File name: Pandora25s1_HoustonTX_20210609_L2Fit_fout2c5d20210307p1-8.txt File generation date: 20250922T132012.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora25_OF_v6d20190903.txt Instrument calibration file used: Pandora25s1_CF_v5d20210307.txt Level 1 file used: Pandora25s1_HoustonTX_20210609_L1_smca1c5d20210307p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20210609 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.0981 305.2388 305.3795 305.5202 305.6609 305.8015 305.9421 306.0828 306.2234 306.3640 306.5045 306.6451 306.7857 306.9262 307.0667 307.2072 307.3477 307.4882 307.6287 307.7691 307.9096 308.0500 308.1904 308.3308 308.4712 308.6115 308.7519 308.8922 309.0326 309.1729 309.3132 309.4535 309.5937 309.7340 309.8742 310.0144 310.1547 310.2949 310.4350 310.5752 310.7154 310.8555 310.9956 311.1358 311.2759 311.4160 311.5560 311.6961 311.8361 311.9762 312.1162 312.2562 312.3962 312.5362 312.6761 312.8161 312.9560 313.0959 313.2359 313.3758 313.5156 313.6555 313.7954 313.9352 314.0750 314.2148 314.3546 314.4944 314.6342 314.7740 314.9137 315.0535 315.1932 315.3329 315.4726 315.6123 315.7519 315.8916 316.0312 316.1709 316.3105 316.4501 316.5897 316.7292 316.8688 317.0083 317.1479 317.2874 317.4269 317.5664 317.7059 317.8454 317.9848 318.1243 318.2637 318.4031 318.5425 318.6819 318.8213 318.9606 319.1000 319.2393 319.3787 319.5180 319.6573 319.7965 319.9358 320.0751 320.2143 320.3536 320.4928 320.6320 320.7712 320.9104 321.0495 321.1887 321.3278 321.4670 321.6061 321.7452 321.8843 322.0234 322.1624 322.3015 322.4405 322.5796 322.7186 322.8576 322.9966 323.1356 323.2745 323.4135 323.5524 323.6914 323.8303 323.9692 324.1081 324.2469 324.3858 324.5247 324.6635 324.8023 324.9411 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210609T121054.7Z 7830.507577 110 1 51.37 2 80.83 68.71 73.24 74.82 0.00 1 0.00 1 0 17 1.703e-01 2.458e-02 1.956e-02 2.669e-03 3.585607e-01 1.360430e-03 3.937387e-03 -6.000000e+00 9.863176e-02 230.95 -2.00 3.24 -2.00 318.53 0.00e+00 5.642722e-03 2.827190e-04 3.055719e-04 -6.000000e+00 4.475866e-03 292.14 -2.00 20.00 -2.00 317.63 0.00e+00 5.953 0.002 302.00 328.00 3 1.7646e+00 3.7385e-03 6.1521e-02 -6.0000e+00 2.4615e-01 3.8515e-01 4.2847e-03 1.8760e-02 -6.0000e+00 2.6615e-01 -1.0174e-01 2.7619e-03 9.1320e-03 -6.0000e+00 1.5903e-01 4.4759e-02 1.4216e-03 5.0826e-03 -6.0000e+00 6.7831e-02 1.5440e-04 -1.0709e-03 7.6724e-05 4.7690e-05 -6.0000e+00 4.6395e-03 -2.7295e-03 -5.9973e-05 12 8 8 10 0 0 99.96 23.77 0.47 -0.00273 -0.01078 18 4 1 5 0 2819.390 26.32 20.00 23.77 35.18 21.2 1037.50 -128064 57015 35710 58317 7251 21171 71667 16804 35005 18458 333 15643 -10292 6724 16358 48366 18886 23210 23922 28815 18965 18665 11048 12591 -1811 2657 5381 14013 3522 -2658 13995 13301 10231 8491 9658 6122 9671 9252 -925 -1623 -1612 1591 4377 2001 3921 4767 111 -150 5840 3312 5166 691 1180 1476 1638 444 1358 -1763 -808 -1995 -324 90 679 1538 -382 -760 -1574 -931 366 685 -682 17 -704 178 -77 -1748 -4154 -1151 702 -1587 -1326 -1484 -2598 -157 -1786 -1994 -340 -822 -835 839 -213 -730 -940 -595 -693 295 -792 662 1319 59 175 -1692 -906 -1071 -476 -556 -454 -254 550 128 1081 1108 407 -130 -510 -370 -163 -364 367 466 605 1396 1095 1506 1070 1252 468 1112 277 1379 314 145 -296 278 -442 -259 -149 234 -265 -573 -434 -1418 -973 -23658 2065 1614 1989 360 894 1990 855 1619 1022 22 955 -944 626 1627 3962 2169 2707 2901 3463 2517 2453 1588 1856 -315 455 894 2058 552 -457 2282 2421 2091 1794 1905 1241 2077 2305 -295 -590 -631 632 1755 831 1619 1972 48 -64 2380 1412 2302 342 613 800 909 253 776 -1028 -461 -1151 -191 57 461 1100 -278 -527 -1050 -616 255 527 -566 14 -599 146 -59 -1256 -2841 -755 481 -1231 -1132 -1373 -2552 -157 -1902 -2235 -390 -969 -986 954 -231 -747 -914 -572 -704 323 -950 850 1762 79 225 -2066 -1055 -1271 -594 -722 -610 -353 792 194 1706 1775 645 -199 -743 -519 -228 -525 550 726 954 2168 1672 2236 1542 1749 637 1516 400 2087 498 236 -491 473 -785 -474 -278 439 -502 -1071 -790 -2527 -1697 SS 20210609T122124.8Z 7830.514870 125 1 49.56 2 78.70 69.87 71.09 75.87 0.00 1 0.00 1 0 17 3.610e-02 6.846e-03 9.847e-03 1.952e-03 3.405155e-01 9.972464e-04 3.708883e-03 -6.000000e+00 2.091154e-02 230.95 -2.00 3.24 -2.00 318.03 0.00e+00 6.280831e-04 1.798974e-04 1.094594e-04 -6.000000e+00 9.484442e-04 292.15 -2.00 20.00 -2.00 317.12 0.00e+00 4.926 0.001 302.00 328.00 3 2.2967e+00 2.6934e-03 5.1528e-02 -6.0000e+00 5.2189e-02 2.6356e-01 3.0593e-03 1.7016e-02 -6.0000e+00 5.6420e-02 -2.0270e-02 1.9351e-03 7.9780e-03 -6.0000e+00 3.3713e-02 -2.3736e-03 9.9318e-04 2.2339e-03 -6.0000e+00 1.4387e-02 2.6057e-04 -3.5435e-04 5.6118e-05 2.4251e-05 -6.0000e+00 9.8284e-04 -3.5379e-03 3.5851e-05 11 8 0 10 0 0 82.81 23.77 0.43 -0.00354 -0.00620 21 4 1 5 0 2359.760 26.32 20.01 23.77 35.73 21.2 1039.77 -16845 11670 -3393 13745 -5968 -3659 20885 -578 10134 -3737 -10744 -1694 -10149 -5511 -325 -1909 -1075 2874 104 6138 2470 3605 -2424 2997 -2534 -766 -5446 5045 -830 -4301 1497 1640 1659 -1729 -6070 -3011 2824 672 -1002 -637 -1518 -391 1632 256 376 1181 -2207 -2879 89 564 1282 51 -77 1118 1220 1206 1709 572 180 -647 1259 -218 1447 364 479 -447 -1042 -766 1386 606 494 748 415 1119 937 -298 -2488 -451 -595 -752 -876 -1058 -1652 239 -872 -1022 113 74 -210 753 639 185 -73 17 28 -517 288 742 901 -126 -14 -1038 -919 -388 -439 -452 -401 -708 -87 547 543 517 23 -59 -354 -364 87 -408 -231 46 -129 362 226 522 620 574 -60 375 326 622 -83 39 -465 403 -366 -94 161 496 101 -93 -225 -608 -389 -1210 701 -240 773 -367 -218 1072 -41 717 -314 -967 -150 -1116 -675 -44 -285 -169 458 18 1033 436 629 -463 580 -543 -167 -1233 988 -164 -890 319 383 420 -459 -1587 -767 751 211 -374 -269 -694 -184 777 124 183 572 -1090 -1417 43 275 659 28 -45 674 756 763 1092 368 114 -413 814 -152 1065 284 374 -333 -747 -547 1034 499 433 673 373 972 771 -229 -1819 -318 -442 -614 -782 -1017 -1672 247 -953 -1171 133 88 -253 878 709 194 -73 16 29 -580 347 953 1203 -168 -18 -1265 -1079 -463 -550 -589 -538 -981 -124 817 844 814 36 -88 -505 -501 119 -577 -340 70 -199 553 339 765 881 792 -81 507 460 923 -128 62 -749 662 -626 -165 289 897 184 -168 -395 -1045 -657 SS 20210609T122601.5Z 7830.518073 131 1 49.05 2 77.76 70.37 70.14 76.33 0.00 1 0.00 1 0 17 2.473e-02 6.374e-03 7.684e-03 1.777e-03 3.256133e-01 9.113606e-04 3.560730e-03 -6.000000e+00 1.433018e-02 230.95 -2.00 3.24 -2.00 317.86 0.00e+00 3.498712e-04 1.566180e-04 1.207271e-04 -6.000000e+00 6.539447e-04 292.15 -2.00 20.00 -2.00 316.94 0.00e+00 4.576 0.001 302.00 328.00 3 2.5001e+00 2.4504e-03 4.8018e-02 -6.0000e+00 3.5762e-02 2.2229e-01 2.7757e-03 1.6233e-02 -6.0000e+00 3.8668e-02 -1.0944e-02 1.7329e-03 7.6239e-03 -6.0000e+00 2.3107e-02 -4.7586e-03 8.8397e-04 2.0923e-03 -6.0000e+00 9.9234e-03 3.0851e-04 -2.3171e-04 5.1329e-05 2.3122e-05 -6.0000e+00 6.7692e-04 -3.9769e-03 4.9766e-05 11 1 0 11 8 0 99.59 23.78 0.42 -0.00398 -0.00572 24 5 1 5 0 2043.230 26.32 19.99 23.78 35.83 21.1 1039.90 900000 8931 -4401 2650 -7813 -6317 11432 91 1655 680 -9573 4757 -13024 -3083 -2604 813 -1262 3006 833 4757 235 -183 747 1199 -2977 -800 375 3297 -1228 -4541 3279 2083 1355 44 -5440 -930 195 790 -2302 -1073 -2082 320 997 277 200 659 -1407 -1700 318 -428 1441 -628 -304 396 1606 588 1524 343 786 -36 811 808 1200 1171 -70 -274 -1049 -1012 686 964 349 852 420 868 734 -444 -1599 -445 307 -667 -765 -842 -1540 -436 -1223 -959 173 187 -104 697 132 401 -375 66 -133 661 -56 988 951 -13 -416 -1082 -577 -787 -514 -653 -646 -626 60 173 573 529 165 96 -241 -421 -122 -378 23 100 -296 329 228 720 361 733 205 511 134 491 10 -102 -281 309 -210 -96 209 504 -123 -317 -89 -480 -399 900000 623 -354 186 -551 -434 723 7 143 62 -958 443 -1636 -409 -393 130 -217 522 154 882 46 -36 151 256 -695 -190 87 712 -263 -1015 738 517 366 12 -1503 -247 56 262 -916 -478 -1003 157 500 140 102 335 -721 -864 158 -218 766 -360 -182 247 1021 384 1003 227 511 -24 541 572 906 928 -56 -208 -766 -736 523 803 310 776 383 766 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