File name: Pandora105s1_Helsinki_20180609_L2Fit_fwvt1c2d20180411p1-8.txt File generation date: 20251122T163458.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20180411.txt Level 1 file used: Pandora105s1_Helsinki_20180609_L1_smca1c2d20180411p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20180609 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1767 Nominal wavelengths inside fitting window [nm]: 492.0970 492.2178 492.3385 492.4593 492.5800 492.7007 492.8214 492.9421 493.0628 493.1834 493.3041 493.4247 493.5453 493.6659 493.7864 493.9070 494.0275 494.1480 494.2685 494.3890 494.5094 494.6299 494.7503 494.8707 494.9911 495.1115 495.2318 495.3522 495.4725 495.5928 495.7131 495.8334 495.9536 496.0738 496.1941 496.3143 496.4345 496.5546 496.6748 496.7949 496.9150 497.0351 497.1552 497.2753 497.3953 497.5153 497.6353 497.7553 497.8753 497.9953 498.1152 498.2351 498.3550 498.4749 498.5948 498.7147 498.8345 498.9543 499.0741 499.1939 499.3137 499.4334 499.5532 499.6729 499.7926 499.9123 500.0319 500.1516 500.2712 500.3908 500.5104 500.6300 500.7495 500.8691 500.9886 501.1081 501.2276 501.3471 501.4665 501.5859 501.7054 501.8248 501.9442 502.0635 502.1829 502.3022 502.4215 502.5408 502.6601 502.7793 502.8986 503.0178 503.1370 503.2562 503.3754 503.4945 503.6137 503.7328 503.8519 503.9710 504.0901 504.2091 504.3281 504.4472 504.5662 504.6851 504.8041 504.9230 505.0420 505.1609 505.2798 505.3986 505.5175 505.6363 505.7552 505.8740 505.9928 506.1115 506.2303 506.3490 506.4677 506.5864 506.7051 506.8238 506.9424 507.0610 507.1797 507.2983 507.4168 507.5354 507.6539 507.7725 507.8910 508.0094 508.1279 508.2464 508.3648 508.4832 508.6016 508.7200 508.8384 508.9567 509.0750 509.1934 509.3117 509.4299 509.5482 509.6664 509.7847 509.9029 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180609T010946.5Z 6734.048455 1 1 33.06 2 89.95 38.58 82.65 101.64 0.00 1 0.00 1 0 29 1.018e-02 9.904e-03 4.363e-04 4.324e-04 1.670607e+04 3.083323e+01 1.137027e+03 -6.000000e+00 5.634102e+02 276.52 -2.00 20.00 -2.00 505.51 0.00e+00 3.580646e-03 1.203841e-05 1.895673e-04 -6.000000e+00 2.844442e-04 276.52 -2.00 20.00 -2.00 501.32 0.00e+00 2.172234e+00 8.480379e-03 1.199466e-01 -6.000000e+00 2.065749e-01 233.75 -2.00 4.26 -2.00 502.77 0.00e+00 20.386 0.220 489.00 513.00 1 -6.0606e+00 6.4595e-04 4.3819e-02 -6.0000e+00 1.5774e-02 -8.8343e-02 1.6089e-04 3.7706e-03 -6.0000e+00 4.1129e-03 3.8004e+01 1.0439e-03 3.7482e-05 1.4808e-04 -6.0000e+00 9.7797e-04 1.5493e-02 -7.9311e-05 12 8 8 10 0 0 36.41 21.75 4.89 0.01549 0.02273 105 22 1 5 0 314.860 24.65 14.90 21.75 -3703 -2530 -1473 -476 202 706 1156 1148 732 260 -264 -721 -1198 -1480 -1532 -1212 -506 227 643 676 627 541 776 812 1150 1110 866 224 -609 -1678 -1783 -1155 -121 891 1377 1117 641 272 88 128 180 551 880 1176 1318 1133 913 540 -166 -676 -1582 -2187 -1915 -1264 -272 485 905 892 734 874 1041 1235 1375 1178 846 507 234 -251 -637 -924 -1029 -803 -251 -200 46 -393 -910 -1310 -1347 -1202 -965 -643 -416 -334 -82 -92 -318 -66 208 341 896 1310 1469 1636 1287 977 653 -382 -1141 -1930 -2110 -1653 -726 -34 287 41 -599 -956 -1051 -804 -337 154 613 845 1418 1730 1817 1612 951 198 -380 -268 52 250 684 729 397 404 273 -25 -109 -360 -1067 -1198 -1170 -1059 -323 220 354 426 478 197 440 650 706 482 -194 -1084 -1739 -1690 -3122 -2171 -1302 -410 178 632 1050 1052 671 236 -238 -648 -1071 -1317 -1364 -1086 -460 212 610 648 603 523 718 759 1082 1048 819 210 -563 -1596 -1682 -1096 -112 852 1344 1096 627 264 85 124 176 544 879 1191 1291 1116 897 527 -168 -673 -1549 -2113 -1838 -1228 -271 474 900 894 738 877 1049 1254 1403 1205 861 511 233 -249 -628 -904 -1003 -785 -248 -200 46 -394 -899 -1279 -1305 -1160 -932 -624 -406 -329 -82 -93 -321 -66 207 337 890 1319 1495 1647 1264 928 602 -363 -1073 -1807 -1982 -1517 -694 -34 287 42 -611 -970 -1067 -825 -351 162 647 894 1498 1842 1893 1713 1022 212 -401 -289 55 269 711 764 420 429 291 -27 -117 -380 -1122 -1262 -1246 -1152 -357 247 388 474 539 226 506 750 815 555 -222 -1233 -1967 -1916 SO 20180609T011131.4Z 6734.049669 3 1 32.81 2 89.81 38.96 82.44 102.01 0.00 1 0.00 1 0 29 9.183e-03 8.925e-03 3.950e-04 3.919e-04 1.662766e+04 2.800809e+01 1.133061e+03 -6.000000e+00 5.082370e+02 276.52 -2.00 20.00 -2.00 505.50 0.00e+00 3.400873e-03 1.091171e-05 1.828789e-04 -6.000000e+00 2.566688e-04 276.52 -2.00 20.00 -2.00 501.25 0.00e+00 2.170153e+00 7.713778e-03 1.183155e-01 -6.000000e+00 1.863608e-01 233.75 -2.00 4.26 -2.00 502.72 0.00e+00 20.214 0.215 489.00 513.00 1 -6.2197e+00 5.8781e-04 4.3054e-02 -6.0000e+00 1.4233e-02 -8.2717e-02 1.4662e-04 3.7212e-03 -6.0000e+00 3.7100e-03 4.5748e+01 1.2264e-03 3.3889e-05 1.4904e-04 -6.0000e+00 8.8433e-04 -8.1082e-03 5.3330e-05 12 8 8 10 0 0 31.74 21.77 4.22 -0.00811 0.00040 121 26 1 5 0 271.170 24.65 15.01 21.77 -3307 -2229 -1264 -375 238 665 1041 1026 710 253 -280 -559 -998 -1373 -1365 -1132 -402 105 540 742 510 487 684 793 1018 1033 802 152 -620 -1414 -1721 -1089 -87 703 1139 1049 562 233 -5 25 112 490 698 1026 1104 975 854 504 -86 -696 -1438 -1986 -1787 -1307 -235 365 726 760 665 722 902 1063 1278 1076 856 434 134 -216 -520 -829 -984 -748 -295 -31 -1 -305 -848 -1128 -1285 -1017 -793 -642 -378 -286 -101 -95 -253 -61 238 310 914 1156 1295 1446 1211 876 567 -346 -1131 -1699 -1942 -1528 -726 -77 261 -88 -597 -819 -983 -786 -350 160 500 828 1282 1582 1650 1403 869 216 -289 -246 31 285 668 612 395 390 305 -52 -92 -423 -973 -1059 -969 -888 -227 252 310 425 410 212 309 585 617 413 -150 -954 -1550 -1620 -2763 -1897 -1108 -337 218 594 944 938 649 230 -253 -500 -888 -1216 -1209 -1010 -364 98 512 708 489 469 661 773 1000 1017 791 150 -598 -1335 -1614 -1028 -84 671 1110 1027 548 227 -5 24 109 481 694 1035 1126 1000 873 511 -86 -688 -1397 -1902 -1701 -1260 -232 370 719 759 664 721 904 1074 1297 1094 865 435 133 -212 -508 -804 -993 -726 -289 -31 -1 -303 -831 -1090 -1287 -1013 -792 -618 -366 -280 -100 -95 -253 -61 234 304 900 1155 1308 1446 1180 826 540 -325 -1051 -1569 -1800 -1447 -687 -76 269 -89 -604 -823 -988 -799 -361 166 524 868 1343 1669 1775 1481 926 229 -314 -262 33 303 716 661 413 410 321 -55 -97 -442 -1012 -1102 -1019 -953 -248 279 349 468 458 240 353 669 706 471 -170 -1072 -1730 -1816 SO 20180609T011312.5Z 6734.050839 5 1 32.98 2 89.68 39.32 82.24 102.37 0.00 1 0.00 1 0 29 8.112e-03 7.885e-03 3.350e-04 3.327e-04 1.651439e+04 2.384389e+01 1.123183e+03 -6.000000e+00 4.489290e+02 276.52 -2.00 20.00 -2.00 505.49 0.00e+00 3.222049e-03 9.224512e-06 1.749529e-04 -6.000000e+00 2.267539e-04 276.52 -2.00 20.00 -2.00 501.20 0.00e+00 2.139780e+00 6.558839e-03 1.162994e-01 -6.000000e+00 1.646687e-01 233.75 -2.00 4.26 -2.00 502.68 0.00e+00 20.018 0.208 489.00 513.00 1 -6.4832e+00 4.9906e-04 4.2198e-02 -6.0000e+00 1.2576e-02 -7.6601e-02 1.2511e-04 3.6518e-03 -6.0000e+00 3.2790e-03 6.1466e+01 1.2001e-03 2.8828e-05 1.4992e-04 -6.0000e+00 7.8052e-04 1.7225e-02 -1.2121e-04 12 8 8 10 0 0 87.36 21.77 3.59 0.01722 0.02555 156 33 1 5 0 211.420 24.65 15.22 21.77 -2815 -1883 -989 -227 307 623 1037 898 644 308 -182 -501 -927 -1172 -1189 -934 -326 93 508 701 419 481 609 644 890 959 718 69 -524 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