File name: Pandora25s1_HoustonTX_20210723_L2Fit_fout2c5d20210307p1-8.txt File generation date: 20250922T133311.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora25_OF_v6d20190903.txt Instrument calibration file used: Pandora25s1_CF_v5d20210307.txt Level 1 file used: Pandora25s1_HoustonTX_20210723_L1_smca1c5d20210307p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20210723 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.0981 305.2388 305.3795 305.5202 305.6609 305.8015 305.9421 306.0828 306.2234 306.3640 306.5045 306.6451 306.7857 306.9262 307.0667 307.2072 307.3477 307.4882 307.6287 307.7691 307.9096 308.0500 308.1904 308.3308 308.4712 308.6115 308.7519 308.8922 309.0326 309.1729 309.3132 309.4535 309.5937 309.7340 309.8742 310.0144 310.1547 310.2949 310.4350 310.5752 310.7154 310.8555 310.9956 311.1358 311.2759 311.4160 311.5560 311.6961 311.8361 311.9762 312.1162 312.2562 312.3962 312.5362 312.6761 312.8161 312.9560 313.0959 313.2359 313.3758 313.5156 313.6555 313.7954 313.9352 314.0750 314.2148 314.3546 314.4944 314.6342 314.7740 314.9137 315.0535 315.1932 315.3329 315.4726 315.6123 315.7519 315.8916 316.0312 316.1709 316.3105 316.4501 316.5897 316.7292 316.8688 317.0083 317.1479 317.2874 317.4269 317.5664 317.7059 317.8454 317.9848 318.1243 318.2637 318.4031 318.5425 318.6819 318.8213 318.9606 319.1000 319.2393 319.3787 319.5180 319.6573 319.7965 319.9358 320.0751 320.2143 320.3536 320.4928 320.6320 320.7712 320.9104 321.0495 321.1887 321.3278 321.4670 321.6061 321.7452 321.8843 322.0234 322.1624 322.3015 322.4405 322.5796 322.7186 322.8576 322.9966 323.1356 323.2745 323.4135 323.5524 323.6914 323.8303 323.9692 324.1081 324.2469 324.3858 324.5247 324.6635 324.8023 324.9411 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210723T150045.5Z 7874.625526 640 1 51.11 2 47.62 89.39 139.93 265.67 0.00 1 0.00 1 0 17 1.623e-02 8.284e-03 3.019e-03 1.747e-03 1.987028e-01 8.979928e-04 2.215791e-03 -6.000000e+00 9.357698e-03 229.90 -2.00 3.24 -2.00 315.66 0.00e+00 -8.002512e-05 9.139785e-05 5.919651e-05 -6.000000e+00 4.307066e-04 294.33 -2.00 20.00 -2.00 314.83 0.00e+00 1.481 0.000 302.00 328.00 3 5.7523e+00 2.3255e-03 1.7592e-02 -6.0000e+00 2.3273e-02 4.1517e-02 2.5922e-03 9.5095e-03 -6.0000e+00 2.5183e-02 4.2767e-03 1.4851e-03 4.6155e-03 -6.0000e+00 1.5082e-02 -3.8268e-03 6.7627e-04 1.2751e-03 -6.0000e+00 6.4544e-03 3.0593e-04 -3.4380e-06 4.9932e-05 1.6258e-05 -6.0000e+00 4.4226e-04 4.7285e-03 -4.1431e-05 11 9 0 11 32 0 99.79 23.98 0.36 0.00473 0.00470 15 3 1 5 0 3406.860 26.51 19.99 23.98 40.82 22.2 1049.22 9788 1467 -2027 127 -3525 -5296 -7560 291 -1791 -387 -1665 212 -4303 1180 -663 4452 -316 1729 -112 1368 2059 -850 1362 952 288 464 -395 1171 -1420 -989 2178 1458 671 -1452 -3847 -1912 -652 56 317 -800 -863 -1111 169 -386 263 -895 -1428 -1886 61 -651 561 -458 690 831 1975 1318 1204 105 103 524 1010 1028 1288 1759 260 -654 -1361 -1513 665 722 573 931 818 822 798 -191 -1663 -1210 -759 -1803 -938 -1404 -1943 -215 -477 -749 7 413 417 589 196 159 -841 -310 -687 409 372 1198 887 -260 -129 -1145 -646 -680 -833 -205 -407 -697 274 438 806 1028 861 -246 -500 -530 -807 -650 -200 57 -200 150 503 537 514 626 252 303 5 805 32 -311 -384 194 76 -156 346 599 -48 24 -444 -593 -539 2265 383 -541 31 -794 -1192 -1857 74 -502 -109 -465 60 -1384 400 -250 1692 -128 702 -47 585 881 -370 596 435 137 225 -189 523 -612 -421 940 665 324 -708 -1807 -886 -325 31 202 -566 -641 -848 129 -297 201 -686 -1077 -1393 43 -469 416 -357 552 684 1638 1112 1025 90 87 441 869 928 1219 1709 251 -595 -1181 -1297 591 694 581 963 844 828 766 -172 -1408 -989 -640 -1649 -918 -1460 -2101 -237 -551 -905 9 520 524 721 229 175 -878 -316 -727 456 442 1499 1144 -333 -159 -1349 -740 -801 -1031 -261 -534 -940 377 623 1173 1496 1222 -335 -647 -661 -1006 -832 -267 79 -282 210 693 721 669 789 308 371 6 1054 43 -427 -532 273 110 -235 528 924 -74 37 -672 -880 -791 SS 20210723T150308.1Z 7874.627177 642 1 47.66 2 47.11 89.68 140.41 265.91 0.00 1 0.00 1 0 17 1.980e-02 9.012e-03 2.767e-03 1.663e-03 1.952434e-01 8.559286e-04 2.175126e-03 -6.000000e+00 1.141437e-02 229.90 -2.00 3.24 -2.00 315.51 0.00e+00 4.735512e-04 8.457505e-05 2.840370e-05 -6.000000e+00 5.251778e-04 294.33 -2.00 20.00 -2.00 314.70 0.00e+00 1.467 0.000 302.00 328.00 3 5.6476e+00 2.2136e-03 1.7378e-02 -6.0000e+00 2.8389e-02 3.8144e-02 2.4658e-03 9.3502e-03 -6.0000e+00 3.0716e-02 1.8300e-03 1.4101e-03 4.5321e-03 -6.0000e+00 1.8395e-02 -2.0392e-03 6.3735e-04 1.2766e-03 -6.0000e+00 7.8744e-03 3.4672e-04 2.8239e-04 4.7400e-05 1.5964e-05 -6.0000e+00 5.3927e-04 4.7799e-03 2.9630e-05 11 9 0 11 32 0 99.42 23.98 0.43 0.00478 0.00690 12 3 1 5 0 3970.330 26.51 19.99 23.98 40.80 22.2 1048.75 -16313 3475 -2275 1723 -2534 -1326 4012 996 5028 282 -3038 -1172 -3261 1092 1040 8649 1282 2216 -88 1917 2136 -649 979 602 594 475 -273 1123 -1780 -99 -790 1920 1264 -1220 -3593 -1440 -1068 2 114 -1332 -532 -513 -128 -995 226 -600 -1406 -1324 75 -433 753 183 632 529 1193 1184 729 214 -318 24 746 570 1663 1701 253 -689 -476 -1540 371 597 297 781 930 404 817 -168 -1729 -1332 -260 -610 -929 -1147 -1915 -370 -636 -881 -313 316 240 824 401 -221 -648 63 -93 339 242 811 743 -262 -81 -955 -804 -669 -550 -837 -138 -677 312 580 770 844 786 -135 -669 -488 -709 -405 -149 81 -104 315 612 767 693 333 -41 462 44 718 318 -329 -671 316 -9 115 376 471 -99 -143 -139 -629 -928 -5019 953 -650 438 -606 -308 950 267 1403 83 -902 -352 -1091 389 405 3330 534 937 -39 852 952 -293 446 286 291 237 -135 519 -797 -44 -361 904 628 -614 -1741 -688 -550 1 74 -960 -400 -395 -100 -781 175 -466 -1078 -991 55 -317 566 144 512 441 1004 1008 627 184 -271 20 649 521 1581 1663 245 -632 -414 -1331 332 577 303 812 962 409 787 -152 -1478 -1101 -220 -558 -912 -1194 -2072 -409 -735 -1062 -388 397 301 1005 467 -244 -676 64 -98 378 287 1014 955 -334 -100 -1122 -920 -786 -678 -1068 -180 -908 427 818 1113 1221 1108 -183 -862 -606 -880 -516 -197 112 -145 438 838 1024 897 418 -50 564 56 937 426 -448 -925 443 -13 172 568 721 -153 -219 -207 -927 -1353 SS 20210723T150530.4Z 7874.628824 644 1 49.24 2 46.59 89.98 140.90 266.16 0.00 1 0.00 1 0 17 7.015e-02 3.297e-02 2.978e-03 1.791e-03 1.837650e-01 9.170294e-04 2.051316e-03 -6.000000e+00 4.042950e-02 229.90 -2.00 3.24 -2.00 315.48 0.00e+00 3.595885e-03 9.093043e-05 2.637628e-04 -6.000000e+00 1.861793e-03 294.33 -2.00 20.00 -2.00 314.69 0.00e+00 1.453 0.000 302.00 328.00 3 5.8137e+00 2.3741e-03 1.7126e-02 -6.0000e+00 1.0055e-01 3.7054e-02 2.6470e-03 1.0247e-02 -6.0000e+00 1.0881e-01 -3.3199e-02 1.5071e-03 4.4133e-03 -6.0000e+00 6.5166e-02 3.0014e-02 6.7492e-04 3.0681e-03 -6.0000e+00 2.7877e-02 3.0232e-04 1.7460e-04 5.0901e-05 2.5034e-05 -6.0000e+00 1.9120e-03 5.7099e-03 -1.0945e-04 12 9 8 11 32 0 99.93 23.98 0.05 0.00571 0.00702 14 3 1 5 0 3516.520 26.51 19.99 23.98 40.81 22.2 1048.68 -64969 18197 15175 16617 13913 11328 7197 11033 4942 6847 3279 7331 3123 9520 8653 10968 8321 10641 8125 10711 9236 5580 4157 1061 1269 487 205 2194 1424 2561 6056 4724 3656 1601 -848 1295 1515 1439 823 -915 -2488 -707 -2553 -936 -1286 -324 -469 -333 508 455 1580 334 561 513 783 -365 -659 -2013 -1768 -862 343 611 1563 1559 -368 -1401 -1573 -1950 -297 -483 -72 -308 -484 -281 -605 -1537 -2333 -3177 -836 -606 -782 -1453 -1935 -1935 -955 -1365 -259 28 -255 393 -56 -112 -1333 -872 -523 659 466 1465 1159 13 -637 -1215 -690 -263 -255 473 421 -115 812 1065 1204 1175 829 -221 -547 -288 -226 142 488 1017 690 906 1517 1024 1084 1021 483 1244 873 1155 408 -172 -502 -697 -211 -272 8 124 -466 -710 -964 -1574 -1437 -33173 4973 4202 4153 3208 2596 1795 2891 1446 1979 949 2122 1035 3326 3339 4362 3449 4430 3526 4656 4058 2487 1895 507 619 242 100 999 622 1108 2661 2207 1805 794 -404 607 767 820 532 -654 -1880 -540 -2010 -731 -1008 -251 -357 -248 368 331 1180 262 453 425 655 -310 -564 -1728 -1499 -731 298 556 1486 1524 -357 -1283 -1368 -1676 -266 -467 -73 -321 -502 -283 -582 -1384 -1976 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