File name: Pandora105s1_Helsinki_20180703_L2Fit_fwvt1c2d20180411p1-8.txt File generation date: 20251122T163520.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20180411.txt Level 1 file used: Pandora105s1_Helsinki_20180703_L1_smca1c2d20180411p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20180703 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1767 Nominal wavelengths inside fitting window [nm]: 492.0970 492.2178 492.3385 492.4593 492.5800 492.7007 492.8214 492.9421 493.0628 493.1834 493.3041 493.4247 493.5453 493.6659 493.7864 493.9070 494.0275 494.1480 494.2685 494.3890 494.5094 494.6299 494.7503 494.8707 494.9911 495.1115 495.2318 495.3522 495.4725 495.5928 495.7131 495.8334 495.9536 496.0738 496.1941 496.3143 496.4345 496.5546 496.6748 496.7949 496.9150 497.0351 497.1552 497.2753 497.3953 497.5153 497.6353 497.7553 497.8753 497.9953 498.1152 498.2351 498.3550 498.4749 498.5948 498.7147 498.8345 498.9543 499.0741 499.1939 499.3137 499.4334 499.5532 499.6729 499.7926 499.9123 500.0319 500.1516 500.2712 500.3908 500.5104 500.6300 500.7495 500.8691 500.9886 501.1081 501.2276 501.3471 501.4665 501.5859 501.7054 501.8248 501.9442 502.0635 502.1829 502.3022 502.4215 502.5408 502.6601 502.7793 502.8986 503.0178 503.1370 503.2562 503.3754 503.4945 503.6137 503.7328 503.8519 503.9710 504.0901 504.2091 504.3281 504.4472 504.5662 504.6851 504.8041 504.9230 505.0420 505.1609 505.2798 505.3986 505.5175 505.6363 505.7552 505.8740 505.9928 506.1115 506.2303 506.3490 506.4677 506.5864 506.7051 506.8238 506.9424 507.0610 507.1797 507.2983 507.4168 507.5354 507.6539 507.7725 507.8910 508.0094 508.1279 508.2464 508.3648 508.4832 508.6016 508.7200 508.8384 508.9567 509.0750 509.1934 509.3117 509.4299 509.5482 509.6664 509.7847 509.9029 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180703T011411.0Z 6758.051516 1 1 32.00 2 89.94 38.43 74.11 167.65 0.00 1 0.00 1 0 54 4.563e-01 2.841e-01 3.637e-01 2.667e-01 -5.885780e+03 1.653383e+04 3.617546e+02 -6.000000e+00 2.551026e+04 279.34 -2.00 20.00 -2.00 505.15 0.00e+00 1.495468e-02 7.651474e-03 8.147003e-04 -6.000000e+00 1.291000e-02 279.34 -2.00 20.00 -2.00 499.62 0.00e+00 3.172356e+00 5.755749e+00 1.279390e-01 -6.000000e+00 9.370249e+00 234.64 -2.00 4.26 -2.00 501.29 0.00e+00 20.288 0.217 489.00 513.00 1 1.7202e+00 4.3979e-01 4.7073e-02 -6.0000e+00 7.1422e-01 1.7805e-01 1.1666e-01 2.7049e-03 -6.0000e+00 1.9004e-01 1.1472e-02 -2.5139e-02 2.3105e-02 2.0801e-04 -6.0000e+00 4.4220e-02 6.6162e-02 -1.3507e-03 12 8 8 10 0 0 93.98 18.66 21.32 0.06616 -0.10822 8 2 1 5 0 4000.000 21.48 15.00 18.66 900000 16421 15898 13881 101082 62805 27709 -18653 -327 -3912 -18232 23192 -1343 15727 -33699 -9631 26345 54682 -27337 11485 13195 -2984 67234 25893 7595 -25023 27287 -27911 14674 -10822 38264 -523 37710 1261 63747 -20970 -31086 59413 18092 1588 24307 43950 29230 3948 -26450 -7815 6115 21620 7444 46262 7145 9045 27089 -9885 -15280 277 -12219 64456 24286 18609 67487 -1170 92145 -10578 55063 -6171 152002 -46436 19460 51630 71445 -13521 26570 106789 -12042 33962 -9646 22351 51434 68814 -10441 47454 -15787 90246 -25712 21638 -34332 68732 15176 17534 -16211 34386 -4041 28399 5074 -12370 110815 -15954 118919 14252 118101 -23002 10268 17041 14308 -16144 75730 21514 25271 -11717 -11809 32624 82022 90194 -33964 45449 65866 -3319 -6902 32215 -32275 9163 -6002 42331 156091 48634 -3533 4617 71583 16045 16773 26084 143414 -48638 70393 -23180 38575 -19154 51489 9474 39348 -14149 41283 14199 -22799 -10161 32379 19917 26483 -158 900000 15645 14972 13529 44086 40947 25913 -27787 -416 -5135 -27436 23012 -1636 15954 -54118 -12060 23134 36317 -40097 11801 13587 -3615 41230 23505 8215 -37453 24890 -43510 15206 -14251 30654 -586 28404 1348 37644 -28905 -48593 39649 17811 1805 21988 32817 25243 4385 -40287 -10157 7040 21712 8553 36356 8058 9816 24130 -12224 -19637 308 -15599 40495 23056 18971 42982 -1442 46137 -14281 39734 -8021 42736 -86920 18941 36372 41030 -17293 22559 41613 -14798 26977 -11659 19871 33864 37574 -12110 31143 -18983 39162 -33849 17953 -48939 36352 13321 14914 -18873 24630 -4197 21782 4997 -14758 41150 -19992 40822 13208 39266 -28682 9048 13815 11925 -18187 35706 16861 18652 -12052 -12027 21780 35015 36588 -46977 29965 36477 -3603 -7799 24916 -45918 8602 -6405 28038 40776 30653 -3706 4498 36657 14114 14538 20815 37464 -78738 35610 -28104 25350 -21772 30079 8441 26581 -16055 27551 12183 -27794 -11023 23409 16169 20004 -149 SO 20180703T011610.0Z 6758.052894 3 1 32.00 2 89.78 38.86 74.05 168.14 0.00 1 0.00 1 0 19 3.731e-01 2.634e-01 3.468e-01 2.789e-01 1.800217e+04 2.337870e+04 1.306235e+03 -6.000000e+00 2.090119e+04 279.34 -2.00 20.00 -2.00 505.32 0.00e+00 2.564739e-03 7.812140e-03 3.294677e-04 -6.000000e+00 1.050877e-02 279.34 -2.00 20.00 -2.00 500.20 0.00e+00 1.235309e+00 5.917327e+00 1.279651e-01 -6.000000e+00 7.536656e+00 234.64 -2.00 4.26 -2.00 501.81 0.00e+00 20.091 0.211 489.00 513.00 1 2.0843e+00 4.5217e-01 4.3090e-02 -6.0000e+00 5.7674e-01 1.0627e-01 1.1085e-01 3.7336e-03 -6.0000e+00 1.4943e-01 1.1069e-02 -5.7988e-03 2.4563e-02 8.8020e-05 -6.0000e+00 3.6112e-02 5.0997e-02 8.7067e-04 12 8 8 10 0 0 90.45 18.69 15.23 0.05100 0.01077 8 2 1 5 0 4000.000 21.48 15.00 18.69 -11952 -10700 73436 -26766 -18488 21505 12455 8922 -13425 14554 20836 -19964 54866 7490 41939 6373 -13970 -12385 7347 3196 -11416 11278 28232 -3857 36181 17549 -18241 87834 -32990 67403 52052 34751 3455 19246 6739 19875 22815 -586 -30357 -857 18176 8320 5892 246 10866 30849 34818 45461 30321 -8359 -30440 127950 70403 -22232 -23701 -6979 -1982 -30942 -235 81136 -11834 36023 -4181 43187 23680 86454 25440 -33509 8746 46248 32632 2852 56186 2691 16411 34633 16815 -2730 9155 45177 64054 -9765 21126 2783 17709 -32435 -9618 -5582 -15438 -15955 12350 -20860 8711 11407 58959 84899 -25754 -1430 20617 21539 17140 114634 16799 -14166 84008 55782 -23226 42458 89350 17263 35233 46328 9571 -31220 39289 -28338 8432 -13471 13538 32062 9329 -47613 11757 36421 30427 52304 26808 90760 20261 -24728 25698 20446 -8712 21330 32559 43222 43455 64665 -34107 49606 10429 -8943 78476 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32.00 2 89.63 39.27 74.00 168.61 0.00 1 0.00 1 0 22 3.498e-01 2.545e-01 3.154e-01 2.597e-01 1.564832e+04 2.026845e+04 2.426887e+03 -6.000000e+00 1.956788e+04 279.34 -2.00 20.00 -2.00 505.26 0.00e+00 1.379868e-03 7.092792e-03 3.022155e-04 -6.000000e+00 9.850222e-03 279.34 -2.00 20.00 -2.00 499.98 0.00e+00 7.520009e-01 5.453685e+00 2.354813e-01 -6.000000e+00 7.079755e+00 234.64 -2.00 4.26 -2.00 501.62 0.00e+00 19.865 0.204 489.00 513.00 1 2.1067e+00 4.1619e-01 4.3644e-02 -6.0000e+00 5.4181e-01 1.5774e-01 1.0638e-01 2.7283e-03 -6.0000e+00 1.4056e-01 1.1952e-02 2.3919e-02 2.2612e-02 1.5344e-04 -6.0000e+00 3.3859e-02 -1.2898e-02 3.3663e-04 12 8 8 10 0 0 80.45 18.70 13.48 -0.01290 0.15302 8 2 1 5 0 4000.000 21.48 14.99 18.70 6532 34317 6521 68959 6230 -9890 32749 165815 78963 13614 -22318 91742 38027 9434 -10002 -12620 -10695 -15661 47910 -11387 -16991 -6503 -2156 22295 29596 -22755 43323 -15030 37339 45787 36151 24826 -7156 3446 -10321 -11129 28272 -132 24078 50065 -5388 -40363 -8384 21622 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