File name: Pandora105s1_Helsinki_20200703_L2Fit_fout2c3d20200617p1-8.txt File generation date: 20251122T174223.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v3d20191121.txt Instrument calibration file used: Pandora105s1_CF_v3d20200617.txt Level 1 file used: Pandora105s1_Helsinki_20200703_L1_smca1c3d20200617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20200703 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0131 305.1548 305.2966 305.4383 305.5800 305.7216 305.8633 306.0049 306.1464 306.2880 306.4295 306.5710 306.7124 306.8538 306.9952 307.1366 307.2780 307.4193 307.5606 307.7019 307.8431 307.9843 308.1255 308.2667 308.4078 308.5490 308.6901 308.8311 308.9722 309.1132 309.2542 309.3952 309.5361 309.6771 309.8180 309.9589 310.0997 310.2406 310.3814 310.5222 310.6630 310.8037 310.9445 311.0852 311.2259 311.3666 311.5072 311.6478 311.7884 311.9290 312.0696 312.2102 312.3507 312.4912 312.6317 312.7722 312.9126 313.0531 313.1935 313.3339 313.4743 313.6146 313.7550 313.8953 314.0356 314.1759 314.3162 314.4564 314.5966 314.7369 314.8771 315.0173 315.1574 315.2976 315.4377 315.5778 315.7179 315.8580 315.9981 316.1381 316.2782 316.4182 316.5582 316.6982 316.8382 316.9781 317.1181 317.2580 317.3979 317.5378 317.6777 317.8175 317.9574 318.0972 318.2370 318.3768 318.5166 318.6564 318.7962 318.9359 319.0757 319.2154 319.3551 319.4948 319.6344 319.7741 319.9137 320.0534 320.1930 320.3326 320.4722 320.6118 320.7513 320.8909 321.0304 321.1700 321.3095 321.4490 321.5884 321.7279 321.8674 322.0068 322.1462 322.2857 322.4251 322.5645 322.7038 322.8432 322.9826 323.1219 323.2612 323.4005 323.5398 323.6791 323.8184 323.9577 324.0969 324.2362 324.3754 324.5146 324.6538 324.7930 324.9322 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200703T032450.3Z 7489.142249 212 1 50.67 2 77.28 65.84 116.00 270.57 0.00 1 0.00 1 0 25 3.014e-01 6.310e-03 7.386e-02 1.235e-03 6.478803e-01 6.868709e-04 8.517170e-03 -6.000000e+00 1.813729e-01 234.66 -2.00 4.26 -2.00 321.17 0.00e+00 1.583533e-03 2.532617e-04 6.801423e-04 -6.000000e+00 7.122867e-03 279.44 -2.00 20.00 -2.00 320.83 0.00e+00 4.416 0.002 302.00 328.00 3 8.4924e-01 2.0518e-03 6.1484e-02 -6.0000e+00 4.6290e-01 3.1704e-02 2.7878e-03 4.2919e-02 -6.0000e+00 5.0128e-01 -3.0265e-02 3.2479e-03 2.3274e-02 -6.0000e+00 2.9287e-01 -9.0698e-04 1.6242e-03 7.4585e-03 -6.0000e+00 1.1884e-01 1.4152e-03 -6.3644e-04 3.5680e-05 7.1125e-05 -6.0000e+00 7.9435e-03 7.2116e-03 2.3621e-05 12 1 1 12 4 4 99.86 4.72 -0.07 0.00721 0.00243 407 79 1 5 0 123.260 20.96 15.00 4.72 21.46 15.4 987.94 -133292 -81654 -115345 -112622 -91061 -127041 -75906 -83264 -65347 -93785 -63557 -79241 -51042 -46344 -24934 -32036 -5744 -34518 -25273 -15620 -17650 -25947 -16289 -13867 -13891 -13515 -17196 -14047 -22934 -11630 -18528 965 -12539 557 -13574 -9146 -12719 -4674 -5370 -1159 -976 -964 -118 -731 752 -1008 1875 -1100 2119 -798 3698 1139 3447 1246 2791 1163 2680 1101 1350 -67 18 2118 2312 3695 2685 1136 -246 -498 -607 1711 941 1406 411 879 -504 -1127 -623 -2089 -1588 -865 -570 -1034 -1283 -2255 -1359 -711 367 109 999 737 676 371 -552 -788 -381 -125 -173 950 1280 540 -399 -1098 -1631 -176 20 -634 -1004 -1074 -618 161 871 837 658 359 -107 -613 -41 -148 367 -97 -169 -677 317 484 772 426 -636 -174 717 398 339 -267 -505 -601 -209 -78 -411 278 621 263 200 -258 -446 -722 -324 -722 -705 -428 -826 -320 -441 -338 -723 -383 -611 -369 -413 -228 -386 -61 -545 -402 -243 -295 -475 -280 -259 -288 -301 -412 -321 -563 -267 -540 28 -492 21 -582 -365 -574 -232 -334 -84 -80 -86 -11 -71 74 -103 192 -120 236 -97 479 171 557 225 530 235 558 235 280 -14 4 480 594 1063 836 350 -75 -155 -208 610 375 586 173 350 -207 -419 -215 -730 -610 -392 -273 -568 -778 -1456 -928 -516 279 86 780 560 481 248 -355 -516 -277 -105 -166 1029 1524 654 -459 -1141 -1547 -166 20 -693 -1150 -1306 -811 234 1282 1306 1033 545 -168 -922 -62 -232 558 -156 -271 -1046 511 757 1161 623 -894 -249 1150 664 620 -519 -1026 -1295 -482 -191 -1024 699 1570 646 466 -566 -945 SS 20200703T033515.4Z 7489.149483 215 1 50.72 2 76.09 67.98 117.25 272.75 0.00 1 0.00 1 0 25 2.216e-01 6.236e-03 4.386e-02 9.266e-04 6.007281e-01 5.084151e-04 8.043773e-03 -6.000000e+00 1.333691e-01 234.66 -2.00 4.26 -2.00 320.88 0.00e+00 1.573056e-03 1.755449e-04 5.475804e-04 -6.000000e+00 5.237777e-03 279.44 -2.00 20.00 -2.00 320.54 0.00e+00 4.064 0.002 302.00 328.00 3 6.7614e-01 1.4829e-03 5.6745e-02 -6.0000e+00 3.4038e-01 2.0840e-02 1.9249e-03 3.9542e-02 -6.0000e+00 3.6862e-01 -1.6074e-02 2.1350e-03 2.1031e-02 -6.0000e+00 2.1537e-01 -5.9078e-03 1.0865e-03 6.5748e-03 -6.0000e+00 8.7364e-02 2.4576e-03 -1.0275e-03 2.6704e-05 6.2457e-05 -6.0000e+00 5.8567e-03 7.7566e-03 -4.4023e-05 12 1 1 12 4 4 85.09 4.86 -0.07 0.00776 0.00004 651 126 1 5 0 77.070 20.96 15.00 4.86 22.36 15.4 993.32 -93477 -83841 -40804 -63615 -72776 -83692 -82961 -85230 -52569 -56989 -55435 -37557 -54456 -42044 -28543 -19641 -12201 -15923 -15246 -12118 -11413 -5531 -14046 -11501 -9112 -9674 -9059 -9129 -11764 -16286 -7800 -7121 -759 -2416 -5487 -9793 -5804 -6235 -1723 -3224 -2133 -1702 -183 292 55 492 1137 528 730 -989 1966 1513 1888 2253 1751 2244 1723 1708 391 1189 218 1782 2193 3150 2601 286 -492 -1126 -192 1200 902 775 501 285 337 -980 -1023 -2069 -1077 -795 -845 -690 -1384 -2214 -1381 -925 13 403 911 1235 592 494 -625 -361 -118 181 -35 826 1187 395 -352 -1076 -1428 -124 192 -747 -906 -1192 -658 91 865 746 626 235 -77 -517 -14 -73 185 45 -252 -600 209 468 701 662 -690 -205 738 536 366 -251 -589 -614 -164 -77 -321 248 610 204 229 -193 -452 -557 -553 -195 -391 -454 -560 -592 -724 -375 -474 -476 -292 -615 -536 -400 -305 -200 -299 -313 -258 -255 -117 -334 -294 -251 -288 -278 -275 -355 -534 -274 -297 -35 -125 -283 -511 -317 -407 -133 -306 -227 -195 -22 36 7 63 147 71 102 -148 316 275 374 484 402 536 431 431 97 289 55 482 668 974 861 94 -157 -404 -68 488 408 368 239 130 142 -415 -401 -814 -461 -363 -449 -416 -922 -1565 -1032 -737 10 346 781 1024 463 361 -437 -254 -92 161 -36 946 1491 504 -425 -1178 -1430 -125 208 -867 -1099 -1535 -910 127 1325 1208 1014 367 -113 -794 -21 -107 287 73 -414 -955 318 753 1086 992 -996 -299 1201 900 671 -487 -1193 -1315 -375 -171 -733 571 1416 462 532 -424 -959 SS 20200703T034200.4Z 7489.154171 219 1 50.72 2 75.31 69.37 118.06 274.17 0.00 1 0.00 1 0 25 1.682e-01 6.182e-03 3.267e-02 7.823e-04 5.723941e-01 4.296161e-04 7.762024e-03 -6.000000e+00 1.012339e-01 234.66 -2.00 4.26 -2.00 320.68 0.00e+00 1.141867e-03 1.401339e-04 4.721728e-04 -6.000000e+00 3.975710e-03 279.44 -2.00 20.00 -2.00 320.34 0.00e+00 3.862 0.001 302.00 328.00 3 6.2010e-01 1.2323e-03 5.3992e-02 -6.0000e+00 2.5836e-01 1.6184e-02 1.5540e-03 3.7557e-02 -6.0000e+00 2.7981e-01 -9.5708e-03 1.6596e-03 1.9693e-02 -6.0000e+00 1.6348e-01 -8.4194e-03 8.5417e-04 6.0490e-03 -6.0000e+00 6.6312e-02 3.2429e-03 -1.0420e-03 2.2677e-05 6.0008e-05 -6.0000e+00 4.4458e-03 7.7729e-03 -5.4126e-05 12 1 1 12 4 4 52.38 5.48 -0.06 0.00777 -0.00006 759 147 1 5 0 66.110 20.96 15.01 5.48 22.91 15.4 995.39 -73408 -49673 -52723 -42256 -58015 -47281 -68906 -40978 -54738 -32393 -67668 -29280 -43299 -23835 -21905 -12508 -17136 -7179 -6341 -3722 -7276 -11092 -5539 -8538 -6186 -10305 -4049 -12643 -6745 -11413 -3416 -7120 -1074 -775 -3506 -7984 -5720 -6094 -2357 -202 -1499 305 -686 1207 -481 1086 91 1022 33 359 214 2495 1427 2259 2170 1678 1915 885 837 -487 690 1003 1959 2690 2268 -460 -635 -1388 -68 1049 929 997 272 418 155 -568 -1113 -2032 -1426 -146 -957 -437 -1697 -2092 -1410 -674 -52 289 844 1066 753 495 -501 -579 149 62 -91 736 1367 329 -217 -1175 -1444 -264 467 -746 -881 -1078 -587 124 788 786 486 337 -111 -455 -23 -30 117 57 -291 -676 249 482 728 558 -513 -170 742 384 476 -269 -530 -647 -148 -132 -344 226 620 186 259 -157 -390 -487 -315 -382 -280 -416 -292 -568 -297 -530 -279 -867 -275 -568 -325 -366 -229 -370 -154 -148 -91 -193 -307 -150 -262 -204 -381 -145 -483 -236 -432 -138 -354 -59 -46 -208 -480 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