File name: Pandora105s1_Helsinki_20181129_L2Fit_fwvt1c2d20180411p1-8.txt File generation date: 20251122T171715.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20170321.txt Instrument calibration file used: Pandora105s1_CF_v2d20180411.txt Level 1 file used: Pandora105s1_Helsinki_20181129_L1_smca1c2d20180411p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20181129 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1618 1767 Nominal wavelengths inside fitting window [nm]: 492.0970 492.2178 492.3385 492.4593 492.5800 492.7007 492.8214 492.9421 493.0628 493.1834 493.3041 493.4247 493.5453 493.6659 493.7864 493.9070 494.0275 494.1480 494.2685 494.3890 494.5094 494.6299 494.7503 494.8707 494.9911 495.1115 495.2318 495.3522 495.4725 495.5928 495.7131 495.8334 495.9536 496.0738 496.1941 496.3143 496.4345 496.5546 496.6748 496.7949 496.9150 497.0351 497.1552 497.2753 497.3953 497.5153 497.6353 497.7553 497.8753 497.9953 498.1152 498.2351 498.3550 498.4749 498.5948 498.7147 498.8345 498.9543 499.0741 499.1939 499.3137 499.4334 499.5532 499.6729 499.7926 499.9123 500.0319 500.1516 500.2712 500.3908 500.5104 500.6300 500.7495 500.8691 500.9886 501.1081 501.2276 501.3471 501.4665 501.5859 501.7054 501.8248 501.9442 502.0635 502.1829 502.3022 502.4215 502.5408 502.6601 502.7793 502.8986 503.0178 503.1370 503.2562 503.3754 503.4945 503.6137 503.7328 503.8519 503.9710 504.0901 504.2091 504.3281 504.4472 504.5662 504.6851 504.8041 504.9230 505.0420 505.1609 505.2798 505.3986 505.5175 505.6363 505.7552 505.8740 505.9928 506.1115 506.2303 506.3490 506.4677 506.5864 506.7051 506.8238 506.9424 507.0610 507.1797 507.2983 507.4168 507.5354 507.6539 507.7725 507.8910 508.0094 508.1279 508.2464 508.3648 508.4832 508.6016 508.7200 508.8384 508.9567 509.0750 509.1934 509.3117 509.4299 509.5482 509.6664 509.7847 509.9029 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181129T070253.0Z 6907.293669 1 1 32.00 2 89.93 137.65 58.11 238.87 0.00 1 0.00 1 0 33 1.474e-01 1.381e-01 1.098e-01 1.046e-01 1.390301e+03 6.083100e+03 8.970162e+02 -6.000000e+00 7.706798e+03 263.77 -2.00 20.00 -2.00 505.18 0.00e+00 1.123273e-03 2.819756e-03 1.342238e-04 -6.000000e+00 3.996649e-03 263.77 -2.00 20.00 -2.00 500.02 0.00e+00 1.559754e+00 2.177963e+00 1.577605e-01 -6.000000e+00 2.926586e+00 218.17 -2.00 4.26 -2.00 501.67 0.00e+00 20.799 0.234 489.00 513.00 1 1.1150e+00 1.6706e-01 4.5537e-02 -6.0000e+00 2.2326e-01 1.7519e-01 4.3561e-02 2.9964e-03 -6.0000e+00 5.7794e-02 2.9853e-02 -3.1399e-02 9.6475e-03 1.8701e-04 -6.0000e+00 1.4186e-02 8.8063e-01 -4.9796e-03 12 9 8 11 780 0 -286.66 24.95 12.50 0.88063 0.66283 8 2 1 5 0 4000.000 28.10 14.98 24.95 -2050 -10145 -7425 5832 -12285 2220 26115 259 16083 -13067 11417 1916 -4246 27315 -3721 13291 -7689 8143 830 31773 6799 11162 -24305 -12787 13493 8427 -6075 -3682 900 -7817 12863 3297 1120 -9555 10822 -2271 -1214 -1319 31233 -14719 26191 2305 31966 -28940 -13112 2806 1022 -10773 40422 4699 -3901 18841 26206 27757 4545 8668 7882 4159 -1694 41881 23990 -7017 -23759 4402 5314 16404 -4065 -2790 721 21316 9142 -2013 -5407 -2742 16353 -8679 18561 -11799 -15571 1495 -9380 14379 -9014 1624 6780 -12003 -7667 -12162 7223 44411 -10478 -10054 -21507 10534 22368 -20722 -5322 8737 -5583 12804 18840 -5869 17621 342 17374 9640 23534 -7257 3351 4209 18205 9625 26108 -11307 18700 6414 -18783 17940 -482 11936 3134 22846 -19035 1381 -6920 -2084 3840 -6248 -13046 8284 11685 -9697 2292 -2897 6289 -7174 -1143 17437 4831 5192 4692 -3273 25731 -5363 5973 10956 17378 -32421 11406 4282 -2114 -11421 -8396 5973 -15335 2464 23426 299 15970 -17019 11549 2085 -4843 22604 -4131 12550 -8989 8319 936 26907 7343 11524 -35194 -16678 13706 8944 -7427 -4359 996 -9130 11984 3338 1178 -11469 11038 -2654 -1394 -1496 25662 -18647 22146 2465 25841 -42774 -16714 3087 1140 -13268 29836 4812 -4198 15804 20167 20970 4379 8273 7726 4290 -1853 29739 20300 -7991 -31885 4534 5352 14705 -4360 -2907 716 17149 8195 -1989 -5550 -2775 13857 -9396 15205 -12717 -17143 1388 -9629 11790 -9325 1519 6069 -12989 -7986 -13248 6518 27813 -11214 -10800 -26096 9540 18000 -24947 -5434 7587 -5456 10242 13924 -5493 13362 316 14039 8563 18119 -7421 3031 3747 14306 8309 19582 -12297 15304 5917 -22212 14993 -481 10412 2938 17418 -21432 1273 -6915 -1995 3494 -6229 -13878 7162 9764 -9893 2041 -2668 5215 -6791 -1031 13350 4277 4640 4219 -3204 19040 -5398 5394 9431 13941 -41401 9291 3659 SO 20181129T070451.0Z 6907.295035 3 1 32.00 2 89.77 138.08 58.31 239.35 0.00 1 0.00 1 0 50 1.306e-01 1.210e-01 9.578e-02 9.217e-02 1.925484e+04 6.983764e+03 8.150106e+02 -6.000000e+00 6.846740e+03 263.77 -2.00 20.00 -2.00 505.23 0.00e+00 2.008464e-03 2.453081e-03 1.576328e-04 -6.000000e+00 3.545554e-03 263.77 -2.00 20.00 -2.00 500.11 0.00e+00 -2.922436e+00 1.916735e+00 1.767385e-01 -6.000000e+00 2.616003e+00 218.17 -2.00 4.26 -2.00 501.73 0.00e+00 20.569 0.226 489.00 513.00 1 1.3034e+00 1.4592e-01 4.5468e-02 -6.0000e+00 1.9934e-01 2.1265e-01 3.7244e-02 4.2427e-03 -6.0000e+00 5.1878e-02 3.4111e-02 -5.6649e-03 7.6342e-03 8.2222e-05 -6.0000e+00 1.2548e-02 -1.0256e-01 7.4839e-04 12 9 8 11 4 0 86.82 24.97 9.30 -0.10256 -0.14185 8 2 1 5 0 4000.000 28.10 15.02 24.97 31313 -16336 15842 6253 466 -2006 -2324 21009 13939 1460 -5594 17503 -1463 13539 -12355 4374 -7835 -29763 2748 -3120 17486 5 1278 -3947 -110 14081 60 -5755 7729 922 9494 -4143 12128 -12007 14859 -18140 3198 13199 -8589 7320 15951 -1296 6530 3069 -15051 7949 -5796 7089 -10857 6151 7914 17433 -5311 21422 549 2474 -7918 14285 1233 -8539 4755 15603 12932 -11812 -1886 3083 28922 27725 7541 -24455 5151 11562 -13455 -2130 -2385 -7655 -8095 -12528 -6048 14494 -14937 -13590 -7399 11257 -10188 31683 21960 7650 12723 19046 9700 1636 17236 -12340 -8004 -4230 1981 7191 -2854 1088 -4086 11686 20572 7014 -12943 2540 5904 -13961 9694 11426 7925 -6689 -17152 -13331 -15057 2482 45400 -558 23343 28170 -5897 9002 2812 2396 -119 37279 -21079 8192 -1138 36800 -13278 -2904 1191 -6792 8590 -1662 2518 2799 -5170 5873 17 4220 2515 7040 -2472 -2707 2295 5583 -14327 8644 22600 -18999 13908 6244 501 -2252 -2661 19378 13754 1596 -6452 15923 -1572 12346 -14361 4342 -8833 -42468 2926 -3560 16369 5 1393 -4551 -122 13629 67 -6640 7661 946 8740 -4343 11130 -14434 14176 -23871 3394 12521 -10016 7229 14463 -1407 6633 3242 -19266 8113 -6755 7180 -12949 6048 7431 14623 -5478 17179 553 2530 -9132 13433 1310 -9976 4869 14550 12359 -14359 -2062 3186 22886 21918 7164 -31124 4908 10343 -15502 -2225 -2526 -8430 -8853 -13927 -6273 12265 -16700 -15070 -7770 9991 -11269 23471 17942 7107 11125 15668 8726 1616 14733 -13973 -8424 -4105 1745 5815 -2495 900 -3536 8786 14790 6086 -14303 2483 5582 -15784 8634 10041 7255 -7161 -20278 -15113 -17296 2416 29425 -574 19182 21789 -6205 7994 2588 2209 -113 24913 -24690 7197 -1093 24304 -14128 -2733 1057 -6479 7105 -1534 2272 2556 -5132 5323 17 3930 2390 6391 -2457 -2675 2123 4895 -14933 7166 SO 20181129T070646.0Z 6907.296366 5 1 32.01 2 89.61 138.50 58.52 239.82 0.00 1 0.00 1 0 19 1.430e-01 1.309e-01 9.642e-02 9.253e-02 -2.404382e+03 5.000813e+03 4.964129e+01 -6.000000e+00 7.494880e+03 263.77 -2.00 20.00 -2.00 505.26 0.00e+00 3.674483e-04 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