File name: Pandora25s1_HoustonTX_20220126_L2Fit_fout2c5d20210307p1-8.txt File generation date: 20250922T143928.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v5d20210307.txt Level 1 file used: Pandora25s1_HoustonTX_20220126_L1_smca1c5d20210307p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20220126 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.0981 305.2388 305.3795 305.5202 305.6609 305.8015 305.9421 306.0828 306.2234 306.3640 306.5045 306.6451 306.7857 306.9262 307.0667 307.2072 307.3477 307.4882 307.6287 307.7691 307.9096 308.0500 308.1904 308.3308 308.4712 308.6115 308.7519 308.8922 309.0326 309.1729 309.3132 309.4535 309.5937 309.7340 309.8742 310.0144 310.1547 310.2949 310.4350 310.5752 310.7154 310.8555 310.9956 311.1358 311.2759 311.4160 311.5560 311.6961 311.8361 311.9762 312.1162 312.2562 312.3962 312.5362 312.6761 312.8161 312.9560 313.0959 313.2359 313.3758 313.5156 313.6555 313.7954 313.9352 314.0750 314.2148 314.3546 314.4944 314.6342 314.7740 314.9137 315.0535 315.1932 315.3329 315.4726 315.6123 315.7519 315.8916 316.0312 316.1709 316.3105 316.4501 316.5897 316.7292 316.8688 317.0083 317.1479 317.2874 317.4269 317.5664 317.7059 317.8454 317.9848 318.1243 318.2637 318.4031 318.5425 318.6819 318.8213 318.9606 319.1000 319.2393 319.3787 319.5180 319.6573 319.7965 319.9358 320.0751 320.2143 320.3536 320.4928 320.6320 320.7712 320.9104 321.0495 321.1887 321.3278 321.4670 321.6061 321.7452 321.8843 322.0234 322.1624 322.3015 322.4405 322.5796 322.7186 322.8576 322.9966 323.1356 323.2745 323.4135 323.5524 323.6914 323.8303 323.9692 324.1081 324.2469 324.3858 324.5247 324.6635 324.8023 324.9411 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220126T142630.0Z 8061.601737 250 1 2.08 2 76.71 120.84 51.07 204.50 0.00 1 0.00 1 0 17 2.583e-01 8.511e-03 2.543e-01 9.356e-03 4.975329e-01 4.796142e-03 5.329051e-03 -6.000000e+00 1.470110e-01 224.64 -2.00 3.24 -2.00 319.70 0.00e+00 7.004645e-04 1.486055e-03 3.298839e-04 -6.000000e+00 6.794906e-03 284.90 -2.00 20.00 -2.00 319.00 0.00e+00 4.242 0.001 302.00 328.00 3 2.3913e+00 1.3799e-02 4.8232e-02 -6.0000e+00 3.6234e-01 -1.0887e-02 1.6709e-02 2.3737e-02 -6.0000e+00 3.9424e-01 3.2186e-02 1.4347e-02 1.1932e-02 -6.0000e+00 2.3576e-01 -2.0800e-02 7.5017e-03 3.6531e-03 -6.0000e+00 1.0167e-01 4.1485e-04 1.8070e-04 2.6679e-04 3.9385e-05 -6.0000e+00 7.0678e-03 -7.9186e-03 1.2262e-04 12 9 1 12 1 1 999.00 23.35 0.46 -0.00792 -0.00656 2 17 1 5 0 634.300 26.00 20.00 23.35 10.81 23.3 1064.39 -58267 900000 -28366 72524 900000 25331 54166 15048 86043 228966 102256 38695 -7497 -1907 -7508 900000 328 12919 3491 10455 10869 13802 -38242 7404 7841 -1556 -4754 11313 -21837 -335 6303 14878 14286 -5961 1316 854 -2350 1840 650 -5360 5541 -849 -2448 -691 4137 -3979 2522 -2011 3413 -556 -279 1815 -3365 2391 -582 1040 1090 -4928 1677 1791 -385 194 3238 -729 2834 -753 -868 17 -2523 482 -426 104 655 1222 631 1080 -1322 1783 136 -819 -1787 -812 -1036 580 -618 -64 463 -1588 22 897 -381 811 440 658 -365 1588 240 1001 254 -106 -564 -1049 916 -689 -981 -609 -32 -89 -1116 1390 -190 -129 -267 664 538 -426 -312 80 736 -78 -72 -198 -675 709 640 -4 -658 -23 520 -115 564 -594 258 -622 369 -629 369 540 -714 67 169 8 49 -982 900000 -430 661 900000 231 494 172 785 2088 932 499 -182 -54 -269 900000 14 523 165 488 518 647 -3073 425 483 -110 -351 695 -1783 -24 479 1197 1299 -681 135 89 -279 249 107 -1090 1128 -194 -591 -167 971 -1018 616 -519 862 -153 -83 580 -1207 872 -227 415 445 -2113 668 709 -160 87 1558 -391 1513 -399 -450 9 -1454 302 -289 73 453 811 395 620 -728 957 80 -544 -1335 -659 -896 517 -584 -63 473 -1681 23 909 -371 742 388 585 -349 1642 275 1236 331 -138 -707 -1237 1016 -781 -1173 -755 -41 -118 -1575 2053 -300 -209 -430 1030 801 -619 -453 119 1135 -126 -115 -314 -1053 1073 942 -6 -929 -32 786 -186 954 -1047 463 -1158 709 -1259 744 1102 -1472 136 331 15 91 SS 20220126T143635.8Z 8061.608748 253 1 49.46 2 74.84 122.38 52.04 207.24 0.00 1 0.00 1 0 25 2.365e-02 4.393e-03 5.475e-03 4.123e-04 4.429820e-01 2.076445e-04 4.829010e-03 -6.000000e+00 1.338699e-02 224.64 -2.00 3.24 -2.00 319.06 0.00e+00 4.453761e-04 5.158591e-05 2.034647e-04 -6.000000e+00 6.024864e-04 284.90 -2.00 20.00 -2.00 318.32 0.00e+00 3.751 0.001 302.00 328.00 3 4.1926e-01 5.7581e-04 4.2736e-02 -6.0000e+00 3.3001e-02 -7.3905e-03 6.7164e-04 2.1129e-02 -6.0000e+00 3.5879e-02 1.4467e-02 5.1083e-04 1.0418e-02 -6.0000e+00 2.1453e-02 -1.3505e-02 2.7146e-04 3.0514e-03 -6.0000e+00 9.2186e-03 5.0871e-03 -3.1448e-04 1.1773e-05 3.2840e-05 -6.0000e+00 6.4259e-04 -7.5561e-03 6.3252e-05 10 0 0 10 0 0 97.64 23.34 0.46 -0.00756 -0.00992 871 185 1 5 0 56.710 26.00 20.00 23.34 11.14 23.4 1066.69 -1918 8802 6904 6760 8423 4710 13929 3196 11475 3085 5827 2381 3383 1574 1849 2570 45 2028 -996 1249 -528 473 -2479 62 -1218 329 -1274 -60 -1001 -1277 1041 967 1024 -1185 -2205 -2825 -2192 -1875 -889 -1514 -1446 -1351 -1180 -1037 -732 -496 -1121 -652 -939 -328 17 419 326 832 389 692 586 400 360 373 666 834 1396 1531 946 -60 -163 -518 427 803 473 579 309 525 369 107 -381 -467 -357 -315 -629 -792 -1514 -1428 -1012 -539 -203 144 506 672 662 624 422 453 600 283 505 625 327 -109 -369 -682 -575 -168 -538 -869 -659 -667 -341 303 153 180 100 141 -68 76 106 35 23 -113 -435 -222 9 245 317 463 96 629 547 365 201 -35 -99 28 -18 -14 -147 154 -10 -42 -89 -201 -287 -41 190 158 147 164 95 282 83 310 97 183 85 144 76 107 169 3 157 -84 109 -48 43 -243 6 -138 39 -153 -7 -110 -147 132 140 154 -189 -338 -436 -375 -382 -219 -412 -436 -432 -392 -350 -248 -170 -387 -225 -331 -120 7 170 143 390 192 352 307 209 184 189 349 448 829 991 628 -38 -100 -321 286 577 353 450 240 410 266 70 -243 -294 -244 -234 -508 -719 -1420 -1414 -1015 -576 -228 158 554 742 679 624 396 426 611 310 597 792 428 -142 -473 -837 -657 -195 -677 -1109 -882 -904 -494 456 239 291 160 213 -100 110 153 51 36 -178 -693 -345 14 369 477 667 133 879 800 588 335 -58 -172 50 -33 -26 -289 297 -19 -82 -166 -372 -517 SS 20220126T144626.3Z 8061.615583 256 1 49.47 2 73.05 123.93 53.06 209.83 0.00 1 0.00 1 0 25 1.974e-02 4.108e-03 9.676e-03 8.710e-04 4.021660e-01 4.382185e-04 4.400264e-03 -6.000000e+00 1.117363e-02 224.64 -2.00 3.24 -2.00 319.16 0.00e+00 1.821403e-04 1.109893e-04 2.245481e-04 -6.000000e+00 5.028819e-04 284.90 -2.00 20.00 -2.00 318.42 0.00e+00 3.378 0.000 302.00 328.00 3 2.0181e+00 1.2202e-03 3.8578e-02 -6.0000e+00 2.7545e-02 -7.5438e-03 1.4260e-03 1.9205e-02 -6.0000e+00 2.9947e-02 2.8950e-02 1.0697e-03 9.4726e-03 -6.0000e+00 1.7906e-02 -1.8730e-02 5.6538e-04 2.7311e-03 -6.0000e+00 7.6944e-03 1.5330e-03 -3.3748e-04 2.5467e-05 3.0477e-05 -6.0000e+00 5.3636e-04 -7.6741e-03 5.3276e-05 10 0 0 10 0 0 99.99 23.33 0.28 -0.00767 -0.01021 649 138 1 5 0 76.210 26.00 20.00 23.33 11.17 23.3 1066.67 1897 5148 3406 6556 1707 9386 7441 2180 7238 2736 -81 6511 -3038 349 1569 10446 812 -259 1120 1377 1125 169 -2885 -296 434 -518 729 348 -234 -163 1567 1937 943 -37 -2831 -1043 -1872 -507 -1261 -1558 -1226 -1467 -1125 -912 -731 -880 -1114 -1077 -747 -614 492 197 261 617 247 544 631 124 241 391 644 554 916 1551 592 -55 -246 -560 262 686 212 528 212 642 400 297 -184 -451 -317 -485 -570 -781 -1393 -1265 -977 -435 -80 304 504 716 614 709 188 475 545 418 401 646 522 -105 -277 -729 -622 -327 -439 -769 -494 -638 -228 485 196 133 176 58 -177 72 -14 38 -99 -68 -491 -200 -35 225 169 469 -7 484 368 286 259 -109 -203 27 1 82 -37 139 51 -43 -86 -144 -243 47 137 96 178 44 224 199 67 237 100 -3 254 -147 20 103 710 62 -21 97 125 104 16 -294 -32 50 -63 88 40 -26 -19 196 272 142 -6 -433 -157 -316 -100 -293 -428 -370 -470 -373 -306 -247 -300 -379 -367 -256 -218 179 79 112 282 118 268 305 60 119 191 326 293 534 975 365 -33 -143 -329 166 473 161 401 160 481 278 193 -111 -266 -201 -339 -456 -673 -1302 -1199 -989 -453 -87 341 564 770 636 677 175 438 521 450 469 817 684 -137 -352 -879 -702 -375 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