File name: Pandora105s1_Helsinki_20180928_L2Fit_fwvt1c2d20180411p1-8.txt File generation date: 20251122T171754.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20180411.txt Level 1 file used: Pandora105s1_Helsinki_20180928_L1_smca1c2d20180411p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20180928 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1767 Nominal wavelengths inside fitting window [nm]: 492.0970 492.2178 492.3385 492.4593 492.5800 492.7007 492.8214 492.9421 493.0628 493.1834 493.3041 493.4247 493.5453 493.6659 493.7864 493.9070 494.0275 494.1480 494.2685 494.3890 494.5094 494.6299 494.7503 494.8707 494.9911 495.1115 495.2318 495.3522 495.4725 495.5928 495.7131 495.8334 495.9536 496.0738 496.1941 496.3143 496.4345 496.5546 496.6748 496.7949 496.9150 497.0351 497.1552 497.2753 497.3953 497.5153 497.6353 497.7553 497.8753 497.9953 498.1152 498.2351 498.3550 498.4749 498.5948 498.7147 498.8345 498.9543 499.0741 499.1939 499.3137 499.4334 499.5532 499.6729 499.7926 499.9123 500.0319 500.1516 500.2712 500.3908 500.5104 500.6300 500.7495 500.8691 500.9886 501.1081 501.2276 501.3471 501.4665 501.5859 501.7054 501.8248 501.9442 502.0635 502.1829 502.3022 502.4215 502.5408 502.6601 502.7793 502.8986 503.0178 503.1370 503.2562 503.3754 503.4945 503.6137 503.7328 503.8519 503.9710 504.0901 504.2091 504.3281 504.4472 504.5662 504.6851 504.8041 504.9230 505.0420 505.1609 505.2798 505.3986 505.5175 505.6363 505.7552 505.8740 505.9928 506.1115 506.2303 506.3490 506.4677 506.5864 506.7051 506.8238 506.9424 507.0610 507.1797 507.2983 507.4168 507.5354 507.6539 507.7725 507.8910 508.0094 508.1279 508.2464 508.3648 508.4832 508.6016 508.7200 508.8384 508.9567 509.0750 509.1934 509.3117 509.4299 509.5482 509.6664 509.7847 509.9029 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180928T042544.0Z 6845.184537 1 1 32.01 2 89.90 94.20 65.97 246.13 0.00 1 0.00 1 0 40 1.290e-01 1.183e-01 1.042e-01 9.952e-02 1.224978e+04 7.553008e+03 1.177854e+03 -6.000000e+00 7.041999e+03 273.61 -2.00 20.00 -2.00 505.23 0.00e+00 -6.581727e-04 2.706328e-03 2.585687e-05 -6.000000e+00 3.582974e-03 273.61 -2.00 20.00 -2.00 499.76 0.00e+00 -3.714946e-01 2.085917e+00 2.579336e-02 -6.000000e+00 2.593074e+00 225.97 -2.00 4.26 -2.00 501.43 0.00e+00 20.455 0.222 489.00 513.00 1 1.2311e+00 1.5845e-01 4.2574e-02 -6.0000e+00 1.9804e-01 2.0499e-01 4.0548e-02 2.5158e-03 -6.0000e+00 5.1557e-02 3.2419e-02 1.7857e-02 8.4926e-03 7.5673e-05 -6.0000e+00 1.2376e-02 3.9859e-02 -1.6523e-04 12 9 8 11 8 0 73.02 21.62 8.82 0.03986 0.16373 8 2 1 5 0 4000.000 24.56 14.85 21.62 -4846 -14035 6060 -5476 566 4040 -1003 -1923 5620 24827 10906 -21802 27160 -11478 -1166 -9999 10748 -7618 827 2121 23511 395 19164 3208 -1740 9041 -5672 21693 -26253 12118 -5187 6618 -2699 2042 8840 13101 -1587 -5899 -6 -3399 -6081 -1486 13609 605 20052 5501 10589 -16144 -244 -11938 -11370 3594 -5718 -13167 4608 -5639 6744 3639 -1290 -600 -10687 23288 7432 2778 -1166 10565 4124 10189 4091 -4955 -6020 12151 -914 9567 6995 13427 16165 6394 5128 -961 7553 19353 1897 -8460 4843 21785 -1961 -26082 12360 -14553 11801 -295 -5320 11735 -2991 3096 5746 30945 15658 1179 -21282 23369 11611 5341 -7687 -9486 43 41362 -3432 25596 -13323 23048 5785 1465 5856 -5714 6178 -19182 8114 -8357 -2669 1666 18184 3419 -15431 -13746 -21368 8637 -9185 -1314 -15334 11781 -3329 17741 -3657 -3581 13247 6858 -11437 45349 -9483 27363 450 16066 12191 -15492 -3353 15456 8867 -8681 -5307 -17429 6334 -6557 650 4548 -1183 -2273 6118 21988 10951 -29435 22588 -13880 -1281 -12243 10996 -9481 960 2426 21685 455 18534 3616 -2054 9518 -6803 19350 -36045 11390 -5806 6779 -3120 2315 9341 13096 -1798 -6894 -7 -3851 -7125 -1678 13345 679 18646 5809 10467 -20263 -257 -13550 -12533 3414 -6003 -15366 4633 -6388 6766 3750 -1390 -643 -12646 19820 7386 2836 -1217 9725 3967 9188 3840 -5058 -6238 10635 -925 8759 6485 11420 13135 5676 4595 -919 6675 15321 1794 -8919 4537 17348 -1955 -32392 10610 -16330 10384 -292 -5475 9965 -2817 2674 4703 19446 11217 971 -22344 16723 9756 4936 -8088 -10053 40 26168 -3368 19168 -14620 17892 5286 1397 5369 -5910 5723 -22631 7212 -8550 -2524 1495 13993 3041 -16459 -14386 -24033 7230 -9093 -1189 -15671 9110 -2953 12921 -3332 -3329 10571 5906 -11870 27314 -9786 19757 423 12963 10050 -16413 -3099 11723 7113 -8332 SO 20180928T042743.0Z 6845.185914 3 1 32.01 2 89.65 94.63 66.18 246.59 0.00 1 0.00 1 0 53 1.054e-01 9.978e-02 9.284e-02 8.969e-02 1.548058e+04 6.971248e+03 7.905835e+02 -6.000000e+00 5.758112e+03 273.61 -2.00 20.00 -2.00 505.22 0.00e+00 2.839102e-03 2.460225e-03 1.302450e-04 -6.000000e+00 2.932966e-03 273.61 -2.00 20.00 -2.00 499.98 0.00e+00 -7.770430e-01 1.898594e+00 1.713978e-01 -6.000000e+00 2.124595e+00 225.97 -2.00 4.26 -2.00 501.59 0.00e+00 20.096 0.211 489.00 513.00 1 1.1510e+00 1.4426e-01 4.3355e-02 -6.0000e+00 1.6219e-01 1.9278e-01 3.7163e-02 4.0392e-03 -6.0000e+00 4.2404e-02 3.6249e-02 -6.4862e-03 7.7755e-03 6.7400e-05 -6.0000e+00 1.0107e-02 -1.1377e-02 8.1053e-04 12 8 8 10 0 0 -158.15 21.66 9.69 -0.01138 -0.05637 8 2 1 5 0 4000.000 24.65 15.22 21.66 -4400 5299 4405 -539 3133 -12722 2692 14368 -7164 788 -115 -19227 -745 8022 -3552 15614 -9085 12020 16684 -8369 -7792 -2556 22923 21498 -2337 -402 17335 -2031 -4597 1439 -159 8286 3907 -16718 7345 3361 16200 7630 6279 1955 -19850 556 12559 -383 -4684 4130 -14085 -476 202 12335 -13408 1807 -8444 13669 -28 324 2600 -5550 6586 -8543 23619 -167 -1896 4840 24042 12028 740 -1956 10224 -7067 6799 -8205 -4758 906 -3420 -13520 8342 -9225 -7443 5594 4437 2083 -391 11851 565 11558 9108 -3780 5878 -4937 5035 18955 -8449 9130 -16131 -2830 -1119 19599 1212 -2348 26349 27262 -11520 -17723 -14347 -1874 -6679 4119 23329 -6225 13081 12339 7721 3232 -671 -2722 -3598 -2907 -3509 9223 175 14058 3470 4440 -3531 -7188 13929 -13359 6300 10314 -3238 19479 -11643 -568 17062 6786 6229 -6103 -13227 -6816 -20130 4919 -8450 -3279 11793 -1380 3533 14786 24312 900000 -4626 5214 4526 -592 3384 -16391 3005 14377 -8710 869 -126 -24942 -799 7800 -3873 14202 -10728 11886 15969 -10217 -9441 -2938 20653 19756 -2710 -455 16321 -2270 -5096 1462 -164 7967 4063 -21728 7656 3618 15264 7677 6349 2063 -26008 606 12280 -428 -5489 4415 -17870 -519 213 11345 -15390 1751 -9087 12175 -29 345 2734 -6332 6631 -9997 20304 -182 -2101 4982 20296 11164 757 -2034 9290 -7486 6301 -8833 -5017 913 -3590 -15295 7480 -9713 -7642 5031 4052 1958 -380 10298 551 10187 8179 -3796 5326 -4992 4659 15593 -9000 8047 -17514 -2609 -982 13749 995 -1976 16935 17975 -11613 -19765 -15834 -1840 -6744 3720 17551 -6282 11119 10640 6925 3027 -655 -2741 -3682 -2974 -3577 8160 164 11345 3082 3931 -3403 -7193 11354 -14041 5472 8557 -3028 14350 -11408 -502 12783 5744 5353 -6004 -14034 -6854 -23286 4479 -8742 -3214 9954 -1300 3102 11446 16943 900000 SO 20180928T042938.0Z 6845.187245 5 1 32.01 2 89.41 95.05 66.39 247.04 0.00 1 0.00 1 0 40 9.593e-02 9.473e-02 8.254e-02 8.016e-02 1.753632e+03 5.026499e+03 2.069479e+01 -6.000000e+00 5.238233e+03 273.61 -2.00 20.00 -2.00 505.27 0.00e+00 5.294084e-03 2.197484e-03 2.531323e-04 -6.000000e+00 2.668616e-03 273.61 -2.00 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