File name: Pandora25s1_HoustonTX_20220106_L2Fit_fout2c5d20210307p1-8.txt File generation date: 20250922T143710.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v5d20210307.txt Level 1 file used: Pandora25s1_HoustonTX_20220106_L1_smca1c5d20210307p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20220106 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.0981 305.2388 305.3795 305.5202 305.6609 305.8015 305.9421 306.0828 306.2234 306.3640 306.5045 306.6451 306.7857 306.9262 307.0667 307.2072 307.3477 307.4882 307.6287 307.7691 307.9096 308.0500 308.1904 308.3308 308.4712 308.6115 308.7519 308.8922 309.0326 309.1729 309.3132 309.4535 309.5937 309.7340 309.8742 310.0144 310.1547 310.2949 310.4350 310.5752 310.7154 310.8555 310.9956 311.1358 311.2759 311.4160 311.5560 311.6961 311.8361 311.9762 312.1162 312.2562 312.3962 312.5362 312.6761 312.8161 312.9560 313.0959 313.2359 313.3758 313.5156 313.6555 313.7954 313.9352 314.0750 314.2148 314.3546 314.4944 314.6342 314.7740 314.9137 315.0535 315.1932 315.3329 315.4726 315.6123 315.7519 315.8916 316.0312 316.1709 316.3105 316.4501 316.5897 316.7292 316.8688 317.0083 317.1479 317.2874 317.4269 317.5664 317.7059 317.8454 317.9848 318.1243 318.2637 318.4031 318.5425 318.6819 318.8213 318.9606 319.1000 319.2393 319.3787 319.5180 319.6573 319.7965 319.9358 320.0751 320.2143 320.3536 320.4928 320.6320 320.7712 320.9104 321.0495 321.1887 321.3278 321.4670 321.6061 321.7452 321.8843 322.0234 322.1624 322.3015 322.4405 322.5796 322.7186 322.8576 322.9966 323.1356 323.2745 323.4135 323.5524 323.6914 323.8303 323.9692 324.1081 324.2469 324.3858 324.5247 324.6635 324.8023 324.9411 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220106T155552.2Z 8041.663799 123 1 49.48 2 63.61 140.71 99.71 99.89 0.00 1 0.00 1 0 17 2.565e-02 6.452e-03 1.213e-02 2.427e-03 3.030513e-01 1.210293e-03 3.375555e-03 -6.000000e+00 1.450250e-02 224.32 -2.00 3.24 -2.00 318.28 0.00e+00 -9.440269e-05 2.306461e-04 1.055361e-04 -6.000000e+00 6.547211e-04 285.36 -2.00 20.00 -2.00 317.50 0.00e+00 2.237 0.000 302.00 328.00 3 4.1741e+00 3.2516e-03 2.6444e-02 -6.0000e+00 3.5720e-02 1.1178e-02 3.7157e-03 1.4312e-02 -6.0000e+00 3.8840e-02 3.2692e-02 2.4043e-03 7.0894e-03 -6.0000e+00 2.3236e-02 -1.9737e-02 1.2441e-03 2.0215e-03 -6.0000e+00 9.9950e-03 5.9729e-04 2.2774e-04 7.1655e-05 2.3236e-05 -6.0000e+00 6.9679e-04 -4.5264e-03 1.8212e-04 11 8 0 10 0 0 100.00 23.87 0.10 -0.00453 -0.00282 244 52 2 5 0 202.740 26.41 20.01 23.87 26.55 24.3 1100.00 -4442 1965 -7839 10706 -7541 5275 12414 8232 5939 5101 -4309 4605 -2964 -981 -2758 8572 -242 -1500 -725 -3637 2685 -2657 1816 486 -369 -1366 -1990 3906 271 -1401 5038 5041 646 1905 -3277 1973 -1679 1869 -1249 -1716 -2623 -697 -756 -1041 124 -1216 -1624 -2678 742 -727 1030 -265 946 823 953 773 1509 -388 502 384 74 246 -248 1562 -487 13 -801 56 751 757 315 455 421 513 1372 709 -518 -566 794 26 -41 -1577 -1425 -537 -1074 -920 -375 232 -68 842 533 769 144 760 85 681 149 507 283 -146 -257 -652 -477 -891 -132 -754 -348 -1350 73 1953 270 -180 -110 236 -393 406 -352 -130 -526 -6 -540 -178 -230 422 133 773 -199 756 353 264 525 -418 116 327 235 -167 -81 -11 144 -143 128 -356 -344 -299 136 -599 654 -493 305 725 559 453 409 -375 390 -303 -113 -366 1122 -36 -236 -118 -631 446 -463 315 91 -73 -284 -414 729 50 -262 955 1039 150 445 -760 435 -420 527 -429 -679 -1133 -309 -345 -479 57 -562 -744 -1221 326 -329 486 -136 506 463 552 459 904 -236 298 227 45 160 -176 1155 -366 9 -535 37 523 588 265 396 366 430 1069 507 -345 -365 533 20 -34 -1457 -1391 -542 -1154 -1046 -443 280 -83 980 584 781 138 709 84 731 176 650 381 -195 -328 -777 -542 -1040 -163 -983 -469 -1908 106 2968 435 -296 -177 359 -563 550 -478 -182 -779 -10 -855 -279 -352 625 190 1056 -263 997 493 391 814 -670 189 548 411 -306 -152 -20 274 -269 234 -631 -598 SS 20220106T162012.4Z 8041.680699 141 1 2.98 2 60.45 145.98 94.67 102.62 0.00 1 0.00 1 0 17 8.270e-03 5.405e-03 5.435e-03 2.427e-03 2.701093e-01 1.220678e-03 3.039773e-03 -6.000000e+00 4.672825e-03 224.32 -2.00 3.24 -2.00 316.44 0.00e+00 2.506871e-04 1.452274e-04 4.540610e-05 -6.000000e+00 2.110503e-04 285.36 -2.00 20.00 -2.00 315.70 0.00e+00 2.019 0.000 302.00 328.00 3 2.9686e+00 3.1543e-03 2.3731e-02 -6.0000e+00 1.1509e-02 1.9914e-02 3.5397e-03 1.2647e-02 -6.0000e+00 1.2517e-02 1.4425e-03 2.0659e-03 6.2580e-03 -6.0000e+00 7.4882e-03 -3.3572e-03 9.8695e-04 1.7885e-03 -6.0000e+00 3.2193e-03 2.6112e-03 -2.5728e-04 6.9123e-05 2.1648e-05 -6.0000e+00 2.2472e-04 -4.1981e-03 3.3905e-05 12 1 1 12 1 1 98.69 23.86 0.31 -0.00420 -0.00613 7 30 1 5 0 350.020 26.41 20.00 23.86 26.91 24.1 1100.00 680 -1989 -1510 -2826 -700 -2886 311 145 1001 -2282 -1233 192 -1975 -492 -90 -826 -653 48 540 713 244 674 1097 1367 448 841 -439 288 427 -278 1597 1695 1412 280 -1230 -2097 -1964 -917 125 17 -340 -821 -51 -1186 -427 175 -660 -558 143 -39 590 272 276 525 205 536 1057 -51 -193 750 619 1014 1362 1178 635 -369 -691 -447 651 655 -56 274 563 706 129 231 -817 -464 -496 -499 -1179 -1073 -1707 -1595 -1094 -611 -341 453 13 530 551 95 -42 601 553 18 360 901 188 -79 -95 -234 -222 -548 -637 -609 -601 -602 -32 676 212 118 7 -31 -245 -118 -79 -40 220 -52 -238 -91 352 565 157 252 362 393 611 364 475 -60 14 227 353 74 -184 256 -184 -181 -265 -503 -584 112 -363 -277 -482 -105 -431 48 26 194 -474 -250 40 -451 -127 -25 -252 -207 16 183 250 82 237 374 493 172 333 -174 106 156 -96 580 669 605 116 -511 -874 -855 -442 68 10 -223 -541 -34 -811 -289 117 -437 -361 94 -26 399 190 204 407 157 420 837 -41 -150 576 493 835 1215 1075 577 -325 -568 -375 558 611 -55 271 552 687 121 202 -682 -370 -417 -455 -1129 -1094 -1805 -1768 -1249 -721 -410 556 16 645 639 104 -44 608 592 20 431 1151 249 -103 -120 -280 -260 -641 -784 -793 -795 -810 -44 980 316 175 10 -44 -326 -152 -104 -53 304 -75 -350 -133 496 784 214 336 459 498 799 498 684 -87 20 338 541 116 -300 412 -300 -297 -419 -786 -891 SS 20220106T163015.9Z 8041.687685 144 1 48.69 2 59.27 148.29 92.59 103.77 0.00 1 0.00 1 0 17 1.130e-01 1.709e-02 2.120e-02 5.158e-03 2.807129e-01 2.574394e-03 3.112935e-03 -6.000000e+00 6.399268e-02 224.32 -2.00 3.24 -2.00 317.50 0.00e+00 -1.952721e-04 3.973445e-04 7.148861e-05 -6.000000e+00 2.887860e-03 285.36 -2.00 20.00 -2.00 316.73 0.00e+00 1.949 0.000 302.00 328.00 3 6.6644e+00 6.7738e-03 2.3437e-02 -6.0000e+00 1.5761e-01 1.0952e-01 7.6747e-03 1.3120e-02 -6.0000e+00 1.7132e-01 -5.7618e-03 4.7050e-03 6.5092e-03 -6.0000e+00 1.0250e-01 -3.6460e-03 2.3712e-03 1.8580e-03 -6.0000e+00 4.4128e-02 6.5215e-05 9.3705e-04 1.4963e-04 2.1285e-05 -6.0000e+00 3.0704e-03 -6.4666e-03 3.6472e-04 12 8 8 10 0 0 99.93 23.88 0.56 -0.00647 0.00057 20 4 1 5 0 2434.060 26.41 19.99 23.88 27.07 24.1 1100.00 82388 7422 -4391 8156 -6562 3028 76407 -11213 43693 -2449 -12602 5464 -15936 -2258 -3021 30560 -3786 6138 -8824 6789 1469 3868 -3597 1339 -4991 -2841 -5847 5749 -1930 -8264 15388 3903 990 -6003 -7829 1790 6024 3979 3019 -2367 -3394 2798 3472 869 1438 3397 -5943 -3471 1528 -484 -3715 -1166 -63 427 4086 -193 2852 -4379 761 -2576 1340 -1651 1412 158 792 -2022 -2100 -1705 -106 699 183 3169 1893 71 3712 2447 -4114 -250 -1302 885 414 -1610 -2320 4123 -198 -1207 1521 -22 43 877 1384 -498 -248 -916 -1213 372 -570 531 897 -762 269 49 -2116 -2587 1817 -754 -1508 -1826 1612 -432 1361 1318 1053 -345 -1155 -1167 -1255 -1811 -1449 -733 -31 812 1008 1195 360 1533 -1220 636 -1036 1071 425 -466 -447 2508 183 410 594 599 -588 -496 371 -1588 -482 3910 755 -504 776 -644 265 3662 -1346 3484 -311 -1744 665 -2657 -378 -577 4641 -825 1267 -2167 1492 343 877 -900 338 -1407 -812 -1703 1416 -480 -2166 3448 1051 295 -1936 -2415 500 1769 1381 1250 -1176 -1836 1489 1881 483 794 1837 -3435 -1923 798 -260 -2163 -708 -40 281 2675 -133 1950 -3173 517 -1791 926 -1247 1117 133 660 -1613 -1577 -1255 -82 594 168 2939 1766 65 3093 1877 -3067 -173 -953 703 366 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