File name: Pandora105s1_Helsinki_20180705_L2Fit_fwvt1c2d20180411p1-8.txt File generation date: 20251122T163559.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20180411.txt Level 1 file used: Pandora105s1_Helsinki_20180705_L1_smca1c2d20180411p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20180705 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1767 Nominal wavelengths inside fitting window [nm]: 492.0970 492.2178 492.3385 492.4593 492.5800 492.7007 492.8214 492.9421 493.0628 493.1834 493.3041 493.4247 493.5453 493.6659 493.7864 493.9070 494.0275 494.1480 494.2685 494.3890 494.5094 494.6299 494.7503 494.8707 494.9911 495.1115 495.2318 495.3522 495.4725 495.5928 495.7131 495.8334 495.9536 496.0738 496.1941 496.3143 496.4345 496.5546 496.6748 496.7949 496.9150 497.0351 497.1552 497.2753 497.3953 497.5153 497.6353 497.7553 497.8753 497.9953 498.1152 498.2351 498.3550 498.4749 498.5948 498.7147 498.8345 498.9543 499.0741 499.1939 499.3137 499.4334 499.5532 499.6729 499.7926 499.9123 500.0319 500.1516 500.2712 500.3908 500.5104 500.6300 500.7495 500.8691 500.9886 501.1081 501.2276 501.3471 501.4665 501.5859 501.7054 501.8248 501.9442 502.0635 502.1829 502.3022 502.4215 502.5408 502.6601 502.7793 502.8986 503.0178 503.1370 503.2562 503.3754 503.4945 503.6137 503.7328 503.8519 503.9710 504.0901 504.2091 504.3281 504.4472 504.5662 504.6851 504.8041 504.9230 505.0420 505.1609 505.2798 505.3986 505.5175 505.6363 505.7552 505.8740 505.9928 506.1115 506.2303 506.3490 506.4677 506.5864 506.7051 506.8238 506.9424 507.0610 507.1797 507.2983 507.4168 507.5354 507.6539 507.7725 507.8910 508.0094 508.1279 508.2464 508.3648 508.4832 508.6016 508.7200 508.8384 508.9567 509.0750 509.1934 509.3117 509.4299 509.5482 509.6664 509.7847 509.9029 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180705T011633.0Z 6760.053160 1 1 32.00 2 89.94 38.92 70.55 144.78 0.00 1 0.00 1 0 33 9.937e-02 9.560e-02 5.500e-02 5.354e-02 1.438428e+04 4.083511e+03 9.658021e+02 -6.000000e+00 5.563160e+03 279.53 -2.00 20.00 -2.00 505.33 0.00e+00 2.087491e-03 1.472244e-03 1.263117e-04 -6.000000e+00 2.802123e-03 279.53 -2.00 20.00 -2.00 500.23 0.00e+00 2.562902e+00 1.104129e+00 7.958852e-02 -6.000000e+00 2.025108e+00 234.67 -2.00 4.26 -2.00 501.84 0.00e+00 20.289 0.217 489.00 513.00 1 3.1835e-01 8.3915e-02 4.2559e-02 -6.0000e+00 1.5471e-01 7.4035e-02 2.1378e-02 3.0871e-03 -6.0000e+00 4.0561e-02 6.3798e-02 8.2207e-03 4.7421e-03 9.9889e-05 -6.0000e+00 9.4974e-03 9.1830e-02 -9.0141e-04 12 9 9 12 12 4 24.62 30.77 9.89 0.09183 0.14885 8 2 1 5 0 4000.000 33.73 15.03 30.77 -12284 24015 15447 -469 4313 -6668 624 6092 -9740 2061 5486 -577 21774 6090 6382 8877 -13085 10992 -16995 3660 -19335 13415 8492 6474 -331 12248 -1639 -2280 -14941 1945 5284 -4117 12904 16567 4851 8050 498 20930 1686 -13857 -6874 834 -7272 -4203 5517 -1671 -4752 -318 -7379 16131 -734 3903 -1081 652 5028 -12989 1892 -3975 15254 2123 -15739 -666 -12819 -9398 1658 3538 4356 2762 -608 7123 4458 -97 13928 -98 12980 7810 16172 6080 -4161 14822 5233 12476 -8389 -12371 -10951 658 14346 1457 -10902 15676 -6239 11219 4362 137 -3462 7774 -15199 177 -2215 17978 5363 4903 1659 7074 -16480 -1857 -116 -4764 23474 14701 -15392 -2503 2830 2362 -2272 -6274 31472 -6634 -1856 -10409 -6571 5623 3477 -1478 -6001 7352 5796 10234 -4143 427 11998 2046 -12354 4990 4544 6269 -4176 5945 -19556 19015 -2307 10945 -230 -1719 -5318 -1101 26124 8609 -6541 85 -12877 18296 13192 -481 4309 -7586 670 6234 -11509 2150 5456 -598 17940 5813 6060 8293 -15420 10474 -21716 3859 -25467 12844 8569 6710 -366 12040 -1829 -2523 -18081 1943 5050 -4370 11909 15303 5149 8271 541 18476 1772 -16954 -7874 893 -8483 -4814 5826 -1882 -5474 -346 -8447 14332 -744 3722 -1068 643 4900 -15500 1997 -4432 14095 2213 -19664 -720 -15697 -11090 1732 3567 4284 2725 -613 6561 4184 -95 12069 -98 11570 7239 13489 5504 -4099 12114 4715 10511 -8633 -13379 -11813 636 12154 1384 -11627 12889 -6381 9770 4103 133 -3385 6546 -15452 151 -1901 12517 4203 3951 1436 6109 -18526 -1837 -112 -4719 17702 12125 -17302 -2504 2700 2266 -2287 -6575 23310 -7180 -1916 -11539 -6858 5128 3190 -1433 -6143 6619 5310 8964 -4160 413 10255 1887 -12984 4425 4047 5592 -4231 5540 -23690 16003 -2413 10183 -239 -1819 -5786 -1149 20605 7873 -6805 83 SO 20180705T011820.0Z 6760.054398 3 1 32.00 2 89.80 39.31 70.42 145.22 0.00 1 0.00 1 0 39 9.752e-02 8.959e-02 5.161e-02 5.014e-02 2.073547e+04 4.208147e+03 1.413223e+03 -6.000000e+00 5.461017e+03 279.53 -2.00 20.00 -2.00 505.34 0.00e+00 7.064219e-03 1.395391e-03 3.960378e-04 -6.000000e+00 2.751142e-03 279.53 -2.00 20.00 -2.00 500.08 0.00e+00 1.471814e+00 1.063553e+00 9.030178e-02 -6.000000e+00 1.985072e+00 234.67 -2.00 4.26 -2.00 501.70 0.00e+00 20.113 0.211 489.00 513.00 1 2.7560e-01 8.1375e-02 4.2931e-02 -6.0000e+00 1.5172e-01 1.1007e-01 2.0183e-02 3.2821e-03 -6.0000e+00 3.9689e-02 6.8297e-02 1.0733e-02 4.2903e-03 1.7226e-04 -6.0000e+00 9.3277e-03 -3.5082e-02 -3.5547e-05 12 9 9 12 4 4 96.91 30.79 13.06 -0.03508 0.03936 8 2 1 5 0 4000.000 33.73 15.00 30.79 4998 -10110 18041 8106 148 -9357 1627 -6567 2888 8103 -8486 -11129 4514 -5127 16893 -15485 9153 -7061 3298 408 4069 8723 911 344 -3648 -10354 2409 1534 4617 -8578 -10475 11396 13780 -3400 -1005 8302 942 -6412 5320 3538 3778 -9959 11710 7403 16331 -12963 10691 3169 1894 8775 -283 2463 684 -7869 1949 -6497 16112 907 -1975 -1705 21651 2459 -6951 2154 11222 -1186 -14091 10409 -15119 4649 7153 -4917 16305 -10285 15798 -4340 16605 2087 1408 -5621 -385 -5735 -4674 -1943 7670 -7128 -5817 2895 11218 -8861 25678 674 -282 -13457 4881 17857 -2485 3163 9502 7515 9446 459 -1938 885 -5555 1572 -227 4490 2708 1816 6683 2248 6748 -8957 -2607 -12782 -11315 -1651 13832 -2744 28094 19385 -685 -6038 773 -3382 8565 -7566 3934 -10709 -9913 -3054 2743 -8970 -8362 40825 2961 10958 3967 24844 -6431 14680 -11243 10826 -1814 -8785 -13165 419 7574 -1226 4584 -11029 15534 7879 160 -11184 1764 -7739 3063 8074 -9746 -12932 4421 -5474 14542 -18280 8674 -8007 3456 438 4202 8672 976 374 -4156 -12523 2573 1623 4587 -9432 -11552 10313 12581 -3793 -1114 8359 1009 -7316 5358 3631 3903 -11884 11519 7718 15722 -16489 10818 3385 2011 8479 -291 2421 683 -8667 2027 -7516 15233 994 -2223 -1911 19456 2675 -8268 2348 11026 -1287 -17106 9840 -18073 4533 6754 -5217 14252 -11777 14052 -4611 14091 1996 1341 -5706 -371 -5795 -4696 -1916 6929 -7477 -5975 2689 9472 -9050 19017 647 -274 -14583 4273 13138 -2158 2528 6991 5555 6852 374 -1688 790 -5433 1456 -211 3970 2422 1664 5944 2115 6092 -9395 -2572 -14114 -12564 -1690 12200 -2786 20579 15151 -646 -6045 731 -3327 7555 -7783 3635 -11351 -10301 -2909 2438 -8958 -8384 25879 2752 9525 3718 19296 -6852 12740 -12583 9777 -1837 -9442 -14526 399 6630 -1168 SO 20180705T012002.0Z 6760.055579 5 1 31.99 2 89.67 39.67 70.29 145.64 0.00 1 0.00 1 0 43 8.777e-02 8.636e-02 4.587e-02 4.478e-02 2.100877e+04 3.633316e+03 1.269370e+03 -6.000000e+00 4.912665e+03 279.53 -2.00 20.00 -2.00 505.32 0.00e+00 3.838309e-03 1.243158e-03 9.112167e-05 -6.000000e+00 2.479330e-03 279.53 -2.00 20.00 -2.00 500.07 0.00e+00 1.290864e+00 9.317922e-01 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