File name: Pandora105s1_Helsinki_20200709_L2Fit_fout2c3d20200617p1-8.txt File generation date: 20251122T174252.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v3d20191121.txt Instrument calibration file used: Pandora105s1_CF_v3d20200617.txt Level 1 file used: Pandora105s1_Helsinki_20200709_L1_smca1c3d20200617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20200709 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0131 305.1548 305.2966 305.4383 305.5800 305.7216 305.8633 306.0049 306.1464 306.2880 306.4295 306.5710 306.7124 306.8538 306.9952 307.1366 307.2780 307.4193 307.5606 307.7019 307.8431 307.9843 308.1255 308.2667 308.4078 308.5490 308.6901 308.8311 308.9722 309.1132 309.2542 309.3952 309.5361 309.6771 309.8180 309.9589 310.0997 310.2406 310.3814 310.5222 310.6630 310.8037 310.9445 311.0852 311.2259 311.3666 311.5072 311.6478 311.7884 311.9290 312.0696 312.2102 312.3507 312.4912 312.6317 312.7722 312.9126 313.0531 313.1935 313.3339 313.4743 313.6146 313.7550 313.8953 314.0356 314.1759 314.3162 314.4564 314.5966 314.7369 314.8771 315.0173 315.1574 315.2976 315.4377 315.5778 315.7179 315.8580 315.9981 316.1381 316.2782 316.4182 316.5582 316.6982 316.8382 316.9781 317.1181 317.2580 317.3979 317.5378 317.6777 317.8175 317.9574 318.0972 318.2370 318.3768 318.5166 318.6564 318.7962 318.9359 319.0757 319.2154 319.3551 319.4948 319.6344 319.7741 319.9137 320.0534 320.1930 320.3326 320.4722 320.6118 320.7513 320.8909 321.0304 321.1700 321.3095 321.4490 321.5884 321.7279 321.8674 322.0068 322.1462 322.2857 322.4251 322.5645 322.7038 322.8432 322.9826 323.1219 323.2612 323.4005 323.5398 323.6791 323.8184 323.9577 324.0969 324.2362 324.3754 324.5146 324.6538 324.7930 324.9322 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200709T020827.6Z 7495.089209 146 1 49.26 2 85.95 50.05 75.73 186.79 0.00 1 0.00 1 0 25 6.626e-01 1.080e-01 4.908e-01 1.064e-01 1.067898e+00 6.233306e-02 1.349176e-02 -6.000000e+00 4.059198e-01 234.76 -2.00 4.26 -2.00 320.84 0.00e+00 -2.258198e-02 1.247254e-02 4.374492e-04 -6.000000e+00 1.681726e-02 280.03 -2.00 20.00 -2.00 320.22 0.00e+00 11.327 0.038 302.00 328.00 3 -8.7187e-01 1.7472e-01 1.3420e-01 -6.0000e+00 1.0435e+00 3.0980e+00 2.0210e-01 6.3816e-02 -6.0000e+00 1.1372e+00 -2.1988e+00 1.1982e-01 3.1294e-02 -6.0000e+00 6.5847e-01 5.2725e-01 6.0801e-02 9.3785e-03 -6.0000e+00 2.6341e-01 3.4158e-06 7.4320e-03 2.6035e-03 7.6589e-05 -6.0000e+00 1.7955e-02 1.3345e-02 -9.6912e-05 12 9 9 12 12 4 51.95 4.00 1.18 0.01334 0.06919 13 3 1 5 0 3740.540 20.56 15.01 4.00 17.96 15.5 975.21 -5364 52376 119346 900000 119962 -58211 198420 -6146 900000 -48330 89002 -19472 900000 88996 96437 55858 900000 109741 56281 900000 900000 900000 -27818 314238 46100 161238 -3992 5934 -35700 -51624 -31116 33125 900000 -43509 217288 900000 -59605 13325 32980 64282 42535 23019 38005 48945 121156 -58315 46776 -29705 196569 133872 323212 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5300 8697 -673 16974 1067 -7861 12262 -2981 14463 9162 10942 -801 11701 -1953 1113 6538 3922 -5458 -2652 8472 -3697 12460 -1828 -8064 -5393 5522 10319 -1820 12297 -14765 -367 -6416 22443 3483 8558 8155 -2208 -5940 2886 3232 4101 15529 -4726 -1965 -2425 -25735 -14728 2440 13137 -6383 3537 9775 -7148 2068 -5024 -10595 -11664 -16124 12251 4883 3761 16445 -1189 -8562 13788 SS 20200709T022059.4Z 7495.097910 149 1 50.80 2 84.73 52.69 75.92 189.83 0.00 1 0.00 1 0 17 4.994e-01 3.747e-02 4.751e-01 3.687e-02 1.155918e+00 2.322391e-02 1.474460e-02 -6.000000e+00 3.025933e-01 234.76 -2.00 4.26 -2.00 322.49 0.00e+00 -1.986545e-02 8.133436e-03 1.312550e-03 -6.000000e+00 1.241980e-02 280.03 -2.00 20.00 -2.00 322.06 0.00e+00 9.427 0.022 302.00 328.00 3 -2.8693e-02 7.6363e-02 1.2141e-01 -6.0000e+00 7.7182e-01 2.2834e+00 8.9525e-02 7.3055e-02 -6.0000e+00 8.3669e-01 -2.4769e+00 6.1776e-02 3.7970e-02 -6.0000e+00 4.8954e-01 8.7161e-01 3.4909e-02 1.2203e-02 -6.0000e+00 1.9977e-01 1.2796e-05 -1.6342e-03 9.5690e-04 1.5263e-04 -6.0000e+00 1.3438e-02 1.4463e-02 -1.5725e-04 12 9 9 12 4 4 -67.21 3.82 0.20 0.01446 0.00218 42 8 1 5 0 1209.330 20.56 14.98 3.82 18.62 15.5 978.80 23607 257873 900000 -3148 -59915 -46983 -12139 -56297 -27296 -48544 34138 -9576 900000 2172 900000 52219 109182 96270 55896 34517 12969 123904 174095 66887 -60225 47199 20017 900000 -31881 -15365 34169 79678 27024 -4188 81234 900000 -2313 38142 106388 48379 70658 59881 50043 -3171 10439 -13860 -1993 900000 16547 137969 119824 98919 75719 159599 83084 15814 4665 -1590 -6853 -4902 -14841 21243 7053 26842 -2884 105257 40623 26929 58633 38675 41617 36584 68382 17501 37643 -13034 -16904 -39687 18343 7969 21243 -6585 13959 7265 -7981 5302 10672 12721 3876 1616 -24526 -2780 -6987 1902 -17043 6215 -4444 2526 -7186 594 -7538 -1616 -5788 2737 4177 -8401 2780 -8377 180 4923 552 -2136 3724 -2415 2546 -4732 -185 -1094 -179 -160 3063 -326 5952 5175 3968 1923 -2208 573 -859 778 -801 1637 -1419 -515 -222 -811 35 1461 2752 -421 -973 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0.00e+00 -2.030143e-03 4.411453e-03 1.963597e-03 -6.000000e+00 1.619342e-02 280.03 -2.00 20.00 -2.00 322.22 0.00e+00 8.232 0.014 302.00 328.00 3 2.0527e-01 3.3412e-02 1.1122e-01 -6.0000e+00 9.5268e-01 1.5133e+00 4.4653e-02 7.3339e-02 -6.0000e+00 1.0332e+00 -1.9455e+00 4.3913e-02 4.0173e-02 -6.0000e+00 5.9876e-01 7.6390e-01 2.1844e-02 1.3587e-02 -6.0000e+00 2.4246e-01 4.0051e-05 -3.1919e-03 4.2903e-04 1.8801e-04 -6.0000e+00 1.7355e-02 1.4106e-02 -1.2680e-04 12 9 9 12 4 4 -28.23 3.71 0.08 0.01411 -0.00988 86 17 1 5 0 586.460 20.56 14.98 3.71 19.00 15.5 980.29 -114149 21889 241388 -57563 900000 -103345 900000 -130853 900000 -147410 900000 -102057 -16347 133535 261685 81893 214998 -195 -8896 80037 -17075 900000 -35787 164984 -72244 211782 -12317 900000 -45899 40309 -16084 -6517 82085 -6871 -35600 -3039 142435 -45266 900000 -2860 129515 -14473 93913 -6887 74061 29362 84120 24891 69754 15674 56504 64824 53517 64574 16160 39860 13456 67799 17784 68160 14811 79177 25167 44103 35992 34423 -3135 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