File name: Pandora25s1_HoustonTX_20210813_L2Fit_fout2c5d20210307p1-8.txt File generation date: 20250922T134006.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v5d20210307.txt Level 1 file used: Pandora25s1_HoustonTX_20210813_L1_smca1c5d20210307p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20210813 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.0981 305.2388 305.3795 305.5202 305.6609 305.8015 305.9421 306.0828 306.2234 306.3640 306.5045 306.6451 306.7857 306.9262 307.0667 307.2072 307.3477 307.4882 307.6287 307.7691 307.9096 308.0500 308.1904 308.3308 308.4712 308.6115 308.7519 308.8922 309.0326 309.1729 309.3132 309.4535 309.5937 309.7340 309.8742 310.0144 310.1547 310.2949 310.4350 310.5752 310.7154 310.8555 310.9956 311.1358 311.2759 311.4160 311.5560 311.6961 311.8361 311.9762 312.1162 312.2562 312.3962 312.5362 312.6761 312.8161 312.9560 313.0959 313.2359 313.3758 313.5156 313.6555 313.7954 313.9352 314.0750 314.2148 314.3546 314.4944 314.6342 314.7740 314.9137 315.0535 315.1932 315.3329 315.4726 315.6123 315.7519 315.8916 316.0312 316.1709 316.3105 316.4501 316.5897 316.7292 316.8688 317.0083 317.1479 317.2874 317.4269 317.5664 317.7059 317.8454 317.9848 318.1243 318.2637 318.4031 318.5425 318.6819 318.8213 318.9606 319.1000 319.2393 319.3787 319.5180 319.6573 319.7965 319.9358 320.0751 320.2143 320.3536 320.4928 320.6320 320.7712 320.9104 321.0495 321.1887 321.3278 321.4670 321.6061 321.7452 321.8843 322.0234 322.1624 322.3015 322.4405 322.5796 322.7186 322.8576 322.9966 323.1356 323.2745 323.4135 323.5524 323.6914 323.8303 323.9692 324.1081 324.2469 324.3858 324.5247 324.6635 324.8023 324.9411 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210813T125245.9Z 7895.536642 59 1 49.42 2 77.22 80.45 138.49 62.98 0.00 1 0.00 1 0 25 2.558e-01 4.071e-03 9.046e-02 7.603e-04 5.600946e-01 3.977421e-04 5.972063e-03 -6.000000e+00 1.482295e-01 229.52 -2.00 3.24 -2.00 320.09 0.00e+00 8.736478e-04 1.419595e-04 4.013763e-04 -6.000000e+00 6.855480e-03 294.60 -2.00 20.00 -2.00 319.25 0.00e+00 4.396 0.001 302.00 328.00 3 7.6861e-01 1.2100e-03 5.1488e-02 -6.0000e+00 3.6847e-01 -2.8695e-02 1.5178e-03 2.7462e-02 -6.0000e+00 3.9930e-01 4.2483e-02 1.3281e-03 1.3293e-02 -6.0000e+00 2.3821e-01 -2.7807e-02 6.8243e-04 4.2019e-03 -6.0000e+00 1.0215e-01 1.6979e-03 -6.0855e-04 2.1235e-05 4.1889e-05 -6.0000e+00 7.1141e-03 1.0418e-02 -1.2011e-04 10 0 0 10 0 0 33.23 24.07 0.45 0.01042 0.00585 410 87 1 5 0 120.520 26.62 19.99 24.07 36.03 22.5 1012.37 900000 92900 56156 183260 88207 97237 900000 42113 127397 27425 22801 19752 23628 6300 9163 65791 7062 8269 4443 2576 5294 2358 406 6626 -1619 -514 -2799 6772 -2422 1639 3925 4476 395 -1662 -3456 -2755 -149 136 -748 -2320 -2011 -2434 -469 -2223 -459 -1021 -1948 -1673 -964 -543 -5 473 -52 452 -285 337 86 -345 -319 -35 381 584 1283 1256 940 82 25 -574 701 670 603 448 273 251 228 265 -770 -478 -403 -447 -640 -651 -1467 -1026 -896 -328 164 288 633 937 962 830 624 402 710 440 470 535 341 -226 -281 -780 -639 -411 -687 -943 -734 -613 -36 198 230 233 220 197 -30 188 85 -71 -146 -227 -415 -324 94 61 397 379 59 509 275 264 275 6 -116 -13 -132 -67 -199 130 -35 11 13 -33 -126 900000 220 201 177 206 215 900000 211 314 194 178 185 266 104 180 873 181 230 137 86 176 82 15 262 -75 -25 -139 298 -116 82 225 296 31 -135 -276 -225 -13 15 -98 -361 -343 -443 -88 -429 -89 -202 -395 -348 -207 -124 -1 129 -15 143 -95 116 30 -122 -111 -12 137 229 553 588 449 38 11 -274 364 388 375 286 173 152 129 138 -384 -242 -224 -282 -454 -506 -1217 -886 -815 -311 161 288 628 899 877 721 527 348 664 454 534 660 441 -291 -345 -900 -703 -461 -811 -1158 -934 -814 -50 296 363 377 354 307 -45 276 125 -108 -231 -369 -674 -517 147 92 588 548 83 738 428 438 482 11 -215 -26 -265 -139 -419 275 -75 24 25 -65 -242 SS 20210813T130805.8Z 7895.547290 61 1 49.47 2 73.93 82.22 135.66 66.34 0.00 1 0.00 1 0 17 6.882e-02 5.108e-03 5.534e-03 4.109e-04 4.586786e-01 2.097503e-04 4.958547e-03 -6.000000e+00 3.958891e-02 229.52 -2.00 3.24 -2.00 319.13 0.00e+00 6.995296e-04 5.417159e-05 1.641096e-04 -6.000000e+00 1.828692e-03 294.60 -2.00 20.00 -2.00 318.21 0.00e+00 3.550 0.000 302.00 328.00 3 5.4372e-01 5.9190e-04 4.1712e-02 -6.0000e+00 9.8353e-02 -1.1062e-02 6.9604e-04 2.2249e-02 -6.0000e+00 1.0648e-01 9.3151e-03 5.0972e-04 1.0759e-02 -6.0000e+00 6.3803e-02 -9.7072e-03 2.6962e-04 3.1005e-03 -6.0000e+00 2.7307e-02 5.3043e-03 -3.7476e-04 1.1578e-05 3.2753e-05 -6.0000e+00 1.8759e-03 9.7364e-03 -1.0231e-04 10 0 0 10 0 0 24.53 24.07 0.40 0.00974 0.00692 795 169 1 5 0 62.220 26.51 19.98 24.07 37.21 22.5 1018.80 -76513 6956 10577 5520 5861 3985 10758 3806 9854 3852 958 2178 1581 2469 325 4384 53 2336 -417 1834 112 86 239 285 -278 -1176 -548 -781 -751 -696 1438 1304 1096 -1228 -2502 -2165 -1701 -811 -703 -1180 -1262 -1052 -854 -908 -256 -446 -908 -742 -730 -258 301 611 737 907 479 669 447 197 343 312 810 1099 1551 1630 825 193 -76 -225 527 658 299 360 180 368 281 -29 -550 -627 -281 -476 -773 -931 -1491 -1330 -827 -560 -81 216 599 582 694 701 366 437 456 384 372 559 193 -198 -461 -826 -613 -264 -665 -947 -623 -623 -164 117 244 198 245 106 17 80 164 -27 -65 -175 -380 -230 113 236 511 450 207 731 515 454 277 24 -48 -26 26 -26 -179 115 -38 -113 -84 -236 -357 -2995 143 217 111 108 77 215 94 257 113 30 76 67 116 19 274 4 175 -34 154 10 8 22 29 -30 -136 -63 -85 -80 -79 182 174 164 -192 -376 -331 -293 -167 -164 -323 -380 -334 -281 -304 -86 -152 -311 -257 -258 -96 114 252 328 432 224 324 222 97 165 150 406 605 946 1014 520 116 -47 -134 346 465 231 287 142 275 204 -19 -336 -384 -189 -351 -655 -838 -1380 -1299 -862 -592 -89 245 672 625 724 676 352 405 465 423 444 714 252 -267 -580 -991 -723 -306 -836 -1207 -833 -847 -238 177 384 321 389 166 25 116 238 -40 -102 -276 -604 -357 176 353 759 640 284 1027 763 712 466 41 -84 -47 47 -50 -344 225 -73 -222 -157 -436 -646 SS 20210813T132451.2Z 7895.558926 65 1 49.64 2 70.32 84.16 132.47 69.67 0.00 1 0.00 1 0 17 8.836e-03 4.708e-03 1.701e-03 2.752e-04 3.827496e-01 1.398946e-04 4.175343e-03 -6.000000e+00 5.083350e-03 229.52 -2.00 3.24 -2.00 318.27 0.00e+00 3.529039e-04 2.759652e-05 1.019510e-04 -6.000000e+00 2.348001e-04 294.60 -2.00 20.00 -2.00 317.31 0.00e+00 2.935 0.000 302.00 328.00 3 4.7682e-01 3.7996e-04 3.4563e-02 -6.0000e+00 1.2629e-02 -1.1638e-02 4.3550e-04 1.8455e-02 -6.0000e+00 1.3673e-02 5.9830e-03 2.8279e-04 8.9184e-03 -6.0000e+00 8.1924e-03 -6.3384e-03 1.4715e-04 2.4629e-03 -6.0000e+00 3.5065e-03 1.1232e-02 -2.5015e-04 7.8237e-06 2.6610e-05 -6.0000e+00 2.4085e-04 9.5822e-03 -9.4949e-05 10 0 0 10 0 0 15.83 24.05 0.39 0.00958 0.00770 1174 249 1 5 0 42.090 26.51 20.01 24.05 38.45 22.5 1025.29 3877 -3 -1623 -771 -3253 -743 -1196 719 -320 -563 -2901 -2307 -1885 -1076 -447 -426 59 53 80 204 176 -514 351 -357 -217 -192 -181 -438 -919 225 797 1159 843 -709 -2647 -2149 -2134 -882 -762 -749 -1047 -866 -590 -744 -291 -461 -590 -452 -677 -112 451 608 782 913 588 836 708 657 458 629 778 1091 1320 1512 642 -33 -261 -394 542 643 338 390 232 281 259 -19 -394 -575 -267 -537 -723 -938 -1612 -1438 -927 -532 -138 109 429 525 513 454 216 450 471 383 481 581 159 -259 -482 -773 -582 -280 -645 -922 -564 -576 -158 214 312 259 255 99 -112 126 81 -33 -71 -73 -385 -151 117 278 494 477 317 757 524 446 296 -59 -55 30 93 0 -127 137 -17 -136 -180 -331 -447 171 0 -84 -37 -158 -36 -58 39 -20 -36 -195 -169 -163 -110 -53 -52 8 7 12 31 27 -80 57 -63 -41 -38 -35 -80 -162 41 161 260 194 -168 -649 -496 -555 -271 -265 -302 -433 -376 -264 -336 -132 -210 -267 -204 -308 -53 229 315 434 538 361 498 431 397 287 393 480 732 923 1132 482 -24 -187 -285 405 519 297 338 198 241 203 -14 -287 -414 -198 -436 -635 -917 -1622 -1523 -1004 -588 -160 130 504 589 557 474 211 441 501 438 592 736 213 -343 -621 -951 -677 -337 -809 -1176 -753 -781 -228 321 482 409 390 148 -161 178 110 -47 -106 -114 -588 -234 175 415 701 671 429 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