File name: Pandora105s1_Helsinki_20200702_L2Fit_fout2c3d20200617p1-8.txt File generation date: 20251122T173950.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v3d20191121.txt Instrument calibration file used: Pandora105s1_CF_v3d20200617.txt Level 1 file used: Pandora105s1_Helsinki_20200702_L1_smca1c3d20200617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20200702 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0131 305.1548 305.2966 305.4383 305.5800 305.7216 305.8633 306.0049 306.1464 306.2880 306.4295 306.5710 306.7124 306.8538 306.9952 307.1366 307.2780 307.4193 307.5606 307.7019 307.8431 307.9843 308.1255 308.2667 308.4078 308.5490 308.6901 308.8311 308.9722 309.1132 309.2542 309.3952 309.5361 309.6771 309.8180 309.9589 310.0997 310.2406 310.3814 310.5222 310.6630 310.8037 310.9445 311.0852 311.2259 311.3666 311.5072 311.6478 311.7884 311.9290 312.0696 312.2102 312.3507 312.4912 312.6317 312.7722 312.9126 313.0531 313.1935 313.3339 313.4743 313.6146 313.7550 313.8953 314.0356 314.1759 314.3162 314.4564 314.5966 314.7369 314.8771 315.0173 315.1574 315.2976 315.4377 315.5778 315.7179 315.8580 315.9981 316.1381 316.2782 316.4182 316.5582 316.6982 316.8382 316.9781 317.1181 317.2580 317.3979 317.5378 317.6777 317.8175 317.9574 318.0972 318.2370 318.3768 318.5166 318.6564 318.7962 318.9359 319.0757 319.2154 319.3551 319.4948 319.6344 319.7741 319.9137 320.0534 320.1930 320.3326 320.4722 320.6118 320.7513 320.8909 321.0304 321.1700 321.3095 321.4490 321.5884 321.7279 321.8674 322.0068 322.1462 322.2857 322.4251 322.5645 322.7038 322.8432 322.9826 323.1219 323.2612 323.4005 323.5398 323.6791 323.8184 323.9577 324.0969 324.2362 324.3754 324.5146 324.6538 324.7930 324.9322 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200702T034658.1Z 7488.157617 217 1 50.23 2 74.64 70.39 122.33 289.87 0.00 1 0.00 1 0 17 2.029e-01 7.896e-03 1.487e-01 4.751e-03 5.360119e-01 2.615328e-03 7.253841e-03 -6.000000e+00 1.221270e-01 234.64 -2.00 4.26 -2.00 320.64 0.00e+00 1.510279e-03 8.367910e-04 4.412196e-04 -6.000000e+00 4.796060e-03 279.35 -2.00 20.00 -2.00 320.30 0.00e+00 3.704 0.001 302.00 328.00 3 3.7345e+00 7.5664e-03 5.1146e-02 -6.0000e+00 3.1168e-01 6.4010e-02 9.3037e-03 3.5028e-02 -6.0000e+00 3.3752e-01 -1.5000e-02 9.4921e-03 1.8181e-02 -6.0000e+00 1.9720e-01 -6.6029e-03 4.9043e-03 5.5560e-03 -6.0000e+00 8.0026e-02 1.6884e-04 -3.7146e-04 1.4012e-04 5.5702e-05 -6.0000e+00 5.3392e-03 7.4314e-03 7.7503e-05 11 9 0 11 8 0 99.95 18.36 -0.09 0.00743 0.00464 67 13 1 5 0 749.600 20.77 15.00 18.36 19.95 15.2 977.72 -47323 -57754 -59374 -77755 -100630 -96397 -70306 -30356 -57710 23931 -73246 -27651 18938 -33624 -31419 -15007 -12168 -6317 -22747 -18415 8761 -5263 -3328 -17930 -15563 6853 -3746 -2720 -20522 -14339 -7160 -3211 8218 -1610 -3897 -3822 -9369 -2736 735 500 -1087 -1147 -356 -1707 3062 3356 1031 -667 1708 1238 -1068 497 3051 3631 3433 2371 2047 -4 1006 -1502 98 591 2189 3999 1317 2085 -512 -925 897 -19 1397 1591 427 461 100 760 -1464 -2497 -850 -1249 -1000 -1323 -2083 -2217 -1356 676 261 153 1395 1854 557 -606 -565 -1522 -314 -1048 10 564 1375 425 -501 -1076 -2095 -526 294 -632 -901 -663 -1087 266 883 770 857 -306 -411 -628 118 -192 62 334 144 -812 437 1058 223 918 -373 -589 1032 419 523 -352 -659 -484 -200 75 -127 251 633 160 137 -220 -864 -352 -562 -648 -1032 -1515 -1347 -820 -274 -793 163 -1323 -342 180 -655 -740 -358 -315 -169 -779 -643 245 -169 -108 -734 -681 256 -160 -112 -978 -658 -349 -177 467 -111 -263 -249 -700 -226 71 58 -145 -164 -53 -266 460 514 164 -110 283 214 -207 106 689 881 881 629 566 -1 280 -421 28 181 739 1481 520 795 -191 -348 361 -9 707 842 228 239 48 329 -597 -1027 -373 -633 -583 -874 -1488 -1663 -1074 562 231 140 1260 1617 460 -479 -419 -1137 -254 -957 10 649 1689 529 -600 -1170 -2143 -538 320 -734 -1093 -846 -1493 392 1411 1270 1424 -492 -619 -910 170 -289 98 554 241 -1323 690 1611 329 1297 -515 -825 1558 709 940 -669 -1297 -985 -435 173 -293 586 1487 372 302 -469 -1792 SS 20200702T040821.8Z 7488.172474 226 1 9.56 2 72.10 74.79 124.72 294.93 0.00 1 0.00 1 0 17 6.364e-02 7.367e-03 3.471e-02 2.384e-03 4.702442e-01 1.276145e-03 6.594504e-03 -6.000000e+00 3.829762e-02 234.64 -2.00 4.26 -2.00 319.32 0.00e+00 1.237331e-03 2.907422e-04 2.436363e-04 -6.000000e+00 1.504117e-03 279.35 -2.00 20.00 -2.00 319.00 0.00e+00 3.210 0.001 302.00 328.00 3 2.5264e+00 3.5223e-03 4.4491e-02 -6.0000e+00 9.7738e-02 4.4308e-02 4.0094e-03 3.0355e-02 -6.0000e+00 1.0584e-01 -1.1491e-02 3.2504e-03 1.5102e-02 -6.0000e+00 6.1841e-02 -4.8072e-03 1.7337e-03 4.3314e-03 -6.0000e+00 2.5093e-02 9.8224e-04 -7.4997e-04 6.7144e-05 4.0207e-05 -6.0000e+00 1.6774e-03 7.3120e-03 2.5286e-05 12 9 1 12 1 1 54.24 18.37 -0.13 0.00731 0.00168 21 23 1 5 0 426.430 20.77 15.00 18.37 20.17 15.1 978.64 -41661 -4631 -25541 -19170 -2884 -16492 -12128 -24189 -16375 -8227 -3038 -25447 -936 -20251 -2092 -5882 -1337 -832 -4343 328 1590 -3566 -5411 -1730 480 667 2246 2684 -3060 -2033 -1892 772 -525 1562 -4851 -3782 -4608 -2765 -1647 -1158 -1425 -2216 95 -2027 1003 -529 2114 -623 -399 -2050 1867 427 2414 475 1071 774 1762 1049 -10 215 -42 1500 1811 3282 2499 623 -1450 -582 210 1285 635 1066 18 586 609 -1245 -1029 -1358 -525 -367 -493 -890 -1576 -2596 -973 -1180 -70 459 754 950 581 127 -760 -237 58 4 -83 851 954 377 -696 -875 -1577 -518 47 -758 -1011 -1092 -654 259 952 860 677 285 -289 -350 118 -188 498 -165 3 -512 432 750 874 647 -271 -94 716 408 325 -251 -597 -568 -202 -76 -350 357 613 213 83 -338 -754 -901 -82 -607 -428 -50 -308 -229 -592 -427 -217 -78 -854 -29 -933 -98 -335 -80 -53 -312 24 119 -281 -443 -148 44 64 218 252 -291 -193 -201 92 -69 220 -695 -515 -685 -475 -343 -275 -380 -636 28 -623 301 -164 645 -197 -128 -688 653 161 966 208 472 354 826 497 -5 99 -20 754 974 1925 1545 373 -837 -331 128 865 459 804 14 441 427 -829 -628 -807 -331 -259 -385 -760 -1471 -2482 -975 -1233 -77 500 821 1034 593 124 -721 -221 57 4 -97 1080 1283 512 -894 -1049 -1805 -598 57 -983 -1330 -1513 -934 390 1509 1385 1078 444 -433 -509 171 -276 773 -266 5 -816 678 1136 1301 930 -383 -134 1080 646 541 -438 -1046 -1019 -377 -146 -691 712 1233 418 159 -634 -1374 SS 20200702T050124.1Z 7488.209307 258 1 2.24 2 65.62 85.88 130.19 308.42 0.00 1 0.00 1 0 25 3.654e-02 1.044e-02 3.537e-02 7.438e-03 3.614192e-01 3.962854e-03 5.193175e-03 -6.000000e+00 2.198671e-02 234.64 -2.00 4.26 -2.00 317.86 0.00e+00 -1.788913e-04 5.898209e-04 1.120837e-04 -6.000000e+00 8.635728e-04 279.35 -2.00 20.00 -2.00 317.52 0.00e+00 2.406 0.000 302.00 328.00 3 3.7309e+00 1.0673e-02 3.3734e-02 -6.0000e+00 5.6111e-02 2.9952e-02 1.1865e-02 2.3191e-02 -6.0000e+00 6.0768e-02 -6.6456e-03 7.5180e-03 1.1303e-02 -6.0000e+00 3.5504e-02 -2.2603e-03 3.7820e-03 3.1233e-03 -6.0000e+00 1.4403e-02 7.3540e-04 -7.9999e-04 2.0827e-04 3.0078e-05 -6.0000e+00 9.6502e-04 8.4277e-03 -3.3180e-06 12 9 9 12 1 1 999.00 18.43 -0.05 0.00843 0.00242 1 9 1 5 0 1028.300 20.77 15.00 18.43 21.57 15.1 985.57 -15982 15908 -8281 -9299 -16491 3538 -8419 6911 -3998 -6909 -1898 -7752 4126 -13001 5663 -2576 947 -4005 3092 -2474 2990 -3024 -1915 -4644 -3493 1292 3234 5033 623 5047 -4748 2889 764 -366 -4131 -3350 -6144 1823 -1937 1759 820 45 1378 -411 1234 1380 -620 76 370 -48 3106 108 1668 -241 1132 96 -839 -1383 230 -1476 -537 2909 1860 2151 3055 790 -999 -3399 -1284 2080 544 1672 10 1846 1027 -335 -1334 -1418 -2522 1442 -689 -1331 -1109 -2778 -2117 -797 -508 357 805 359 732 888 -498 -679 -341 -693 -240 2037 292 341 -792 -128 -2065 -1502 -393 -272 -960 -648 -87 381 299 1211 681 222 -280 -524 -212 -345 553 606 553 -475 327 239 1029 785 -78 -1371 1128 1189 686 288 -541 -726 -64 64 211 864 8 -238 -446 -410 -1085 -1060 901 -622 -693 -1199 201 -559 454 -330 -638 -168 -739 396 -1696 727 -401 151 -698 536 -471 561 -599 -379 -996 -800 299 744 1097 135 1035 -1124 707 209 -106 -1187 -921 -1839 584 -743 751 382 22 684 -209 623 702 -320 38 188 -25 1628 62 988 -151 724 64 -568 -944 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