1292 1500 1650 1394 923 105 -327 -287 -23 331 641 663 344 500 129 -3 -61 -457 -1105 -1039 -1059 -880 -41 344 351 487 431 235 416 569 675 436 -210 -1095 -1541 -1557 -2723 -1889 -973 -155 357 586 1015 865 667 162 -232 -585 -1002 -1221 -1217 -930 -378 199 564 634 404 500 598 808 997 1035 710 49 -653 -1534 -1675 -956 -56 800 1327 929 509 193 24 -70 165 469 817 1057 1236 1121 843 390 -132 -775 -1610 -1984 -1813 -1137 -219 509 798 781 644 786 833 1161 1288 1195 725 423 59 -315 -647 -920 -1044 -755 -225 -82 67 -318 -846 -1240 -1230 -1060 -771 -525 -274 -284 -100 -47 -244 -44 197 396 815 1305 1538 1649 1159 916 358 -441 -1122 -1659 -1869 -1448 -669 3 429 -78 -656 -967 -1076 -807 -285 145 570 776 1354 1587 1780 1475 984 111 -355 -306 -25 352 688 718 360 525 137 -3 -65 -477 -1150 -1082 -1118 -948 -45 382 397 538 483 268 475 652 773 498 -238 -1232 -1724 -1751 SO 20180531T012346.4Z 6725.058177 5 1 32.90 2 89.66 42.30 84.45 206.98 0.00 1 0.00 1 0 22 8.858e-03 8.634e-03 3.255e-04 3.229e-04 1.687034e+04 2.300659e+01 1.166888e+03 -6.000000e+00 4.869027e+02 275.01 -2.00 20.00 -2.00 505.50 0.00e+00 3.129041e-03 8.966246e-06 1.684431e-04 -6.000000e+00 2.465629e-04 275.01 -2.00 20.00 -2.00 501.29 0.00e+00 2.058973e+00 6.320209e-03 1.162438e-01 -6.000000e+00 1.795527e-01 232.92 -2.00 4.26 -2.00 502.74 0.00e+00 20.029 0.209 489.00 513.00 1 -6.5443e+00 4.8142e-04 4.2270e-02 -6.0000e+00 1.3707e-02 -7.9742e-02 1.1980e-04 3.7074e-03 -6.0000e+00 3.5735e-03 6.5592e+01 1.5339e-03 2.7807e-05 1.4954e-04 -6.0000e+00 8.4879e-04 2.4128e-02 -8.3859e-05 12 8 8 10 0 0 5.39 18.81 3.90 0.02413 0.03477 174 37 1 5 0 189.030 21.58 15.00 18.81 -3099 -2018 -1003 -85 328 711 1152 978 690 188 -357 -608 -1048 -1355 -1307 -962 -351 174 719 584 475 489 612 726 1008 955 690 4 -617 -1548 -1607 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