File name: Pandora105s1_Helsinki_20180826_L2Fit_fwvt1c2d20180411p1-8.txt File generation date: 20251122T165824.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20180411.txt Level 1 file used: Pandora105s1_Helsinki_20180826_L1_smca1c2d20180411p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20180826 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1767 Nominal wavelengths inside fitting window [nm]: 492.0970 492.2178 492.3385 492.4593 492.5800 492.7007 492.8214 492.9421 493.0628 493.1834 493.3041 493.4247 493.5453 493.6659 493.7864 493.9070 494.0275 494.1480 494.2685 494.3890 494.5094 494.6299 494.7503 494.8707 494.9911 495.1115 495.2318 495.3522 495.4725 495.5928 495.7131 495.8334 495.9536 496.0738 496.1941 496.3143 496.4345 496.5546 496.6748 496.7949 496.9150 497.0351 497.1552 497.2753 497.3953 497.5153 497.6353 497.7553 497.8753 497.9953 498.1152 498.2351 498.3550 498.4749 498.5948 498.7147 498.8345 498.9543 499.0741 499.1939 499.3137 499.4334 499.5532 499.6729 499.7926 499.9123 500.0319 500.1516 500.2712 500.3908 500.5104 500.6300 500.7495 500.8691 500.9886 501.1081 501.2276 501.3471 501.4665 501.5859 501.7054 501.8248 501.9442 502.0635 502.1829 502.3022 502.4215 502.5408 502.6601 502.7793 502.8986 503.0178 503.1370 503.2562 503.3754 503.4945 503.6137 503.7328 503.8519 503.9710 504.0901 504.2091 504.3281 504.4472 504.5662 504.6851 504.8041 504.9230 505.0420 505.1609 505.2798 505.3986 505.5175 505.6363 505.7552 505.8740 505.9928 506.1115 506.2303 506.3490 506.4677 506.5864 506.7051 506.8238 506.9424 507.0610 507.1797 507.2983 507.4168 507.5354 507.6539 507.7725 507.8910 508.0094 508.1279 508.2464 508.3648 508.4832 508.6016 508.7200 508.8384 508.9567 509.0750 509.1934 509.3117 509.4299 509.5482 509.6664 509.7847 509.9029 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180826T030746.0Z 6812.130394 1 1 32.01 2 89.91 68.77 95.41 249.89 0.00 1 0.00 1 0 50 1.122e-01 1.060e-01 9.663e-02 9.393e-02 1.947691e+04 7.454977e+03 1.847866e+03 -6.000000e+00 6.246035e+03 278.48 -2.00 20.00 -2.00 505.40 0.00e+00 1.687692e-03 2.578063e-03 5.679890e-05 -6.000000e+00 3.153761e-03 278.48 -2.00 20.00 -2.00 500.47 0.00e+00 1.881878e+00 1.889532e+00 2.321204e-02 -6.000000e+00 2.271022e+00 231.27 -2.00 4.26 -2.00 502.04 0.00e+00 20.301 0.217 489.00 513.00 1 9.5829e-01 1.4343e-01 4.2021e-02 -6.0000e+00 1.7354e-01 5.3185e-02 3.5915e-02 2.9059e-03 -6.0000e+00 4.5353e-02 3.5259e-02 2.5284e-02 7.8765e-03 1.1898e-04 -6.0000e+00 1.0750e-02 1.5437e-02 -2.5354e-04 12 8 8 10 0 0 81.78 20.93 13.28 0.01544 0.19082 8 2 1 5 0 4000.000 23.72 14.96 20.93 -3508 -8052 -3307 11586 5308 3523 19520 -9207 27632 1557 1910 -2734 20097 -9193 6054 3070 6727 -4457 -3810 5182 1762 3715 27256 -2802 6348 2278 11405 158 -6627 1417 30356 11306 -149 11029 4179 -4809 -3831 -24747 -12831 -902 -19656 -4444 -2340 -5020 9687 7102 1415 5087 -5235 -5722 -15735 -295 2300 -1114 -9393 4658 7134 18331 -8012 -8453 -11704 -10566 24649 13656 -13388 -5081 -4231 3332 2793 13865 2830 7929 2234 -4209 15315 -2309 33203 22392 5872 8191 13422 -11103 15146 -15943 15796 10634 -13684 1457 -281 -5228 1204 -1668 -5640 -3950 9875 17751 -5515 22810 -5663 -15301 1195 4421 -3811 1757 14175 6830 -13177 -17626 -12829 2275 610 4993 12760 2038 9509 111 5726 5652 9231 -5556 -1287 -5187 -9617 3105 -12766 -563 -5693 7172 11883 3284 -2464 8484 -24220 28581 -7922 9021 11525 4119 21543 -2258 11525 -3571 15636 -15148 -7444 3987 -999 16860 7629 7000 -3372 -8402 -3392 10473 5216 3580 16979 -10513 21873 1567 1892 -2780 16258 -9881 5647 3018 6562 -4962 -4205 5272 1843 3856 22515 -3117 6441 2396 10770 162 -7067 1385 22706 10496 -160 10859 4361 -5430 -4236 -33165 -15351 -963 -25382 -4991 -2606 -5785 9708 7241 1494 5080 -5646 -6027 -17954 -288 2228 -1154 -10802 4768 7145 16369 -9220 -9812 -14128 -12551 20841 12636 -15846 -5491 -4482 3235 2694 11909 2730 7364 2211 -4454 13242 -2311 23252 17173 5250 7173 11309 -11872 12706 -18346 13407 9470 -15285 1387 -272 -5359 1173 -1678 -5793 -3841 8006 12918 -4901 15130 -4902 -14561 1003 3798 -3739 1693 12205 6286 -14534 -20282 -14238 2204 606 4754 11222 1997 8738 113 5623 5555 8610 -5861 -1273 -5297 -10337 2966 -14264 -562 -5938 6630 10470 3122 -2422 7458 -29124 20826 -8435 8290 10496 4103 18313 -2449 10989 -3980 14400 -18795 -8486 4023 -1034 14535 7237 6739 SO 20180826T030944.0Z 6812.131759 3 1 32.01 2 89.68 69.19 95.62 250.30 0.00 1 0.00 1 0 15 5.003e-02 4.933e-02 4.218e-02 4.174e-02 1.995653e+04 3.272485e+03 1.307452e+03 -6.000000e+00 2.787320e+03 278.48 -2.00 20.00 -2.00 505.50 0.00e+00 3.277516e-03 1.168166e-03 1.958786e-04 -6.000000e+00 1.406576e-03 278.48 -2.00 20.00 -2.00 500.88 0.00e+00 1.745252e+00 8.365817e-01 1.319111e-01 -6.000000e+00 1.008749e+00 231.27 -2.00 4.26 -2.00 502.41 0.00e+00 19.982 0.207 489.00 513.00 1 1.5946e-01 6.3991e-02 4.2360e-02 -6.0000e+00 7.7197e-02 1.0116e-02 1.5693e-02 3.9749e-03 -6.0000e+00 2.0026e-02 8.2018e-02 5.7809e-03 3.4933e-03 1.3700e-04 -6.0000e+00 4.8377e-03 -8.9460e-03 2.8068e-04 12 8 8 10 0 0 74.47 20.96 5.67 -0.00895 0.03115 8 2 1 5 0 4000.000 23.72 15.08 20.96 -1913 -6692 1824 487 6827 2497 2017 -5183 5510 -4324 -2566 -4556 405 7199 2963 -5476 2905 -2420 1692 -3913 -208 6916 5340 -583 -55 -1250 766 5300 3726 8171 -11638 6617 -5701 -3152 -8223 960 1827 -123 4121 1639 2561 -503 5367 -4593 11168 -424 9044 -6251 -1629 -9322 -3982 -3749 -134 4886 -1813 3562 3381 1109 1856 4869 667 1586 741 5588 2013 6007 -10081 4840 -6750 8195 -2272 3356 -4820 3512 -4122 -7904 1975 -2265 -3859 1538 7735 -7701 5243 -1698 3797 -1908 -2898 -6138 2385 -397 677 -2497 -3709 13776 -3837 6606 -1944 60 -3423 6604 -2509 9484 -9192 7688 -5357 2651 6446 4114 -5640 5916 -3588 -6598 5712 88 -5044 3861 7536 8540 4307 1556 9616 -9928 2478 -5398 2183 -2532 -6468 6889 229 -3204 684 6277 -6371 -3839 -4908 3744 1187 5876 -3997 1915 -1571 1525 -653 1651 -574 -417 106 -4324 3310 1875 -1665 -6327 1644 458 6154 2399 1971 -5407 5152 -4362 -2514 -4497 376 6260 2675 -5456 2731 -2467 1668 -4093 -209 6568 5145 -602 -56 -1303 777 5037 3485 7144 -12319 6007 -6033 -3364 -9348 989 1847 -125 4011 1639 2562 -522 5371 -5107 10758 -454 8730 -6932 -1690 -10169 -4014 -3719 -128 4591 -1872 3579 3448 1157 1920 4891 704 1670 788 5632 2059 5855 -11299 4661 -7159 7466 -2278 3210 -5079 3446 -4319 -8449 1887 -2226 -3828 1442 6849 -7948 4800 -1688 3612 -1925 -2935 -6310 2253 -384 656 -2531 -3798 11631 -3681 5520 -1700 51 -2930 5115 -2143 7481 -9199 6903 -5599 2569 5959 3862 -5824 5576 -3749 -7157 5485 89 -5420 3856 7413 8416 4404 1603 8917 -10927 2409 -5736 2170 -2653 -7069 6590 235 -3386 686 5866 -6673 -3942 -5180 3709 1230 5900 -4470 2051 -1763 1672 -734 1815 -643 -462 114 -4782 3399 1972 SO 20180826T031139.0Z 6812.133090 5 1 32.01 2 89.46 69.61 95.84 250.70 0.00 1 0.00 1 0 22 4.723e-02 4.672e-02 4.246e-02 4.198e-02 1.892797e+04 3.288520e+03 1.332212e+03 -6.000000e+00 2.633671e+03 278.48 -2.00 20.00 -2.00 505.56 0.00e+00 -2.610303e-04 1.168166e-03 9.119977e-05 -6.000000e+00 1.326546e-03 278.48 -2.00 20.00 -2.00 500.82 0.00e+00 4.211749e+00 8.401249e-01 1.057848e-01 -6.000000e+00 9.506126e-01 231.27 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