File name: Pandora25s1_HoustonTX_20210903_L2Fit_fwvt1c5d20210307p1-8.txt File generation date: 20250922T134651.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v5d20210307.txt Level 1 file used: Pandora25s1_HoustonTX_20210903_L1_smca1c5d20210307p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20210903 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1709 1859 Nominal wavelengths inside fitting window [nm]: 492.0874 492.2076 492.3277 492.4479 492.5680 492.6881 492.8083 492.9283 493.0484 493.1685 493.2885 493.4085 493.5285 493.6485 493.7685 493.8885 494.0084 494.1283 494.2482 494.3681 494.4880 494.6079 494.7277 494.8475 494.9673 495.0871 495.2069 495.3267 495.4464 495.5661 495.6858 495.8055 495.9252 496.0449 496.1645 496.2841 496.4038 496.5234 496.6429 496.7625 496.8820 497.0016 497.1211 497.2406 497.3600 497.4795 497.5989 497.7184 497.8378 497.9572 498.0766 498.1959 498.3153 498.4346 498.5539 498.6732 498.7925 498.9117 499.0310 499.1502 499.2694 499.3886 499.5078 499.6270 499.7461 499.8652 499.9844 500.1034 500.2225 500.3416 500.4606 500.5797 500.6987 500.8177 500.9367 501.0556 501.1746 501.2935 501.4124 501.5313 501.6502 501.7690 501.8879 502.0067 502.1255 502.2443 502.3631 502.4819 502.6006 502.7193 502.8380 502.9567 503.0754 503.1941 503.3127 503.4314 503.5500 503.6686 503.7871 503.9057 504.0243 504.1428 504.2613 504.3798 504.4983 504.6167 504.7352 504.8536 504.9720 505.0904 505.2088 505.3271 505.4455 505.5638 505.6821 505.8004 505.9187 506.0370 506.1552 506.2734 506.3916 506.5098 506.6280 506.7462 506.8643 506.9824 507.1005 507.2186 507.3367 507.4548 507.5728 507.6908 507.8088 507.9268 508.0448 508.1628 508.2807 508.3986 508.5165 508.6344 508.7523 508.8701 508.9880 509.1058 509.2236 509.3414 509.4592 509.5769 509.6947 509.8124 509.9301 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20210903T125730.2Z 7916.539933 130 1 6.18 2 78.39 88.11 35.95 89.03 0.00 1 0.00 1 0 22 2.631e-03 2.613e-03 9.810e-05 9.794e-05 1.286697e+04 7.029934e+00 8.331807e+02 -6.000000e+00 1.507163e+02 293.98 -2.00 20.00 -2.00 505.29 0.00e+00 1.054679e-03 2.768218e-06 7.759458e-05 -6.000000e+00 7.545395e-05 293.98 -2.00 20.00 -2.00 500.47 0.00e+00 4.131390e-01 1.921452e-03 7.117234e-02 -6.000000e+00 5.161169e-02 228.89 -2.00 3.24 -2.00 502.06 0.00e+00 4.805 0.001 489.00 513.00 1 8.2497e-01 1.4771e-04 9.3542e-03 -6.0000e+00 3.9698e-03 -1.1224e-02 3.7683e-05 1.7817e-03 -6.0000e+00 1.0328e-03 4.0522e-01 2.6229e-04 8.8678e-06 7.9751e-05 -6.0000e+00 2.6078e-04 6.5580e-03 -9.1610e-05 10 0 0 10 0 0 -6.03 24.10 1.56 0.00656 0.00838 829 176 1 4 0 7.010 26.51 20.00 24.10 36.02 23.0 1009.34 -381 -259 35 164 185 472 543 452 387 175 81 10 -216 -213 -268 -333 -254 20 144 60 136 241 167 311 434 332 300 320 -42 -388 -336 -405 -378 122 137 -145 -42 -13 -173 -199 -86 -77 -16 117 209 225 190 100 44 -160 -429 -523 -651 -585 -222 -46 24 87 75 102 170 298 290 260 272 163 85 -16 -54 -244 -358 -279 -272 -129 95 -26 -230 -260 -259 -325 -399 -308 -355 -298 -20 -79 -170 -112 -111 -104 -31 75 365 416 233 286 206 16 -82 -360 -632 -592 -537 -161 34 -120 -121 -124 -302 -153 -1 -24 27 175 217 258 419 574 468 247 195 89 -41 137 286 110 102 230 29 166 336 -17 -158 -59 -271 -255 107 68 -22 205 205 109 188 227 191 216 147 -74 -316 -403 -372 -370 -253 35 166 188 490 565 469 401 182 83 11 -218 -215 -270 -337 -258 21 149 63 142 251 174 325 456 345 314 332 -43 -391 -337 -407 -384 126 143 -153 -44 -13 -179 -204 -88 -79 -16 122 218 235 197 104 45 -162 -427 -514 -641 -578 -221 -46 24 89 77 105 175 304 297 267 277 166 86 -16 -54 -242 -351 -274 -269 -127 95 -26 -227 -254 -252 -315 -387 -300 -345 -292 -19 -78 -167 -111 -109 -103 -31 74 362 413 228 276 197 15 -76 -332 -580 -543 -503 -154 33 -119 -120 -122 -295 -151 -1 -24 26 174 217 259 419 579 471 248 194 88 -41 134 280 107 100 225 28 162 326 -16 -151 -56 -259 -246 104 67 -21 202 205 109 189 229 192 218 148 -74 -309 -393 -364 SQ 20210903T125736.6Z 7916.540007 130 2 6.15 2 78.37 88.13 35.93 89.04 0.00 1 0.00 1 0 22 2.623e-03 2.606e-03 9.793e-05 9.776e-05 1.282747e+04 7.011422e+00 8.312227e+02 -6.000000e+00 1.502830e+02 293.98 -2.00 20.00 -2.00 505.29 0.00e+00 1.060772e-03 2.764267e-06 7.784659e-05 -6.000000e+00 7.523631e-05 293.98 -2.00 20.00 -2.00 500.47 0.00e+00 4.129112e-01 1.918945e-03 7.082784e-02 -6.000000e+00 5.146142e-02 228.89 -2.00 3.24 -2.00 502.05 0.00e+00 4.797 0.001 489.00 513.00 1 8.2258e-01 1.4754e-04 9.3290e-03 -6.0000e+00 3.9583e-03 -1.1173e-02 3.7637e-05 1.7740e-03 -6.0000e+00 1.0297e-03 4.0670e-01 2.2937e-04 8.8556e-06 7.9714e-05 -6.0000e+00 2.6002e-04 6.0514e-03 -8.5819e-05 10 0 0 10 0 0 3.59 24.10 1.55 0.00605 0.00764 829 176 1 4 0 7.010 26.51 20.00 24.10 36.02 23.0 1009.34 -361 -263 45 173 195 483 534 450 390 194 66 -13 -216 -205 -279 -316 -233 12 147 55 152 232 162 317 443 316 304 304 -40 -395 -330 -410 -380 117 131 -123 -38 -32 -164 -197 -92 -72 -2 116 198 205 196 85 24 -156 -401 -513 -653 -595 -229 -61 29 109 78 103 176 268 283 245 281 147 56 -23 -66 -238 -368 -255 -239 -134 114 -26 -259 -282 -260 -319 -369 -290 -356 -316 -51 -87 -164 -116 -87 -88 -27 93 369 429 241 287 203 20 -76 -376 -637 -583 -524 -207 11 -124 -128 -152 -305 -179 19 -25 15 171 225 279 415 594 476 270 190 103 -53 148 283 107 97 229 34 176 311 -35 -163 -27 -267 -249 98 66 -35 200 225 103 204 192 203 215 125 -54 -299 -390 -361 -351 -257 45 174 199 501 557 468 404 202 67 -13 -218 -207 -281 -320 -237 12 152 57 158 242 170 332 465 329 319 314 -41 -399 -331 -413 -386 119 136 -129 -39 -33 -170 -202 -95 -74 -2 121 206 214 204 88 24 -158 -400 -506 -643 -582 -228 -61 30 113 80 105 179 273 291 251 287 150 56 -23 -65 -236 -362 -250 -236 -133 114 -26 -256 -277 -253 -309 -358 -282 -346 -310 -50 -86 -162 -114 -86 -87 -27 92 367 428 237 277 194 19 -71 -348 -586 -535 -490 -198 10 -123 -127 -151 -298 -174 18 -25 15 171 225 277 415 600 480 271 190 102 -52 144 277 104 95 225 34 172 303 -35 -156 -26 -255 -238 95 64 -34 198 226 103 205 192 204 215 125 -54 -293 -381 -353 SQ 20210903T125742.8Z 7916.540079 130 3 6.09 2 78.35 88.14 35.91 89.06 0.00 1 0.00 1 0 22 2.648e-03 2.629e-03 9.781e-05 9.765e-05 1.282492e+04 7.002194e+00 8.316768e+02 -6.000000e+00 1.516892e+02 293.98 -2.00 20.00 -2.00 505.29 0.00e+00 1.060765e-03 2.760296e-06 7.772134e-05 -6.000000e+00 7.594102e-05 293.98 -2.00 20.00 -2.00 500.46 0.00e+00 4.115566e-01 1.916263e-03 7.062217e-02 -6.000000e+00 5.194488e-02 228.89 -2.00 3.24 -2.00 502.05 0.00e+00 4.788 0.001 489.00 513.00 1 8.2140e-01 1.4733e-04 9.3100e-03 -6.0000e+00 3.9955e-03 -1.1166e-02 3.7590e-05 1.7706e-03 -6.0000e+00 1.0394e-03 4.0772e-01 2.7454e-04 8.8424e-06 8.0186e-05 -6.0000e+00 2.6246e-04 6.7635e-03 -9.2902e-05 10 0 0 10 0 0 -0.65 24.10 1.55 0.00676 0.00867 829 176 1 4 0 7.010 26.62 20.00 24.10 36.02 23.0 1009.34 -345 -268 37 178 205 492 547 449 402 187 67 2 -216 -207 -262 -331 -232 19 144 41 130 253 178 316 430 312 332 312 -29 -377 -339 -425 -367 146 135 -126 -69 -37 -170 -244 -99 -81 0 121 185 193 179 102 42 -170 -424 -507 -641 -590 -230 -63 26 89 99 111 176 278 281 246 275 143 65 -17 -48 -244 -368 -275 -265 -146 96 -32 -241 -279 -265 -340 -376 -270 -339 -312 -33 -82 -150 -107 -107 -116 -26 112 361 406 269 313 188 25 -93 -364 -660 -604 -520 -195 0 -122 -121 -131 -303 -171 -12 -46 23 172 238 284 419 596 487 267 189 84 -69 147 296 108 75 234 35 166 346 -30 -178 -64 -267 -248 108 67 -15 219 228 108 182 217 204 206 149 -45 -295 -397 -370 -336 -262 37 179 209 505 571 468 418 195 69 2 -219 -210 -264 -332 -236 20 150 42 136 264 186 331 448 326 345 324 -30 -381 -341 -429 -374 150 140 -132 -73 -38 -176 -251 -101 -84 0 126 193 202 187 105 43 -173 -424 -500 -632 -578 -227 -64 27 90 101 113 180 284 288 253 281 146 65 -17 -48 -242 -363 -271 -263 -145 96 -32 -238 -273 -256 -330 -365 -260 -329 -307 -32 -81 -148 -105 -106 -114 -25 110 360 405 265 303 180 23 -86 -333 -608 -556 -487 -187 0 -121 -121 -130 -297 -166 -12 -46 23 172 236 282 420 596 491 268 189 83 -67 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