File name: Pandora25s1_HoustonTX_20211025_L2Fit_fout2c5d20210307p1-8.txt File generation date: 20250922T140537.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v5d20210307.txt Level 1 file used: Pandora25s1_HoustonTX_20211025_L1_smca1c5d20210307p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20211025 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.0981 305.2388 305.3795 305.5202 305.6609 305.8015 305.9421 306.0828 306.2234 306.3640 306.5045 306.6451 306.7857 306.9262 307.0667 307.2072 307.3477 307.4882 307.6287 307.7691 307.9096 308.0500 308.1904 308.3308 308.4712 308.6115 308.7519 308.8922 309.0326 309.1729 309.3132 309.4535 309.5937 309.7340 309.8742 310.0144 310.1547 310.2949 310.4350 310.5752 310.7154 310.8555 310.9956 311.1358 311.2759 311.4160 311.5560 311.6961 311.8361 311.9762 312.1162 312.2562 312.3962 312.5362 312.6761 312.8161 312.9560 313.0959 313.2359 313.3758 313.5156 313.6555 313.7954 313.9352 314.0750 314.2148 314.3546 314.4944 314.6342 314.7740 314.9137 315.0535 315.1932 315.3329 315.4726 315.6123 315.7519 315.8916 316.0312 316.1709 316.3105 316.4501 316.5897 316.7292 316.8688 317.0083 317.1479 317.2874 317.4269 317.5664 317.7059 317.8454 317.9848 318.1243 318.2637 318.4031 318.5425 318.6819 318.8213 318.9606 319.1000 319.2393 319.3787 319.5180 319.6573 319.7965 319.9358 320.0751 320.2143 320.3536 320.4928 320.6320 320.7712 320.9104 321.0495 321.1887 321.3278 321.4670 321.6061 321.7452 321.8843 322.0234 322.1624 322.3015 322.4405 322.5796 322.7186 322.8576 322.9966 323.1356 323.2745 323.4135 323.5524 323.6914 323.8303 323.9692 324.1081 324.2469 324.3858 324.5247 324.6635 324.8023 324.9411 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211025T135737.2Z 7968.581680 277 1 0.54 2 72.94 115.58 55.25 281.73 0.00 1 0.00 1 0 17 8.782e-02 1.091e-02 7.343e-02 9.166e-03 3.925382e-01 4.624375e-03 4.303682e-03 -6.000000e+00 4.998858e-02 226.35 -2.00 3.24 -2.00 318.44 0.00e+00 9.191627e-04 9.580127e-04 1.826911e-04 -6.000000e+00 2.290736e-03 290.45 -2.00 20.00 -2.00 317.58 0.00e+00 3.357 0.000 302.00 328.00 3 1.5154e+00 1.2561e-02 3.8209e-02 -6.0000e+00 1.2346e-01 -1.1557e-02 1.4427e-02 1.8835e-02 -6.0000e+00 1.3400e-01 1.9999e-03 9.7320e-03 9.1526e-03 -6.0000e+00 8.0285e-02 3.5132e-03 5.1240e-03 2.7457e-03 -6.0000e+00 3.4515e-02 2.6338e-03 -4.4347e-04 2.6151e-04 2.9322e-05 -6.0000e+00 2.3892e-03 -4.9686e-04 -3.0651e-06 12 9 9 12 1 1 999.00 23.89 0.28 -0.00050 -0.00383 1 57 1 5 0 183.800 26.41 20.00 23.89 33.74 23.5 1009.81 16450 -3332 18848 51190 -32737 52526 6949 -5370 -22020 35740 -19043 4385 2714 14222 242 -2762 5927 -9535 17441 -5054 4393 -3302 957 -8046 9214 -1312 -2013 -260 -88 -3484 2299 -863 559 7198 -3399 5435 -513 -1956 -1751 1498 -3484 -1322 -1979 -2055 -805 602 3230 -2617 1962 -1064 3479 -3083 -496 1312 3501 -721 2772 -1196 2301 114 -1709 3970 -1358 2983 -1286 1183 -949 -2644 78 -449 478 1421 -698 -141 -179 -297 797 -1748 2543 -700 -311 -797 -2398 -1716 457 -248 302 294 635 1930 -123 1139 -574 1715 891 -61 -1337 1327 917 -108 -840 -1130 -340 -795 -784 -1943 -102 -802 447 903 390 -1228 -452 162 605 1370 158 881 165 -990 -895 -1090 0 564 757 1474 657 1140 279 -359 -386 -222 -349 149 232 216 -97 806 475 -1128 127 -826 32 577 -154 731 1387 -1757 1286 282 -276 -1457 1465 -1306 264 194 1081 24 -316 670 -1313 1986 -732 595 -479 140 -1357 1415 -230 -354 -43 -14 -593 409 -175 122 1521 -749 1118 -122 -545 -570 539 -1402 -546 -845 -887 -347 258 1355 -1148 837 -478 1606 -1595 -265 726 1964 -427 1624 -719 1330 67 -1045 2481 -945 2126 -948 823 -649 -1837 57 -356 400 1214 -602 -118 -142 -219 552 -1220 1821 -562 -272 -750 -2384 -1758 483 -275 344 342 736 2166 -134 1168 -571 1678 921 -69 -1621 1694 1219 -144 -1079 -1379 -398 -951 -982 -2537 -136 -1106 636 1343 606 -1955 -708 245 875 1911 222 1266 247 -1541 -1405 -1695 0 838 1093 2066 902 1576 406 -551 -617 -363 -580 254 408 391 -178 1495 885 -2090 228 -1456 55 SS 20211025T140345.0Z 7968.585938 281 1 49.64 2 71.75 116.53 56.52 282.29 0.00 1 0.00 1 0 25 9.372e-02 7.900e-03 1.372e-02 1.674e-03 3.753343e-01 8.439170e-04 4.126528e-03 -6.000000e+00 5.333513e-02 226.35 -2.00 3.24 -2.00 318.85 0.00e+00 6.062426e-04 1.950542e-04 1.174619e-04 -6.000000e+00 2.445206e-03 290.45 -2.00 20.00 -2.00 317.99 0.00e+00 3.150 0.000 302.00 328.00 3 3.5417e+00 2.3304e-03 3.6053e-02 -6.0000e+00 1.3172e-01 2.4180e-02 2.7042e-03 1.8009e-02 -6.0000e+00 1.4298e-01 1.1947e-02 1.8771e-03 8.7982e-03 -6.0000e+00 8.5668e-02 -9.7883e-03 9.8674e-04 2.5235e-03 -6.0000e+00 3.6815e-02 4.2360e-04 -6.9688e-04 4.8753e-05 2.8012e-05 -6.0000e+00 2.5505e-03 5.1212e-04 -6.7080e-05 11 8 0 10 0 0 99.97 23.89 0.34 0.00051 -0.00472 140 30 1 5 0 354.510 26.41 19.98 23.89 34.12 23.8 1012.74 -81071 2800 -6576 26742 -3255 -2098 11826 1404 9790 9873 -13956 9788 -3541 7563 -2210 60400 3149 865 1002 426 5679 -336 3286 -2605 766 -2542 -651 3312 1488 -2698 6326 3886 1027 2693 -2899 1143 -2233 3655 -1635 -2116 -2311 357 -810 486 1210 -136 -1159 -1741 1586 -1789 2439 -384 -46 666 985 688 1547 -731 716 -95 771 863 958 1758 -609 536 -845 -87 1128 1022 318 423 60 -201 598 -306 -1148 -896 263 -831 -439 -1094 -1395 -912 -896 -696 -301 13 155 828 109 871 227 523 57 309 181 637 173 -110 -362 -506 -658 -681 20 -924 -475 -752 121 257 259 106 366 -10 -48 277 -138 -73 -77 -51 -281 48 -39 351 430 588 101 853 538 392 365 -230 5 42 -49 -177 105 -38 -39 -178 116 -526 -265 -6052 108 -281 797 -117 -74 402 59 422 446 -790 484 -229 520 -192 3297 307 91 111 49 637 -40 395 -353 107 -380 -95 445 196 -380 902 628 187 491 -529 202 -451 819 -457 -681 -808 128 -302 181 450 -52 -441 -664 590 -707 994 -172 -22 332 506 363 825 -396 377 -50 418 503 606 1174 -415 343 -526 -54 745 750 252 346 49 -158 438 -207 -730 -560 173 -617 -360 -982 -1325 -899 -931 -761 -340 15 179 922 116 861 214 489 57 335 214 815 232 -147 -462 -605 -755 -799 25 -1196 -636 -1046 175 392 414 173 586 -16 -70 389 -194 -106 -116 -81 -448 76 -61 527 625 827 138 1173 783 607 590 -384 9 73 -89 -334 201 -75 -77 -343 217 -959 -474 SS 20211025T140919.6Z 7968.589810 284 1 0.95 2 70.67 117.41 57.67 282.79 0.00 1 0.00 1 0 17 4.742e-02 8.980e-03 3.964e-02 7.997e-03 3.543431e-01 4.026440e-03 3.883173e-03 -6.000000e+00 2.699153e-02 226.35 -2.00 3.24 -2.00 317.90 0.00e+00 1.329698e-03 7.104447e-04 2.087587e-04 -6.000000e+00 1.237097e-03 290.45 -2.00 20.00 -2.00 317.03 0.00e+00 2.985 0.000 302.00 328.00 3 2.3828e+00 1.0760e-02 3.4084e-02 -6.0000e+00 6.6663e-02 2.1280e-02 1.2239e-02 1.7002e-02 -6.0000e+00 7.2354e-02 1.8917e-03 7.7404e-03 8.2204e-03 -6.0000e+00 4.3352e-02 -7.2006e-03 3.9932e-03 2.6508e-03 -6.0000e+00 1.8635e-02 1.6351e-03 -2.7517e-04 2.2864e-04 2.7465e-05 -6.0000e+00 1.2903e-03 -3.7752e-04 -3.2141e-05 12 9 1 12 1 1 999.00 23.87 0.37 -0.00038 -0.00245 1 27 1 5 0 384.350 26.41 20.01 23.87 34.36 23.7 1013.38 -11065 23457 -10397 26389 -18712 13423 7553 194 4263 6871 -11550 5176 -3615 2960 7823 -10936 7892 -5005 4603 -1482 3742 -1281 2389 -6858 1190 -1545 -8450 3178 -1854 8087 1918 7829 1704 2108 -5673 2106 -1115 1135 -3392 1157 -2464 -1716 655 -2453 -377 -443 1354 -2783 1406 -1128 1392 -120 913 156 1805 2082 2084 2559 269 1608 -1700 1613 -66 1641 -1200 591 -2018 -1163 987 293 1338 -932 -73 -1011 1211 -1427 1347 -1442 165 -223 855 -2041 -478 -2327 -1318 -201 -370 1570 -116 740 149 352 286 1960 -273 -310 -558 547 122 -539 -224 -175 355 -467 -73 243 530 -1002 -285 315 -82 547 143 -225 227 -216 -412 324 15 551 -191 -926 -2 428 603 -260 380 -400 494 -13 238 -953 731 706 140 61 -306 34 -155 108 -90 -94 -425 -776 1309 -807 1369 -1341 712 458 14 330 542 -1083 449 -394 355 1033 -1867 1212 -906 801 -282 690 -247 462 -1519 259 -356 -2049 668 -392 1614 439 1867 463 579 -1582 554 -329 378 -1354 500 -1168 -840 323 -1248 -190 -225 674 -1421 697 -583 745 -69 545 98 1144 1342 1360 1660 175 1035 -1151 1131 -50 1286 -958 446 -1496 -858 760 247 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