File name: Pandora105s1_Helsinki_20180905_L2Fit_fwvt1c2d20180411p1-8.txt File generation date: 20251122T165715.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20180411.txt Level 1 file used: Pandora105s1_Helsinki_20180905_L1_smca1c2d20180411p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20180905 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1767 Nominal wavelengths inside fitting window [nm]: 492.0970 492.2178 492.3385 492.4593 492.5800 492.7007 492.8214 492.9421 493.0628 493.1834 493.3041 493.4247 493.5453 493.6659 493.7864 493.9070 494.0275 494.1480 494.2685 494.3890 494.5094 494.6299 494.7503 494.8707 494.9911 495.1115 495.2318 495.3522 495.4725 495.5928 495.7131 495.8334 495.9536 496.0738 496.1941 496.3143 496.4345 496.5546 496.6748 496.7949 496.9150 497.0351 497.1552 497.2753 497.3953 497.5153 497.6353 497.7553 497.8753 497.9953 498.1152 498.2351 498.3550 498.4749 498.5948 498.7147 498.8345 498.9543 499.0741 499.1939 499.3137 499.4334 499.5532 499.6729 499.7926 499.9123 500.0319 500.1516 500.2712 500.3908 500.5104 500.6300 500.7495 500.8691 500.9886 501.1081 501.2276 501.3471 501.4665 501.5859 501.7054 501.8248 501.9442 502.0635 502.1829 502.3022 502.4215 502.5408 502.6601 502.7793 502.8986 503.0178 503.1370 503.2562 503.3754 503.4945 503.6137 503.7328 503.8519 503.9710 504.0901 504.2091 504.3281 504.4472 504.5662 504.6851 504.8041 504.9230 505.0420 505.1609 505.2798 505.3986 505.5175 505.6363 505.7552 505.8740 505.9928 506.1115 506.2303 506.3490 506.4677 506.5864 506.7051 506.8238 506.9424 507.0610 507.1797 507.2983 507.4168 507.5354 507.6539 507.7725 507.8910 508.0094 508.1279 508.2464 508.3648 508.4832 508.6016 508.7200 508.8384 508.9567 509.0750 509.1934 509.3117 509.4299 509.5482 509.6664 509.7847 509.9029 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180905T033124.0Z 6822.146806 1 1 32.01 2 89.90 76.29 48.24 128.99 0.00 1 0.00 1 0 15 1.108e-01 1.042e-01 9.867e-02 9.518e-02 -4.500930e+02 5.673034e+03 4.187306e+02 -6.000000e+00 6.134339e+03 277.16 -2.00 20.00 -2.00 505.24 0.00e+00 6.777153e-06 2.605972e-03 7.726641e-05 -6.000000e+00 3.104336e-03 277.16 -2.00 20.00 -2.00 499.85 0.00e+00 3.980109e+00 1.977500e+00 9.602613e-02 -6.000000e+00 2.240507e+00 229.75 -2.00 4.26 -2.00 501.53 0.00e+00 20.342 0.219 489.00 513.00 1 8.8061e-01 1.5067e-01 4.2647e-02 -6.0000e+00 1.7114e-01 1.1672e-01 3.9358e-02 2.5947e-03 -6.0000e+00 4.4750e-02 3.4468e-02 3.3036e-03 8.8059e-03 5.3739e-05 -6.0000e+00 1.0587e-02 1.9957e-02 -3.1504e-04 12 8 8 10 0 0 92.71 20.42 8.98 0.01996 0.04287 8 2 1 5 0 4000.000 23.22 15.03 20.42 6494 -2957 21773 5482 -11763 5324 12098 -5428 -6783 -8197 13914 -16807 10988 -3874 15755 -6599 -2921 -8113 2819 8922 7526 6999 -8607 -5854 12146 -5862 -7275 17470 8683 -3996 2669 19395 3252 -5334 19698 8599 -2927 -10202 2466 4611 -18734 -11041 4804 11572 15074 -8142 18325 -8200 -9644 -7671 6757 2561 9569 36030 -13523 -1187 2134 -9169 -6109 -6855 -372 1178 -3101 -1562 -8375 17365 2393 17656 975 1284 -7099 1853 8582 7476 951 -12936 8887 7375 17101 4995 15598 -499 6321 6497 20694 -3810 -1498 -3402 -6286 15339 -1889 21223 -329 -6879 -1271 10921 6816 -5310 205 5630 -393 10522 -10040 2581 -8284 -6611 -5756 9701 15122 -10830 17128 -8580 -23394 7101 12458 5366 23296 255 5934 -15510 -5853 23747 11338 -12302 10970 -14002 5457 283 -20599 -5362 -1830 10334 -4161 3108 -5201 -7655 -12537 17665 16839 8043 8144 -4966 19618 -2929 10176 -6327 -3704 25261 14761 -12634 6026 -3061 18375 5573 -14542 5659 12224 -6531 -8239 -9963 13480 -21686 10679 -4285 14377 -7516 -3266 -9829 3135 9418 8060 7533 -10755 -7145 12534 -7173 -8986 16759 8847 -4435 2727 17020 3415 -6333 18654 9114 -3412 -12622 2675 4860 -24529 -13577 5087 11566 14647 -9889 17200 -9728 -11382 -8642 6439 2479 8535 25105 -15658 -1251 2218 -10713 -6892 -7748 -394 1233 -3394 -1665 -9447 15002 2358 14726 941 1217 -7245 1730 7571 6762 924 -14182 7729 6387 13409 4373 12429 -466 5549 5732 15990 -3757 -1445 -3343 -6302 12514 -1842 16644 -325 -7212 -1250 9431 6021 -5130 182 4696 -343 8421 -10023 2371 -8576 -6710 -5697 8142 11910 -11031 13502 -8832 -28126 6407 10718 4977 18138 248 5401 -17235 -5815 17476 9426 -12839 9200 -14981 4839 264 -23463 -5252 -1722 8555 -3883 2664 -4835 -7395 -12923 13858 13522 7123 7247 -5020 15725 -2941 8994 -6512 -3649 18433 11618 -12907 SO 20180905T033323.0Z 6822.148183 3 1 32.01 2 89.66 76.72 48.05 129.54 0.00 1 0.00 1 0 19 1.081e-01 9.949e-02 9.153e-02 8.806e-02 -6.965131e+03 5.149394e+03 3.796332e+02 -6.000000e+00 5.986492e+03 277.16 -2.00 20.00 -2.00 505.17 0.00e+00 2.110720e-03 2.431396e-03 1.131797e-04 -6.000000e+00 3.029806e-03 277.16 -2.00 20.00 -2.00 499.71 0.00e+00 5.224658e+00 1.857649e+00 8.644244e-02 -6.000000e+00 2.188071e+00 229.75 -2.00 4.26 -2.00 501.38 0.00e+00 20.001 0.208 489.00 513.00 1 7.4334e-01 1.4244e-01 4.1262e-02 -6.0000e+00 1.6713e-01 1.2249e-01 3.6885e-02 2.8094e-03 -6.0000e+00 4.3730e-02 3.7283e-02 -9.1356e-04 8.1482e-03 4.6381e-05 -6.0000e+00 1.0327e-02 5.0052e-02 -5.3442e-04 12 8 8 10 0 0 -132.99 20.45 5.84 0.05005 0.04371 8 2 1 5 0 4000.000 23.22 14.99 20.45 -7423 7862 10597 7436 -10758 6864 -11103 341 -805 689 -3412 5553 -4241 -1221 8524 -13319 -5005 -3886 -15472 12728 -5955 11859 14706 -712 -5609 4179 4366 2563 12790 -5875 13839 -2705 7798 2552 6222 -4126 6191 19899 -5565 -11909 2746 -730 -263 8460 2739 11240 -7143 14619 -18083 8378 110 4069 -3147 -3813 8709 9109 9074 -11837 -1553 -4025 -5172 -4483 35385 -12241 7693 6353 -2409 -12702 3387 10484 12253 -8094 -7229 4180 -629 -4851 25632 6845 683 7274 8382 9631 -3448 4588 -20279 16984 -9583 980 -232 -3766 18231 -2060 9855 10136 33888 -13748 13829 -10724 863 6436 -9438 -5594 16321 2528 28328 -6980 -4762 -4569 -2794 17642 621 605 -1138 -645 -15299 -9291 -5250 -2506 3316 4209 -2674 1545 -9816 -8137 3804 -1616 19426 8186 11402 5373 14651 27113 26314 -7392 3424 -18214 4348 11351 24611 -2650 -18025 6961 -2035 3409 -18862 -1698 -1430 -5629 7621 5449 -8035 7502 10173 7557 -13331 7332 -14331 397 -945 785 -3988 5856 -4862 -1341 8504 -16438 -5766 -4541 -20644 13061 -7311 12271 14801 -832 -6925 4681 4863 2876 12642 -6763 12891 -2951 7817 2795 6761 -4967 6652 18538 -6548 -14800 2945 -815 -295 8795 3041 11482 -8639 14140 -23629 8261 113 3947 -3202 -3919 8157 8690 8851 -14226 -1691 -4433 -5745 -4962 26765 -14636 7520 6139 -2493 -14335 3210 9184 10404 -8325 -7420 3875 -617 -4895 18985 5944 623 6187 7066 8066 -3278 4037 -22829 13457 -9761 905 -217 -3630 14294 -1987 8657 9001 24042 -15311 11699 -11305 794 5458 -9160 -5280 12597 2297 20285 -6943 -4533 -4248 -2521 13117 552 550 -1077 -615 -17080 -9823 -5335 -2462 3033 3755 -2522 1386 -9789 -8040 3386 -1522 14815 6977 9407 4686 11718 18931 18182 -6972 2869 -18907 3706 9234 17969 -2526 -19949 6051 -1944 3108 -21476 -1626 -1344 -5368 6242 4506 SO 20180905T033518.0Z 6822.149514 5 1 32.01 2 89.43 77.14 47.88 130.07 0.00 1 0.00 1 0 29 8.744e-02 8.292e-02 7.969e-02 7.742e-02 1.546632e+03 4.756077e+03 5.873699e+01 -6.000000e+00 4.845210e+03 277.16 -2.00 20.00 -2.00 505.17 0.00e+00 3.276730e-04 2.113735e-03 2.364836e-05 -6.000000e+00 2.450295e-03 277.16 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