File name: Pandora105s1_Helsinki_20181120_L2Fit_fwvt1c2d20180411p1-8.txt File generation date: 20251122T171752.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20180411.txt Level 1 file used: Pandora105s1_Helsinki_20181120_L1_smca1c2d20180411p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20181120 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1767 Nominal wavelengths inside fitting window [nm]: 492.0970 492.2178 492.3385 492.4593 492.5800 492.7007 492.8214 492.9421 493.0628 493.1834 493.3041 493.4247 493.5453 493.6659 493.7864 493.9070 494.0275 494.1480 494.2685 494.3890 494.5094 494.6299 494.7503 494.8707 494.9911 495.1115 495.2318 495.3522 495.4725 495.5928 495.7131 495.8334 495.9536 496.0738 496.1941 496.3143 496.4345 496.5546 496.6748 496.7949 496.9150 497.0351 497.1552 497.2753 497.3953 497.5153 497.6353 497.7553 497.8753 497.9953 498.1152 498.2351 498.3550 498.4749 498.5948 498.7147 498.8345 498.9543 499.0741 499.1939 499.3137 499.4334 499.5532 499.6729 499.7926 499.9123 500.0319 500.1516 500.2712 500.3908 500.5104 500.6300 500.7495 500.8691 500.9886 501.1081 501.2276 501.3471 501.4665 501.5859 501.7054 501.8248 501.9442 502.0635 502.1829 502.3022 502.4215 502.5408 502.6601 502.7793 502.8986 503.0178 503.1370 503.2562 503.3754 503.4945 503.6137 503.7328 503.8519 503.9710 504.0901 504.2091 504.3281 504.4472 504.5662 504.6851 504.8041 504.9230 505.0420 505.1609 505.2798 505.3986 505.5175 505.6363 505.7552 505.8740 505.9928 506.1115 506.2303 506.3490 506.4677 506.5864 506.7051 506.8238 506.9424 507.0610 507.1797 507.2983 507.4168 507.5354 507.6539 507.7725 507.8910 508.0094 508.1279 508.2464 508.3648 508.4832 508.6016 508.7200 508.8384 508.9567 509.0750 509.1934 509.3117 509.4299 509.5482 509.6664 509.7847 509.9029 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181120T064118.0Z 6898.278681 1 1 32.01 2 89.92 132.88 115.98 341.87 0.00 1 0.00 1 0 26 2.149e-01 1.701e-01 1.329e-01 1.221e-01 -6.725315e+03 6.622638e+03 4.463971e+02 -6.000000e+00 1.129903e+04 264.65 -2.00 20.00 -2.00 505.25 0.00e+00 1.085172e-02 3.246974e-03 5.057692e-04 -6.000000e+00 5.866009e-03 264.65 -2.00 20.00 -2.00 500.22 0.00e+00 2.509537e+00 2.520269e+00 8.500806e-02 -6.000000e+00 4.334560e+00 218.53 -2.00 4.26 -2.00 501.83 0.00e+00 20.766 0.233 489.00 513.00 1 1.0689e+00 1.9145e-01 4.5982e-02 -6.0000e+00 3.2982e-01 1.2514e-01 4.9733e-02 2.7420e-03 -6.0000e+00 8.7014e-02 2.5401e-02 2.3595e-02 1.0814e-02 1.8856e-04 -6.0000e+00 2.0642e-02 5.4586e-02 -1.0488e-03 12 9 8 11 12 0 32.83 27.92 14.64 0.05459 0.21825 8 2 1 5 0 4000.000 31.10 14.99 27.92 -6549 40683 1211 -1062 -20490 -15181 5272 17321 23956 10063 9322 7774 10451 -11739 5882 19101 17397 -16379 -14793 6673 10793 9949 -5495 14356 3878 -19089 -22858 -18150 -17146 10466 915 45727 1924 4570 8609 29456 -82 35203 -5336 9407 -1018 1944 -10480 8387 12559 34360 -6347 -5564 33962 -17854 39279 -18340 26528 -20400 28241 -4974 24163 -12308 -3032 -16578 -5712 -15894 25568 17642 21432 22565 2288 11326 9329 5553 -578 13724 11796 -19907 -4954 -4646 -9018 8079 8285 -7905 21797 90206 -2689 -2853 4487 72063 -1292 18698 6585 35636 -1483 -9549 38331 -8549 -13251 6076 34832 3294 -26553 8808 7361 62588 -9148 22325 -14402 5956 7388 -7170 8389 30879 -14206 -11470 -17692 22356 -11215 43228 -6258 73222 -18519 -19326 -2006 3421 1305 7646 -7667 21789 330 -5897 -756 21735 37291 18673 26189 -25952 34938 2 5450 -17660 11276 -16377 -29747 3211 28887 10723 6116 18554 4335 9022 -9252 22231 -6808 27752 1251 -1153 -27317 -19507 5609 16255 20688 9777 8967 7470 9635 -13272 5612 16105 15210 -20188 -18135 6643 10287 9579 -6168 13461 4034 -24791 -30598 -22659 -20462 9369 891 29440 1957 4680 8568 23812 -87 26319 -5867 9047 -1093 2063 -12724 8639 12519 27752 -7514 -6446 26391 -22350 27515 -22008 20728 -25718 23004 -5712 21189 -15448 -3463 -21521 -6747 -20752 22421 16634 19177 19617 2380 10627 8797 5361 -590 12197 10803 -24894 -5361 -4929 -9801 7369 7510 -8364 17335 37119 -2713 -2864 4227 35302 -1272 15136 5974 24711 -1490 -10585 27369 -9751 -15923 6061 25937 3227 -33784 7796 6557 32814 -9765 17667 -16027 5325 6376 -7037 7155 21680 -15886 -12879 -21577 18924 -13224 30118 -7007 37684 -22583 -23605 -2046 3304 1299 7220 -8426 18146 338 -6391 -781 18063 26460 15535 19786 -32034 23936 2 5108 -21015 10197 -19402 -39875 3116 22110 9821 5814 15453 4014 7788 -9354 16610 SO 20181120T064317.0Z 6898.280058 3 1 32.01 2 89.74 133.31 116.05 342.39 0.00 1 0.00 1 0 75 1.754e-01 1.560e-01 1.148e-01 1.082e-01 9.393901e+03 7.107128e+03 7.054741e+02 -6.000000e+00 9.220247e+03 264.65 -2.00 20.00 -2.00 505.21 0.00e+00 -6.028317e-03 2.861827e-03 1.806090e-04 -6.000000e+00 4.790097e-03 264.65 -2.00 20.00 -2.00 500.07 0.00e+00 -1.395095e-01 2.181282e+00 1.299800e-01 -6.000000e+00 3.537302e+00 218.53 -2.00 4.26 -2.00 501.72 0.00e+00 20.511 0.224 489.00 513.00 1 1.3926e+00 1.6664e-01 4.3947e-02 -6.0000e+00 2.6929e-01 1.4281e-01 4.2752e-02 2.7836e-03 -6.0000e+00 7.0959e-02 2.8779e-02 2.4202e-02 9.2660e-03 8.3905e-05 -6.0000e+00 1.6842e-02 3.7366e-02 -8.8216e-04 12 9 8 11 12 0 94.08 27.95 5.10 0.03737 0.20524 8 2 1 5 0 4000.000 31.19 15.01 27.95 32178 3807 16765 -10750 -3279 864 -2713 -12848 23869 -3687 1243 24657 5086 8775 13100 7827 35635 4886 25168 11885 -14882 1416 -6734 15372 -28172 9691 -4542 -21792 -6205 10049 8792 15679 -3225 -15553 -15383 16970 16880 7545 -3148 9424 44506 -4583 -14649 1240 28610 2291 14059 -6484 3798 980 40544 -17425 6204 -16501 17169 190 1174 18498 2638 15708 -4466 859 -9983 11209 2311 -16456 -2130 -3351 -6242 10041 -16409 24614 12305 -16888 17763 -15337 -17740 -19975 25964 3595 8531 -10288 51432 22328 16764 -30452 -9351 19853 35609 -17631 18873 6745 -4056 19472 40959 126 11214 -7957 -2560 -16842 -12067 17684 -26975 32277 -5855 15642 -12655 11589 12073 8332 -8273 24077 5389 22999 -23003 -3062 15719 15385 3793 -11143 17617 10896 -4996 -270 -4614 -6510 24857 115 13163 28755 22574 11300 -3575 -16787 8183 8858 9330 35999 -8235 -693 -9399 -4624 -18258 27218 -4520 668 8140 22099 -20163 58163 22956 3660 14748 -12559 -3629 937 -3088 -16229 20888 -4168 1325 20706 5094 8420 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264.65 -2.00 20.00 -2.00 505.21 0.00e+00 3.900058e-03 2.611642e-03 2.211127e-04 -6.000000e+00 4.184754e-03 264.65 -2.00 20.00 -2.00 499.86 0.00e+00 2.453194e+00 2.013372e+00 4.443809e-02 -6.000000e+00 3.092562e+00 218.53 -2.00 4.26 -2.00 501.51 0.00e+00 20.219 0.215 489.00 513.00 1 1.0134e+00 1.5300e-01 4.1964e-02 -6.0000e+00 2.3553e-01 1.3415e-01 3.8557e-02 2.4036e-03 -6.0000e+00 6.1912e-02 3.1784e-02 4.1128e-02 9.2192e-03 7.6313e-05 -6.0000e+00 1.4896e-02 2.7869e-03 -5.6076e-04 12 9 8 11 4 0 7.34 27.97 10.57 0.00279 0.28807 8 2 1 5 0 4000.000 31.19 15.05 27.97 45917 13381 -13152 26083 -22459 9889 -6127 14666 -2605 -10873 13449 -21064 10260 19105 -3203 -13575 803 39710 -4126 14542 6266 -3496 5839 8491 18030 -6154 11275 37878 -5772 21951 9547 15289 -9006 4535 -17346 -15884 14669 -10546 -6562 766 246 -6496 -10758 -13946 11500 -852 10430 10396 17995 24814 -9593 167 5840 5983 -884 -2143 2924 2876 -6166 -18612 -3215 9415 13311 5299 2596 2860 -15965 9634 2206 5095 -11516 20876 46319 9591 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