File name: Pandora105s1_Helsinki_20200708_L2Fit_fout2c3d20200617p1-8.txt File generation date: 20251122T174056.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v3d20191121.txt Instrument calibration file used: Pandora105s1_CF_v3d20200617.txt Level 1 file used: Pandora105s1_Helsinki_20200708_L1_smca1c3d20200617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20200708 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0131 305.1548 305.2966 305.4383 305.5800 305.7216 305.8633 306.0049 306.1464 306.2880 306.4295 306.5710 306.7124 306.8538 306.9952 307.1366 307.2780 307.4193 307.5606 307.7019 307.8431 307.9843 308.1255 308.2667 308.4078 308.5490 308.6901 308.8311 308.9722 309.1132 309.2542 309.3952 309.5361 309.6771 309.8180 309.9589 310.0997 310.2406 310.3814 310.5222 310.6630 310.8037 310.9445 311.0852 311.2259 311.3666 311.5072 311.6478 311.7884 311.9290 312.0696 312.2102 312.3507 312.4912 312.6317 312.7722 312.9126 313.0531 313.1935 313.3339 313.4743 313.6146 313.7550 313.8953 314.0356 314.1759 314.3162 314.4564 314.5966 314.7369 314.8771 315.0173 315.1574 315.2976 315.4377 315.5778 315.7179 315.8580 315.9981 316.1381 316.2782 316.4182 316.5582 316.6982 316.8382 316.9781 317.1181 317.2580 317.3979 317.5378 317.6777 317.8175 317.9574 318.0972 318.2370 318.3768 318.5166 318.6564 318.7962 318.9359 319.0757 319.2154 319.3551 319.4948 319.6344 319.7741 319.9137 320.0534 320.1930 320.3326 320.4722 320.6118 320.7513 320.8909 321.0304 321.1700 321.3095 321.4490 321.5884 321.7279 321.8674 322.0068 322.1462 322.2857 322.4251 322.5645 322.7038 322.8432 322.9826 323.1219 323.2612 323.4005 323.5398 323.6791 323.8184 323.9577 324.0969 324.2362 324.3754 324.5146 324.6538 324.7930 324.9322 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200708T022734.4Z 7494.102482 149 1 50.81 2 83.95 54.05 81.50 201.93 0.00 1 0.00 1 0 41 5.075e-01 2.970e-02 4.124e-01 2.646e-02 1.004492e+00 1.662015e-02 1.284039e-02 -6.000000e+00 3.157209e-01 234.74 -2.00 4.26 -2.00 322.36 0.00e+00 1.913133e-03 6.838868e-03 1.481440e-03 -6.000000e+00 1.314012e-02 279.93 -2.00 20.00 -2.00 321.96 0.00e+00 8.474 0.016 302.00 328.00 3 9.3021e-01 5.4076e-02 1.0833e-01 -6.0000e+00 8.0921e-01 1.7090e+00 6.5552e-02 6.5737e-02 -6.0000e+00 8.8181e-01 -1.9147e+00 5.7510e-02 3.4680e-02 -6.0000e+00 5.1175e-01 6.9849e-01 3.0412e-02 1.1328e-02 -6.0000e+00 2.0642e-01 1.4930e-05 -1.8384e-03 7.4641e-04 1.5018e-04 -6.0000e+00 1.4383e-02 1.3383e-02 -1.7027e-04 12 9 9 12 4 4 99.75 6.84 0.28 0.01338 -0.00043 24 5 1 5 0 2116.950 20.67 15.00 6.84 18.73 15.4 978.07 900000 157561 58554 -66420 900000 -75563 -25072 22611 900000 -38095 -49425 56672 -83067 -74543 -35977 900000 29586 900000 -31436 900000 40444 70421 -26142 -17554 -9876 900000 -4893 -7817 900000 -68044 900000 -924 306582 -2348 900000 -17134 900000 -34062 51432 175325 205752 21535 -15885 74378 70232 178266 -1292 900000 -17712 47281 -4688 13910 8340 60565 -761 16443 29768 43397 3961 38419 12272 16958 75745 28846 43694 -24902 23811 36768 38696 -903 47925 36950 6230 -2804 27392 2346 21979 16079 -6905 2839 -3250 -6385 6516 4802 6281 13487 3316 9915 -3274 6449 -3045 7626 -16774 -11898 -5063 -3459 151 -174 801 -3719 744 -3860 -1202 -12798 -553 -6176 -92 -823 -352 -3127 750 -926 -2 -1759 -209 -2812 -566 1772 -1559 771 349 1059 198 5807 3676 2422 2521 388 -995 1424 2072 -224 -337 784 173 -490 612 -1126 1217 336 -74 -1310 -1935 900000 4057 1508 -3563 900000 -3360 -646 582 900000 -1159 -1620 1459 -4666 -4711 -1853 900000 969 900000 -1987 900000 1136 1813 -1224 -781 -416 900000 -183 -274 900000 -4141 900000 -41 7894 -126 900000 -882 900000 -2392 1986 4514 5297 1311 -1413 2872 2712 4590 -91 900000 -1575 2556 -428 1289 880 4054 -89 1820 2912 3575 449 2869 1169 1659 4680 3268 4612 -4663 3004 4260 4882 -195 6910 6089 1347 -606 3879 374 2716 2194 -1369 621 -895 -2104 2097 1657 2248 4722 1341 3829 -1425 2441 -1184 2533 -7040 -5085 -2359 -1897 94 -127 652 -3227 579 -2773 -743 -8798 -365 -4548 -67 -652 -312 -3341 892 -1232 -2 -2446 -277 -3722 -745 2399 -2316 1155 509 1436 260 7072 4477 2919 2934 490 -1514 2494 4086 -492 -797 1983 433 -1306 1638 -3098 3271 955 -196 -3204 -4529 SS 20200708T023853.1Z 7494.110337 152 1 50.27 2 82.80 56.42 82.01 204.51 0.00 1 0.00 1 0 25 4.405e-01 2.527e-02 3.730e-01 1.738e-02 9.590185e-01 1.107274e-02 1.235951e-02 -6.000000e+00 2.747973e-01 234.74 -2.00 4.26 -2.00 322.27 0.00e+00 7.241785e-03 4.808113e-03 1.498053e-03 -6.000000e+00 1.226882e-02 279.93 -2.00 20.00 -2.00 321.90 0.00e+00 7.343 0.010 302.00 328.00 3 1.5683e+00 3.6212e-02 9.7927e-02 -6.0000e+00 7.0646e-01 1.1674e+00 4.9172e-02 6.3927e-02 -6.0000e+00 7.7022e-01 -1.3127e+00 5.2815e-02 3.4382e-02 -6.0000e+00 4.4014e-01 4.9997e-01 2.5804e-02 1.1346e-02 -6.0000e+00 1.7763e-01 2.5045e-05 -2.8507e-03 5.0695e-04 1.4955e-04 -6.0000e+00 1.2862e-02 1.1385e-02 -3.6113e-05 12 9 9 12 4 4 99.61 6.60 0.04 0.01139 -0.01004 29 6 1 5 0 1732.970 20.67 15.00 6.60 18.87 15.4 979.48 900000 -109560 -98282 28012 900000 900000 900000 -66767 900000 900000 -154633 900000 147334 900000 -45597 900000 -88886 -49511 -90288 900000 -72603 900000 -61048 900000 -15003 -43467 2118 122592 -13847 -121234 900000 -44129 15876 -67602 900000 -54822 900000 -14871 900000 23302 102133 15856 132770 84558 32310 -2520 18147 59317 14007 83019 -744 39808 34066 98434 -2142 113859 17301 40199 4661 27483 24768 20626 15248 14653 24243 39310 60522 -2746 46113 -3053 23676 6410 24743 9455 24393 12877 8231 555 10382 8810 6347 14729 -4935 3053 -6852 2881 -5413 5049 -4002 2810 -1733 3587 -11595 2752 -5723 -1636 -20 -1582 97 133 707 -5519 3460 -5647 -921 -4961 -330 -6295 -2509 -2005 550 -172 1166 318 -1263 -1290 -1628 677 -1624 1412 -1298 2056 462 2972 827 5023 1295 1360 -348 1357 2057 743 -276 -1168 714 -98 1207 -959 683 -910 117 -496 -1636 900000 -2041 -1756 473 900000 900000 900000 -1128 900000 900000 -3767 900000 2490 900000 -844 900000 -3388 -1398 -4009 900000 -2713 900000 -1842 900000 -312 -1195 37 2072 -260 -6772 900000 -1779 419 -4379 900000 -2746 900000 -591 900000 879 1985 752 2244 2161 1362 -150 909 2080 802 2613 -59 2392 2338 3930 -237 4262 1669 3061 473 2133 1969 1855 1640 1839 3042 4228 5303 -461 5368 -659 4367 1438 4579 1886 3806 1991 1248 94 1826 1899 1671 4140 -1865 1126 -2943 1186 -2538 2193 -1893 1199 -725 1361 -5013 1086 -2805 -921 -13 -1213 83 116 588 -4333 2210 -3865 -649 -3808 -253 -5508 -2355 -2173 662 -230 1590 435 -1697 -1694 -2164 923 -2403 2077 -1940 2785 607 3770 1046 5942 1530 1673 -511 2278 3877 1523 -610 -2799 1793 -261 3241 -2654 1864 -2447 289 -1141 -3596 SS 20200708T025020.2Z 7494.118289 156 1 50.39 2 81.60 58.80 82.58 207.11 0.00 1 0.00 1 0 25 7.020e-01 1.592e-02 3.734e-01 7.459e-03 8.609640e-01 4.538491e-03 1.100652e-02 -6.000000e+00 4.281813e-01 234.74 -2.00 4.26 -2.00 322.17 0.00e+00 4.600699e-03 2.004691e-03 1.366634e-03 -6.000000e+00 1.764523e-02 279.93 -2.00 20.00 -2.00 321.81 0.00e+00 6.432 0.007 302.00 328.00 3 1.3467e+00 1.4927e-02 8.6789e-02 -6.0000e+00 1.0945e+00 4.6231e-01 2.3513e-02 5.8797e-02 -6.0000e+00 1.1884e+00 -6.1462e-01 2.8084e-02 3.2935e-02 -6.0000e+00 6.9432e-01 2.4954e-01 1.3109e-02 1.1073e-02 -6.0000e+00 2.8072e-01 9.9746e-05 -2.0853e-03 2.2169e-04 1.3381e-04 -6.0000e+00 1.8732e-02 1.1272e-02 -8.7458e-05 12 9 9 12 4 4 99.92 6.95 0.05 0.01127 -0.00440 107 21 1 5 0 470.890 20.77 15.00 6.95 19.34 15.5 982.66 -301513 900000 -164718 -94892 56004 -180957 -272625 -166263 -208472 13290 -162071 -262148 900000 -45252 -3709 -111987 900000 -33779 900000 -118513 -271 -121318 900000 -58100 -59467 -45358 900000 -18509 119091 8315 -39908 3745 -3365 97053 -67546 39599 -53587 351799 -32109 53842 5981 49468 13578 57795 17363 46623 39057 -6760 51361 -3790 42302 8925 33836 18040 32935 8355 31873 14791 29651 -8639 22699 8255 11222 13794 11147 12954 6172 7074 5661 12434 2423 7471 3849 9979 5112 5081 1074 405 -2117 4343 3398 -1118 367 -516 -707 -3004 -70 632 3067 -36 4196 323 737 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