File name: Pandora105s1_Helsinki_20180812_L2Fit_fwvt1c2d20180411p1-8.txt File generation date: 20251122T165818.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20180411.txt Level 1 file used: Pandora105s1_Helsinki_20180812_L1_smca1c2d20180411p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20180812 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1767 Nominal wavelengths inside fitting window [nm]: 492.0970 492.2178 492.3385 492.4593 492.5800 492.7007 492.8214 492.9421 493.0628 493.1834 493.3041 493.4247 493.5453 493.6659 493.7864 493.9070 494.0275 494.1480 494.2685 494.3890 494.5094 494.6299 494.7503 494.8707 494.9911 495.1115 495.2318 495.3522 495.4725 495.5928 495.7131 495.8334 495.9536 496.0738 496.1941 496.3143 496.4345 496.5546 496.6748 496.7949 496.9150 497.0351 497.1552 497.2753 497.3953 497.5153 497.6353 497.7553 497.8753 497.9953 498.1152 498.2351 498.3550 498.4749 498.5948 498.7147 498.8345 498.9543 499.0741 499.1939 499.3137 499.4334 499.5532 499.6729 499.7926 499.9123 500.0319 500.1516 500.2712 500.3908 500.5104 500.6300 500.7495 500.8691 500.9886 501.1081 501.2276 501.3471 501.4665 501.5859 501.7054 501.8248 501.9442 502.0635 502.1829 502.3022 502.4215 502.5408 502.6601 502.7793 502.8986 503.0178 503.1370 503.2562 503.3754 503.4945 503.6137 503.7328 503.8519 503.9710 504.0901 504.2091 504.3281 504.4472 504.5662 504.6851 504.8041 504.9230 505.0420 505.1609 505.2798 505.3986 505.5175 505.6363 505.7552 505.8740 505.9928 506.1115 506.2303 506.3490 506.4677 506.5864 506.7051 506.8238 506.9424 507.0610 507.1797 507.2983 507.4168 507.5354 507.6539 507.7725 507.8910 508.0094 508.1279 508.2464 508.3648 508.4832 508.6016 508.7200 508.8384 508.9567 509.0750 509.1934 509.3117 509.4299 509.5482 509.6664 509.7847 509.9029 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180812T023427.0Z 6798.107257 1 1 32.00 2 89.91 58.77 96.24 50.32 0.00 1 0.00 1 0 66 6.458e-01 3.122e-01 3.617e-01 2.558e-01 5.137076e+04 2.237506e+04 2.552385e+03 -6.000000e+00 3.687938e+04 279.92 -2.00 20.00 -2.00 505.27 0.00e+00 -3.990428e-03 6.661330e-03 1.611182e-04 -6.000000e+00 1.832913e-02 279.92 -2.00 20.00 -2.00 500.11 0.00e+00 -5.948428e+00 5.052536e+00 2.359072e-01 -6.000000e+00 1.327930e+01 233.07 -2.00 4.26 -2.00 501.70 0.00e+00 20.258 0.216 489.00 513.00 1 2.5252e+00 3.7625e-01 4.6438e-02 -6.0000e+00 1.0124e+00 1.8179e-01 1.0136e-01 6.4381e-03 -6.0000e+00 2.6961e-01 1.1693e-02 3.7811e-02 1.6708e-02 9.2489e-05 -6.0000e+00 6.3470e-02 2.7487e-01 -2.6790e-03 12 9 8 11 12 0 83.63 25.28 30.65 0.27487 0.53714 8 2 1 5 0 4000.000 28.10 14.96 25.28 900000 24657 21106 26815 66711 -22481 52702 -8632 38837 24322 49097 32749 23985 15238 29405 -5455 -27707 -41847 -18819 5350 -9855 21787 20369 -17993 14697 20982 12065 20628 -5873 58646 -6069 36029 34167 57893 -18774 14313 18059 218740 30843 47585 5487 6775 -27039 121569 -8133 -24504 -3689 29021 99164 -5829 17513 -14939 41128 -45463 33089 17103 12468 -2014 20427 -23709 21727 -18879 47909 273748 9384 5655 -31624 42205 36467 8919 -22828 16127 49973 29269 111103 -34474 -17127 39143 273960 60194 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-20736 16509 31721 -34054 -17957 19028 26061 -10240 -12468 23855 4047 900000 10440 -25769 -33650 -9226 -39233 38454 -12641 33546 18973 5323 28622 36502 21853 26809 8240 39379 13222 18680 25707 4763 39512 -60779 37183 -24952 24688 -13108 900000 -33476 12935 14395 22087 16600 25172 -16320 13277 36513 -22287 18151 34466 42207 -65280 41424 1096 2026 39328 23529 SO 20180812T023626.1Z 6798.108635 3 1 32.15 2 89.70 59.20 96.07 50.75 0.00 1 0.00 1 0 15 3.540e-01 2.480e-01 2.275e-01 1.854e-01 4.241714e+04 1.787862e+04 4.231682e+03 -6.000000e+00 1.983492e+04 279.92 -2.00 20.00 -2.00 505.31 0.00e+00 6.494456e-05 5.155736e-03 1.192621e-04 -6.000000e+00 1.006941e-02 279.92 -2.00 20.00 -2.00 499.96 0.00e+00 2.403910e+00 3.962658e+00 1.373014e-01 -6.000000e+00 7.267633e+00 233.07 -2.00 4.26 -2.00 501.54 0.00e+00 19.971 0.207 489.00 513.00 1 1.6008e+00 2.9836e-01 4.1204e-02 -6.0000e+00 5.5320e-01 2.9632e-02 7.6763e-02 2.8718e-03 -6.0000e+00 1.4839e-01 1.6829e-02 1.2975e-02 1.2102e-02 1.2870e-04 -6.0000e+00 3.4076e-02 5.9842e-02 -1.8722e-03 12 9 8 11 4 0 47.42 25.32 7.34 0.05984 0.14984 8 2 1 5 0 4000.000 28.21 15.05 25.32 900000 40875 33823 765 -24430 25125 3619 7766 -6276 6376 -16852 81210 28815 -90 -14808 -7811 31565 -22059 -2098 87069 29318 39019 35282 107281 8153 3928 -5943 18660 17188 -34470 16426 -21699 27639 17430 15976 23762 -24797 -14560 450 23484 3996 30394 -1096 -5712 -4284 39864 -110 39889 -30617 -14669 -25060 54583 -1766 27309 -1212 -21638 13010 9840 10063 4011 65628 -22389 29193 -23211 19522 27304 -19175 -6415 71805 -3404 17216 11949 -4867 -29363 54947 81321 43014 6789 1904 24588 -6956 118160 15658 76453 43610 3091 -7545 -9442 17909 24860 -2800 14138 -32952 15458 14535 -12138 492 -2676 35249 16851 23028 48323 -27599 -18921 98017 -17592 26919 -30971 27773 16395 41428 -16421 -1309 -15907 34852 15137 -3243 -12917 -8205 24507 -5116 70245 -1521 26454 -18224 51649 12399 -19718 19135 66948 -29006 100470 3493 16407 29716 11443 30138 -14607 42501 -1307 80196 -8256 70570 -40988 72907 -16789 29982 46940 17459 29650 900000 26804 24418 784 -32735 21373 3868 8114 -7549 6795 -22205 41353 23902 -98 -18299 -8978 25084 -29839 -2415 43559 25747 31420 29289 44969 8886 4455 -7443 18364 16967 -54684 15432 -28957 23276 16582 15902 22642 -37618 -19899 524 21640 4414 26246 -1286 -7095 -5309 32584 -133 32426 -48153 -19483 -35728 35188 -1920 22141 -1300 -29103 12978 10266 10543 4453 40159 -31765 25487 -33562 18694 24158 -25944 -7564 39449 -3798 15560 11286 -5403 -41418 35216 40681 30748 6704 1927 19651 -7412 37917 13363 36994 29024 3090 -8416 -10706 15465 19639 -2855 12173 -45145 13371 12342 -12488 418 -2201 19569 10907 14021 23076 -28121 -18876 34732 -20213 21060 -42798 21688 14122 28145 -19686 -1366 -18892 25122 12937 -3316 -14962 -9412 20911 -5753 37569 -1556 20040 -21124 31026 10897 -23714 16031 35332 -38437 38251 3288 13526 21716 10137 22697 -17367 29682 -1403 40489 -9877 40658 -68935 41063 -22188 25234 33383 16289 24503 SO 20180812T023820.0Z 6798.109954 5 1 32.01 2 89.50 59.61 95.89 51.16 0.00 1 0.00 1 0 27 2.191e-01 1.806e-01 1.512e-01 1.375e-01 -4.481103e+03 8.659307e+03 3.960462e+02 -6.000000e+00 1.227386e+04 279.92 -2.00 20.00 -2.00 505.24 0.00e+00 3.150294e-03 3.872389e-03 2.322785e-04 -6.000000e+00 6.196410e-03 279.92 -2.00 20.00 -2.00 499.86 0.00e+00 8.318103e+00 2.918467e+00 8.156152e-02 -6.000000e+00 4.473043e+00 233.07 -2.00 4.26 -2.00 501.51 0.00e+00 19.631 0.197 489.00 513.00 1 9.7094e-01 2.2460e-01 3.9987e-02 -6.0000e+00 3.4119e-01 2.1151e-02 5.6680e-02 2.6965e-03 -6.0000e+00 9.0425e-02 2.3463e-02 1.1686e-02 1.2710e-02 9.4990e-05 -6.0000e+00 2.1111e-02 -1.4931e-02 -5.9100e-04 12 9 8 11 4 0 77.13 25.32 9.31 -0.01493 0.06612 8 2 1 5 0 4000.000 28.21 15.00 25.32 900000 8467 8564 24749 -14632 41419 -2644 9093 -11919 18952 2498 36606 8881 29487 -3262 -25476 2750 10598 15825 6183 -26140 12071 38163 -19278 11262 -25399 2792 -14426 16923 1847 7027 -6825 -2262 1839 12074 25725 17584 51975 -10593 11424 13364 27242 14822 -1702 -29293 5783 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