File name: Pandora25s1_HoustonTX_20210828_L2Fit_fout2c5d20210307p1-8.txt File generation date: 20250922T134530.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v5d20210307.txt Level 1 file used: Pandora25s1_HoustonTX_20210828_L1_smca1c5d20210307p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20210828 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.0981 305.2388 305.3795 305.5202 305.6609 305.8015 305.9421 306.0828 306.2234 306.3640 306.5045 306.6451 306.7857 306.9262 307.0667 307.2072 307.3477 307.4882 307.6287 307.7691 307.9096 308.0500 308.1904 308.3308 308.4712 308.6115 308.7519 308.8922 309.0326 309.1729 309.3132 309.4535 309.5937 309.7340 309.8742 310.0144 310.1547 310.2949 310.4350 310.5752 310.7154 310.8555 310.9956 311.1358 311.2759 311.4160 311.5560 311.6961 311.8361 311.9762 312.1162 312.2562 312.3962 312.5362 312.6761 312.8161 312.9560 313.0959 313.2359 313.3758 313.5156 313.6555 313.7954 313.9352 314.0750 314.2148 314.3546 314.4944 314.6342 314.7740 314.9137 315.0535 315.1932 315.3329 315.4726 315.6123 315.7519 315.8916 316.0312 316.1709 316.3105 316.4501 316.5897 316.7292 316.8688 317.0083 317.1479 317.2874 317.4269 317.5664 317.7059 317.8454 317.9848 318.1243 318.2637 318.4031 318.5425 318.6819 318.8213 318.9606 319.1000 319.2393 319.3787 319.5180 319.6573 319.7965 319.9358 320.0751 320.2143 320.3536 320.4928 320.6320 320.7712 320.9104 321.0495 321.1887 321.3278 321.4670 321.6061 321.7452 321.8843 322.0234 322.1624 322.3015 322.4405 322.5796 322.7186 322.8576 322.9966 323.1356 323.2745 323.4135 323.5524 323.6914 323.8303 323.9692 324.1081 324.2469 324.3858 324.5247 324.6635 324.8023 324.9411 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210828T130954.6Z 7910.548548 203 1 4.13 2 75.07 87.44 35.55 253.10 0.00 1 0.00 1 0 25 8.977e-02 5.862e-03 7.841e-02 4.436e-03 4.526555e-01 2.268373e-03 4.890995e-03 -6.000000e+00 5.157558e-02 229.08 -2.00 3.24 -2.00 319.27 0.00e+00 6.998247e-04 6.100707e-04 1.738351e-04 -6.000000e+00 2.381055e-03 294.19 -2.00 20.00 -2.00 318.36 0.00e+00 3.803 0.001 302.00 328.00 3 2.3606e+00 6.4446e-03 4.3652e-02 -6.0000e+00 1.2802e-01 -1.0556e-02 7.6186e-03 2.1992e-02 -6.0000e+00 1.3864e-01 2.0891e-02 5.7264e-03 1.0610e-02 -6.0000e+00 8.3079e-02 -1.6355e-02 3.0220e-03 3.0863e-03 -6.0000e+00 3.5588e-02 6.8660e-04 -2.9176e-04 1.2650e-04 3.2808e-05 -6.0000e+00 2.4462e-03 9.0214e-03 -2.4565e-05 12 1 1 12 1 1 67.76 24.06 0.39 0.00902 0.00683 7 21 1 5 0 494.280 26.51 19.99 24.06 34.22 22.6 1001.99 54098 -7979 -3548 14680 596 -15275 76627 9788 6613 -545 -21332 -15353 -11435 12702 -8933 580 -3716 8438 -2374 -3772 -4455 -1999 573 268 43 -3498 23 -2103 5835 -358 10739 6336 1264 -741 -4003 -689 -1805 1478 1345 997 -4061 -1580 -902 -1342 -334 -441 -735 191 381 -2248 602 -226 824 634 -91 955 -654 1194 718 -814 1253 1903 38 1473 751 -241 -1099 -400 919 1220 657 708 -731 514 1484 761 -599 -1195 -136 -1979 -744 -601 -1393 -757 -458 -914 345 168 92 585 892 299 93 -249 488 243 690 853 217 -299 -75 -799 -496 -855 -152 -1331 -70 -644 240 293 332 188 907 228 -17 -165 -518 -551 -149 21 -611 -165 120 -14 619 434 -293 680 292 887 179 -174 -255 -197 -59 66 398 -31 44 -190 297 -786 -2 585 -169 -74 239 10 -315 746 202 158 -15 -738 -563 -462 491 -513 34 -250 543 -181 -307 -373 -165 49 24 4 -362 2 -203 537 -35 1081 760 178 -109 -579 -98 -295 267 297 259 -1164 -468 -276 -418 -104 -139 -234 61 123 -788 215 -89 348 287 -41 447 -318 566 335 -385 608 1008 22 907 470 -144 -640 -236 593 860 487 544 -563 371 1013 490 -363 -728 -90 -1491 -609 -529 -1285 -734 -459 -950 372 187 102 616 900 291 85 -233 497 262 814 1092 288 -393 -94 -955 -575 -993 -189 -1718 -91 -893 345 446 529 301 1449 347 -25 -238 -751 -814 -234 33 -991 -261 188 -21 914 615 -415 979 437 1406 298 -297 -450 -356 -111 127 784 -62 87 -373 567 -1485 -3 SS 20210828T132449.9Z 7910.558911 205 1 49.42 2 71.83 89.27 38.60 256.09 0.00 1 0.00 1 0 25 1.053e-02 4.690e-03 2.774e-03 4.130e-04 3.833175e-01 2.095393e-04 4.189499e-03 -6.000000e+00 6.049045e-03 229.08 -2.00 3.24 -2.00 318.41 0.00e+00 3.970139e-04 4.296328e-05 1.056575e-04 -6.000000e+00 2.793641e-04 294.19 -2.00 20.00 -2.00 317.46 0.00e+00 3.164 0.000 302.00 328.00 3 1.0615e+00 5.7239e-04 3.6472e-02 -6.0000e+00 1.5014e-02 -1.6639e-02 6.5742e-04 1.8523e-02 -6.0000e+00 1.6262e-02 7.8432e-03 4.3309e-04 8.9464e-03 -6.0000e+00 9.7447e-03 -7.6596e-03 2.2668e-04 2.4848e-03 -6.0000e+00 4.1730e-03 5.0795e-03 -2.9284e-04 1.1783e-05 2.6896e-05 -6.0000e+00 2.8704e-04 9.5640e-03 -9.3449e-05 10 0 0 10 0 0 72.43 24.04 0.40 0.00956 0.00736 587 125 1 5 0 84.180 26.51 20.00 24.04 35.03 22.7 1006.72 6336 -141 -922 -3009 -1785 -3464 1253 -1429 1347 -1018 -3391 -1199 -2013 -287 -261 2159 -684 821 -117 766 322 -265 206 214 -62 -505 -435 -625 -418 -236 1178 993 708 -956 -2301 -2253 -1940 -1149 -843 -854 -1194 -799 -712 -841 -527 -381 -825 -728 -518 -220 436 577 692 837 548 826 765 561 458 410 711 1017 1414 1547 617 109 -187 -304 595 715 358 489 219 436 325 25 -331 -672 -385 -559 -856 -951 -1573 -1401 -898 -499 -128 150 419 584 584 445 316 545 404 378 480 551 105 -279 -517 -793 -642 -253 -588 -889 -610 -526 -103 316 283 246 241 92 -69 67 102 -97 -67 -170 -386 -209 80 299 511 493 233 754 465 410 283 -12 -41 84 128 30 -134 136 -52 -144 -153 -329 -397 265 -6 -42 -143 -77 -152 58 -72 73 -59 -205 -78 -157 -26 -28 251 -87 110 -15 105 45 -37 30 34 -11 -90 -77 -104 -67 -39 216 204 161 -224 -515 -514 -497 -325 -288 -317 -485 -340 -313 -374 -235 -171 -369 -324 -232 -103 205 295 378 458 312 484 457 333 267 239 432 674 972 1139 456 76 -125 -206 439 568 310 416 185 367 252 18 -227 -455 -284 -449 -745 -920 -1562 -1466 -958 -567 -146 175 486 647 626 460 307 529 427 429 586 719 139 -365 -660 -969 -742 -302 -731 -1171 -808 -735 -147 469 449 383 379 137 -99 95 145 -139 -99 -265 -608 -322 119 444 724 695 316 1037 670 620 456 -19 -69 142 223 55 -243 251 -97 -270 -273 -586 -692 SS 20210828T134136.4Z 7910.570560 209 1 49.45 2 68.19 91.36 42.07 259.09 0.00 1 0.00 1 0 17 7.980e-03 4.879e-03 1.281e-03 3.342e-04 3.260049e-01 1.696263e-04 3.590240e-03 -6.000000e+00 4.583691e-03 229.08 -2.00 3.24 -2.00 317.63 0.00e+00 2.388435e-04 2.774741e-05 7.428555e-05 -6.000000e+00 2.116837e-04 294.19 -2.00 20.00 -2.00 316.68 0.00e+00 2.667 0.000 302.00 328.00 3 1.2258e+00 4.5234e-04 3.0800e-02 -6.0000e+00 1.1377e-02 -1.0797e-02 5.1226e-04 1.5684e-02 -6.0000e+00 1.2322e-02 3.5760e-03 3.1237e-04 7.5905e-03 -6.0000e+00 7.3840e-03 -4.0858e-03 1.5788e-04 2.0893e-03 -6.0000e+00 3.1622e-03 7.4842e-03 -1.8380e-04 9.5780e-06 2.3726e-05 -6.0000e+00 2.1750e-04 9.2304e-03 -9.6974e-05 10 0 0 10 0 0 95.99 24.04 0.38 0.00923 0.00785 682 145 1 5 0 72.490 26.51 20.01 24.04 35.48 22.6 1008.07 -362 -295 -1731 -1459 -4174 -2161 -1349 494 230 22 -2221 -905 -839 -117 -34 -385 -18 250 376 343 531 -370 442 97 463 128 196 -168 -274 373 980 1225 1110 -345 -2284 -1813 -1906 -755 -662 -760 -813 -610 -684 -708 -270 -487 -629 -665 -546 -64 572 672 767 811 667 856 669 599 325 457 609 1054 1331 1529 572 -113 -383 -304 639 600 346 289 144 319 314 -74 -393 -670 -231 -613 -809 -984 -1587 -1377 -873 -556 -189 121 322 441 469 425 225 510 460 346 460 538 129 -282 -481 -861 -592 -257 -498 -869 -546 -611 -119 286 328 265 230 104 -138 98 62 63 -72 -45 -387 -224 130 329 580 525 266 728 601 467 321 14 -22 8 116 -23 -131 111 -27 -160 -221 -369 -507 -30 -27 -160 -123 -329 -167 -114 47 24 2 -248 -108 -107 -17 -6 -73 -4 52 76 72 113 -79 98 23 117 34 51 -41 -63 88 252 347 343 -109 -688 -552 -609 -284 -282 -374 -409 -320 -370 -386 -147 -266 -339 -354 -289 -35 333 398 483 540 435 572 456 405 216 303 422 790 1035 1262 470 -87 -294 -234 506 514 307 266 132 291 263 -59 -302 -505 -178 -514 -734 -988 -1635 -1492 -969 -632 -225 148 390 511 523 453 223 524 488 393 561 700 170 -367 -609 -1043 -681 -306 -621 -1149 -726 -854 -169 422 495 406 352 149 -190 132 84 90 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