File name: Pandora105s1_Helsinki_20180911_L2Fit_fwvt1c2d20180411p1-8.txt File generation date: 20251122T165845.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20180411.txt Level 1 file used: Pandora105s1_Helsinki_20180911_L1_smca1c2d20180411p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20180911 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1767 Nominal wavelengths inside fitting window [nm]: 492.0970 492.2178 492.3385 492.4593 492.5800 492.7007 492.8214 492.9421 493.0628 493.1834 493.3041 493.4247 493.5453 493.6659 493.7864 493.9070 494.0275 494.1480 494.2685 494.3890 494.5094 494.6299 494.7503 494.8707 494.9911 495.1115 495.2318 495.3522 495.4725 495.5928 495.7131 495.8334 495.9536 496.0738 496.1941 496.3143 496.4345 496.5546 496.6748 496.7949 496.9150 497.0351 497.1552 497.2753 497.3953 497.5153 497.6353 497.7553 497.8753 497.9953 498.1152 498.2351 498.3550 498.4749 498.5948 498.7147 498.8345 498.9543 499.0741 499.1939 499.3137 499.4334 499.5532 499.6729 499.7926 499.9123 500.0319 500.1516 500.2712 500.3908 500.5104 500.6300 500.7495 500.8691 500.9886 501.1081 501.2276 501.3471 501.4665 501.5859 501.7054 501.8248 501.9442 502.0635 502.1829 502.3022 502.4215 502.5408 502.6601 502.7793 502.8986 503.0178 503.1370 503.2562 503.3754 503.4945 503.6137 503.7328 503.8519 503.9710 504.0901 504.2091 504.3281 504.4472 504.5662 504.6851 504.8041 504.9230 505.0420 505.1609 505.2798 505.3986 505.5175 505.6363 505.7552 505.8740 505.9928 506.1115 506.2303 506.3490 506.4677 506.5864 506.7051 506.8238 506.9424 507.0610 507.1797 507.2983 507.4168 507.5354 507.6539 507.7725 507.8910 508.0094 508.1279 508.2464 508.3648 508.4832 508.6016 508.7200 508.8384 508.9567 509.0750 509.1934 509.3117 509.4299 509.5482 509.6664 509.7847 509.9029 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180911T034524.0Z 6828.156528 1 1 32.01 2 89.91 80.88 103.05 65.36 0.00 1 0.00 1 0 15 6.541e-02 6.351e-02 3.996e-02 3.935e-02 1.245317e+04 2.889013e+03 6.784316e+02 -6.000000e+00 3.612952e+03 276.36 -2.00 20.00 -2.00 505.30 0.00e+00 -7.810445e-06 1.081053e-03 7.466043e-05 -6.000000e+00 1.830295e-03 276.36 -2.00 20.00 -2.00 500.21 0.00e+00 2.527502e+00 8.080993e-01 1.272579e-01 -6.000000e+00 1.319594e+00 228.84 -2.00 4.26 -2.00 501.83 0.00e+00 20.385 0.220 489.00 513.00 1 4.7434e-02 6.1755e-02 4.3522e-02 -6.0000e+00 1.0085e-01 8.4100e-02 1.5556e-02 3.5074e-03 -6.0000e+00 2.6264e-02 8.6550e-02 -4.8272e-04 3.4294e-03 6.2922e-05 -6.0000e+00 6.2950e-03 -6.8306e-02 4.0151e-04 12 9 9 12 4 4 80.55 31.85 17.99 -0.06831 -0.07165 8 2 1 5 0 4000.000 34.75 14.96 31.85 -5449 -3570 -85 5085 -90 2363 9654 8492 -12007 8417 -4711 833 -11644 6186 2557 -2138 1125 -3475 -3115 4985 6538 -9766 -52 4075 -580 -1380 4042 7427 -1789 -931 -2243 -1709 2188 5484 -1549 -4486 8470 2516 6969 408 -155 -1258 51 14852 5009 -4250 -6507 6053 -4656 -12836 8400 11122 11773 -3222 3010 3603 3152 10001 -8103 -53 -7227 -3873 6251 -5610 -11421 6698 872 12604 2190 1519 5805 -7208 -7730 -7501 2336 -5706 3782 -4284 3745 127 3771 -3572 1637 2635 -6326 488 6727 7033 -7622 2282 -4330 4050 -4352 5250 -4628 -613 5869 -2068 -7433 -8148 13169 -8919 4216 -8347 4987 -5702 -2583 -704 10463 -3651 -5820 -688 9180 11123 252 -6162 8565 14581 4588 -5286 824 1420 530 9033 9431 -1638 -79 22841 -2826 12374 3981 7429 -442 -10754 6928 -3926 -11941 -4398 -1647 661 8402 -4741 -5655 6018 -6236 6239 -4753 1168 -2723 1055 -5379 -3507 -83 4904 -94 2450 9477 8515 -14629 8325 -5201 867 -13441 5958 2522 -2223 1153 -3838 -3515 5245 6783 -11837 -58 4329 -649 -1555 4300 7553 -1944 -970 -2330 -1776 2244 5652 -1746 -5230 8651 2673 7055 435 -166 -1372 56 14081 5285 -4884 -7593 6194 -5170 -15079 7805 9801 10187 -3243 2933 3599 3230 9630 -9252 -56 -8146 -4245 6214 -6270 -13399 6452 875 11183 2116 1457 5289 -7433 -8100 -7959 2282 -5942 3535 -4221 3392 117 3403 -3464 1517 2443 -6446 472 6119 6348 -7856 2126 -4332 3772 -4451 4845 -4595 -565 4899 -1817 -6749 -7337 9557 -8177 3567 -8381 4555 -5877 -2566 -677 8913 -3574 -5906 -672 8163 9785 246 -6433 7823 12702 4423 -5513 792 1328 495 7840 8221 -1591 -75 17492 -2774 10442 3632 6449 -406 -10895 5957 -3803 -12738 -4468 -1652 657 7826 -5043 -6109 5810 -6808 5981 -5014 1138 -2712 1009 SO 20180911T034711.0Z 6828.157766 3 1 32.01 2 89.69 81.27 102.86 65.75 0.00 1 0.00 1 0 39 6.035e-02 5.932e-02 3.468e-02 3.415e-02 1.300801e+04 2.571559e+03 1.031378e+03 -6.000000e+00 3.334638e+03 276.36 -2.00 20.00 -2.00 505.37 0.00e+00 2.539406e-03 9.384539e-04 8.971556e-05 -6.000000e+00 1.691300e-03 276.36 -2.00 20.00 -2.00 500.17 0.00e+00 3.803118e+00 7.075326e-01 4.474534e-02 -6.000000e+00 1.224493e+00 228.84 -2.00 4.26 -2.00 501.81 0.00e+00 20.080 0.210 489.00 513.00 1 -1.8581e-01 5.3819e-02 4.1245e-02 -6.0000e+00 9.3494e-02 5.0383e-02 1.3645e-02 2.7620e-03 -6.0000e+00 2.4514e-02 9.9954e-02 7.3630e-04 3.0311e-03 1.0413e-04 -6.0000e+00 5.8697e-03 -8.8522e-02 1.2060e-04 12 9 9 12 4 4 95.32 31.88 5.54 -0.08852 -0.08341 8 2 1 5 0 4000.000 34.86 15.04 31.88 424 -6147 -1245 -6156 5313 1246 1119 4555 -8036 5782 -3615 -5430 6167 -1973 -5526 -1814 -2833 9228 -7293 -3938 -5396 -9070 1435 -1117 13607 4529 4705 7215 3411 6170 5217 -2776 3114 1012 1663 2805 -1919 -6553 12866 -1320 2055 5275 10629 1391 -7385 -5806 -8531 -253 322 6892 -6272 -7453 2792 1923 4564 1250 -1123 -2211 861 5426 -2867 -6477 5928 8017 2029 2535 -4325 3673 -2518 7451 -5121 9655 -9115 -7544 2085 1982 -5024 11756 -2752 7045 488 4890 -230 7274 7003 895 1762 2513 -281 -731 9479 4763 14405 -2135 1045 4804 -4617 5519 2133 -7951 6625 -380 3352 -3164 -3100 -8495 33 -7808 -1971 1135 4593 -984 -4430 -2666 3416 -5875 3334 10548 -9717 13412 -4608 -8347 6192 10994 6586 5318 12579 -6195 -3416 -11677 -788 3983 -6871 -3939 3390 812 -9408 -3736 -952 5233 4035 -1414 -4525 2208 1854 -10663 12712 3651 -6561 13507 390 -6074 -1210 -6518 5161 1289 1183 4713 -9375 5866 -3938 -5947 5986 -2037 -5864 -1856 -2965 8770 -8340 -4430 -6181 -10780 1538 -1234 13171 4783 4954 7363 3547 6045 5024 -2886 3104 1067 1790 3028 -2160 -7633 12299 -1431 2151 5383 10396 1499 -8797 -6846 -10309 -278 347 6812 -6877 -8037 2668 1853 4379 1281 -1201 -2423 915 5488 -3143 -7395 6010 7968 2128 2608 -4681 3612 -2602 6876 -5251 8565 -9739 -8036 2041 1939 -5180 10098 -2668 6189 453 4357 -217 6402 6242 850 1663 2342 -267 -694 8130 4325 12137 -2114 986 4229 -4310 4514 1761 -7068 5067 -314 2751 -2890 -2964 -8723 31 -7886 -1857 1038 4143 -947 -4463 -2652 3204 -6026 3177 9501 -10730 11771 -4724 -8697 5493 9360 5870 4841 10693 -6317 -3387 -12597 -761 3631 -6872 -3790 3032 755 -9827 -3770 -950 4980 3939 -1473 -4897 2247 1898 -12259 11540 3564 -6908 11603 SO 20180911T034853.0Z 6828.158947 5 1 32.01 2 89.49 81.64 102.68 66.13 0.00 1 0.00 1 0 39 3.773e-02 3.722e-02 1.935e-02 1.921e-02 1.195749e+04 1.378977e+03 8.638271e+02 -6.000000e+00 2.082929e+03 276.36 -2.00 20.00 -2.00 505.47 0.00e+00 2.375381e-03 5.328378e-04 9.859022e-05 -6.000000e+00 1.055558e-03 276.36 -2.00 20.00 -2.00 500.77 0.00e+00 2.609583e+00 3.847054e-01 7.571282e-02 -6.000000e+00 7.626471e-01 228.84 -2.00 4.26 -2.00 502.34 0.00e+00 19.721 0.199 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