File name: Pandora25s1_HoustonTX_20211020_L2Fit_fout2c5d20210307p1-8.txt File generation date: 20250922T140512.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v5d20210307.txt Level 1 file used: Pandora25s1_HoustonTX_20211020_L1_smca1c5d20210307p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20211020 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.0981 305.2388 305.3795 305.5202 305.6609 305.8015 305.9421 306.0828 306.2234 306.3640 306.5045 306.6451 306.7857 306.9262 307.0667 307.2072 307.3477 307.4882 307.6287 307.7691 307.9096 308.0500 308.1904 308.3308 308.4712 308.6115 308.7519 308.8922 309.0326 309.1729 309.3132 309.4535 309.5937 309.7340 309.8742 310.0144 310.1547 310.2949 310.4350 310.5752 310.7154 310.8555 310.9956 311.1358 311.2759 311.4160 311.5560 311.6961 311.8361 311.9762 312.1162 312.2562 312.3962 312.5362 312.6761 312.8161 312.9560 313.0959 313.2359 313.3758 313.5156 313.6555 313.7954 313.9352 314.0750 314.2148 314.3546 314.4944 314.6342 314.7740 314.9137 315.0535 315.1932 315.3329 315.4726 315.6123 315.7519 315.8916 316.0312 316.1709 316.3105 316.4501 316.5897 316.7292 316.8688 317.0083 317.1479 317.2874 317.4269 317.5664 317.7059 317.8454 317.9848 318.1243 318.2637 318.4031 318.5425 318.6819 318.8213 318.9606 319.1000 319.2393 319.3787 319.5180 319.6573 319.7965 319.9358 320.0751 320.2143 320.3536 320.4928 320.6320 320.7712 320.9104 321.0495 321.1887 321.3278 321.4670 321.6061 321.7452 321.8843 322.0234 322.1624 322.3015 322.4405 322.5796 322.7186 322.8576 322.9966 323.1356 323.2745 323.4135 323.5524 323.6914 323.8303 323.9692 324.1081 324.2469 324.3858 324.5247 324.6635 324.8023 324.9411 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211020T133323.9Z 7963.564860 268 1 49.36 2 76.90 110.43 105.29 287.57 0.00 1 0.00 1 0 25 2.471e-01 4.670e-03 1.241e-01 1.707e-03 5.007319e-01 8.800379e-04 5.387285e-03 -6.000000e+00 1.408852e-01 226.66 -2.00 3.24 -2.00 320.04 0.00e+00 8.843229e-04 3.038581e-04 7.056841e-04 -6.000000e+00 6.499538e-03 290.90 -2.00 20.00 -2.00 319.25 0.00e+00 4.299 0.001 302.00 328.00 3 2.3894e+00 2.6409e-03 4.9104e-02 -6.0000e+00 3.4814e-01 -2.8308e-02 3.2745e-03 2.4921e-02 -6.0000e+00 3.7777e-01 4.3374e-02 2.8119e-03 1.1884e-02 -6.0000e+00 2.2640e-01 -2.6298e-02 1.4478e-03 4.0204e-03 -6.0000e+00 9.7966e-02 3.9633e-04 -1.6303e-04 4.9103e-05 3.9285e-05 -6.0000e+00 6.7569e-03 -6.3165e-04 5.6648e-05 10 0 0 10 0 0 99.89 23.92 0.39 -0.00063 -0.00186 145 31 1 5 0 340.310 26.41 20.00 23.92 28.96 23.2 982.52 900000 110232 -31105 85539 27362 -3219 180193 4914 164696 -12967 -10287 13772 7452 4102 490 15637 18249 7687 -7564 288 2598 3561 -3758 760 -4716 -2101 -2794 8136 2744 -5482 8084 4968 486 2797 -3868 -900 558 2463 1885 -5832 -3090 -1004 -827 527 2311 924 -2963 -3936 1725 -1193 1556 -1091 -1986 1064 798 766 787 -1206 743 -1234 -108 508 348 1334 295 -198 -663 -822 1544 362 764 455 317 -271 741 -43 -1785 -109 1 84 -404 -760 -1267 -450 -785 -668 58 592 513 903 837 1340 678 401 304 190 592 728 300 -80 -84 -792 -541 -693 -35 -752 -796 -742 -350 -206 148 -16 134 217 -73 207 84 -82 -384 -169 -628 -155 154 170 345 504 68 846 547 315 409 -65 -31 145 -131 -120 -75 25 -169 -49 161 -194 -163 900000 353 -399 350 186 -28 300 51 422 -196 -158 188 134 95 13 423 531 271 -334 12 112 154 -187 40 -282 -129 -174 437 153 -354 527 363 42 246 -348 -80 55 286 271 -1011 -579 -197 -169 108 474 195 -658 -900 384 -290 406 -305 -609 341 270 270 285 -444 262 -442 -40 206 158 626 143 -93 -302 -383 777 211 487 288 198 -171 425 -22 -878 -56 1 52 -277 -589 -1018 -380 -713 -648 56 586 508 896 773 1143 579 349 277 197 667 885 393 -104 -103 -925 -588 -769 -42 -913 -1018 -1009 -490 -304 237 -27 220 339 -111 300 123 -125 -602 -278 -1040 -249 239 265 514 719 98 1188 848 521 702 -118 -58 277 -259 -250 -160 55 -357 -103 323 -385 -316 SS 20211020T134819.9Z 7963.575231 274 1 19.49 2 73.89 112.60 108.23 289.70 0.00 1 0.00 1 0 25 3.142e-02 4.810e-03 1.594e-02 1.443e-03 4.184773e-01 7.293833e-04 4.568407e-03 -6.000000e+00 1.790489e-02 226.66 -2.00 3.24 -2.00 318.92 0.00e+00 3.266750e-04 1.757522e-04 2.118395e-04 -6.000000e+00 8.210720e-04 290.90 -2.00 20.00 -2.00 318.07 0.00e+00 3.542 0.000 302.00 328.00 3 2.1806e+00 2.0260e-03 4.0456e-02 -6.0000e+00 4.4246e-02 -2.1973e-02 2.3573e-03 2.0132e-02 -6.0000e+00 4.8007e-02 2.1278e-02 1.6985e-03 9.7810e-03 -6.0000e+00 2.8765e-02 -1.5347e-02 9.0092e-04 2.7930e-03 -6.0000e+00 1.2364e-02 1.1073e-03 -1.8736e-04 4.1411e-05 3.0764e-05 -6.0000e+00 8.5479e-04 3.9678e-05 1.8458e-05 12 1 1 12 1 1 97.43 23.92 0.47 0.00004 -0.00137 58 32 1 5 0 327.350 26.41 20.01 23.92 29.56 23.3 986.20 23903 10029 -7983 15252 -4793 6873 3415 -1354 10102 -3887 -356 -1317 5065 -302 465 -3364 2862 -1870 -320 -2096 1457 -910 12 1194 -1115 -1324 -2724 1893 -133 -1265 3196 3098 -797 -408 -3937 -2965 -2443 445 81 -3001 -1069 -1334 -531 -1179 152 -271 -909 -1205 357 -1308 822 363 421 1048 235 1095 557 146 745 260 860 766 1474 1219 913 -243 -122 -782 988 321 695 97 314 300 572 -9 -144 -426 -358 -614 -627 -918 -1617 -1024 -1003 -623 -305 434 411 707 445 724 383 272 546 354 498 662 407 -238 -347 -929 -513 -367 -379 -895 -636 -727 -96 161 304 293 232 335 -198 72 -54 -21 -334 -147 -464 -275 -22 129 624 413 240 605 402 552 384 43 -45 160 2 -54 -162 166 -116 -120 -169 -73 -382 505 248 -244 379 -133 171 97 -43 319 -150 -14 -56 241 -18 33 -282 243 -179 -32 -207 141 -91 1 134 -138 -172 -358 225 -16 -157 426 468 -139 -73 -692 -522 -480 102 21 -943 -363 -448 -184 -417 54 -97 -325 -434 128 -500 335 163 203 503 119 568 297 78 387 135 462 451 899 809 613 -156 -75 -488 664 234 552 80 258 235 412 -6 -92 -269 -246 -460 -536 -834 -1514 -1006 -1058 -667 -343 499 471 777 477 714 375 267 551 385 583 830 546 -317 -434 -1115 -603 -443 -471 -1133 -844 -1022 -138 240 469 466 361 511 -295 101 -76 -30 -507 -234 -752 -436 -34 199 911 579 337 862 600 864 620 73 -75 283 3 -103 -308 321 -227 -228 -317 -131 -694 SS 20211020T135850.6Z 7963.582530 277 1 49.51 2 71.80 114.18 110.27 291.26 0.00 1 0.00 1 0 25 9.431e-03 4.674e-03 3.074e-03 4.728e-04 3.749067e-01 2.381079e-04 4.133191e-03 -6.000000e+00 5.374336e-03 226.66 -2.00 3.24 -2.00 318.35 0.00e+00 3.371319e-04 4.780191e-05 1.254360e-04 -6.000000e+00 2.464689e-04 290.89 -2.00 20.00 -2.00 317.47 0.00e+00 3.159 0.000 302.00 328.00 3 1.3815e+00 6.4531e-04 3.6112e-02 -6.0000e+00 1.3281e-02 -2.1305e-02 7.3966e-04 1.7979e-02 -6.0000e+00 1.4410e-02 1.1208e-02 4.9070e-04 8.7513e-03 -6.0000e+00 8.6342e-03 -8.3994e-03 2.5746e-04 2.4687e-03 -6.0000e+00 3.7109e-03 3.7587e-03 -2.9115e-04 1.3542e-05 2.7071e-05 -6.0000e+00 2.5660e-04 2.2632e-04 1.1795e-05 10 0 0 10 0 0 98.05 23.92 0.40 0.00023 -0.00196 440 93 1 5 0 112.440 26.41 19.98 23.92 29.81 23.3 987.09 -1663 910 -3406 -1494 -4514 -2543 -310 -1727 2366 -2055 -2324 -1731 -481 -239 -472 1240 32 89 -276 115 -167 -144 -285 28 -143 283 -258 546 -343 -506 1216 1250 685 -436 -1908 -2595 -1847 -1113 -556 -1331 -1030 -856 -540 -816 -157 -427 -758 -595 -445 -367 415 620 465 953 408 925 699 607 593 381 599 981 1259 1415 758 19 -163 -535 579 598 286 389 215 254 198 55 -384 -571 -310 -379 -641 -878 -1539 -1413 -1011 -703 -266 114 343 605 547 540 327 502 560 337 502 542 252 -214 -305 -743 -611 -237 -550 -940 -608 -595 -190 235 301 260 200 94 -55 58 31 -30 -130 -145 -431 -285 46 273 473 513 337 766 619 488 347 123 -23 36 38 2 -154 106 -103 -159 -178 -325 -341 -74 43 -174 -70 -197 -109 -14 -92 135 -129 -148 -120 -39 -23 -53 141 4 12 -38 17 -25 -21 -44 5 -26 53 -48 95 -58 -88 230 265 161 -98 -445 -613 -450 -320 -194 -509 -430 -376 -229 -352 -68 -185 -328 -256 -192 -164 199 323 260 532 238 554 429 370 354 227 371 623 880 1064 575 13 -111 -367 430 479 238 337 185 209 158 42 -269 -392 -229 -304 -558 -813 -1540 -1421 -1087 -772 -307 134 404 682 598 569 322 491 591 382 611 706 337 -283 -394 -921 -713 -283 -685 -1243 -807 -834 -271 349 460 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