File name: Pandora25s1_HoustonTX_20220521_L2Fit_fout2c6d20220503p1-8.txt File generation date: 20250922T145749.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v6d20220503.txt Level 1 file used: Pandora25s1_HoustonTX_20220521_L1_smca1c6d20220503p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20220521 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update session 4 for SO2 First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.1116 305.2524 305.3931 305.5338 305.6745 305.8152 305.9558 306.0965 306.2371 306.3777 306.5183 306.6589 306.7995 306.9401 307.0806 307.2212 307.3617 307.5022 307.6427 307.7832 307.9236 308.0641 308.2045 308.3449 308.4853 308.6257 308.7661 308.9065 309.0468 309.1872 309.3275 309.4678 309.6081 309.7484 309.8886 310.0289 310.1691 310.3093 310.4495 310.5897 310.7299 310.8701 311.0102 311.1504 311.2905 311.4306 311.5707 311.7108 311.8509 311.9909 312.1310 312.2710 312.4110 312.5510 312.6910 312.8310 312.9709 313.1109 313.2508 313.3907 313.5306 313.6705 313.8104 313.9503 314.0901 314.2300 314.3698 314.5096 314.6494 314.7892 314.9290 315.0687 315.2085 315.3482 315.4879 315.6276 315.7673 315.9070 316.0466 316.1863 316.3259 316.4656 316.6052 316.7448 316.8843 317.0239 317.1635 317.3030 317.4425 317.5821 317.7216 317.8611 318.0005 318.1400 318.2794 318.4189 318.5583 318.6977 318.8371 318.9765 319.1159 319.2552 319.3946 319.5339 319.6732 319.8125 319.9518 320.0911 320.2304 320.3696 320.5089 320.6481 320.7873 320.9265 321.0657 321.2049 321.3441 321.4832 321.6223 321.7615 321.9006 322.0397 322.1788 322.3178 322.4569 322.5960 322.7350 322.8740 323.0130 323.1520 323.2910 323.4300 323.5689 323.7079 323.8468 323.9857 324.1246 324.2635 324.4024 324.5413 324.6801 324.8190 324.9578 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220521T132754.5Z 8176.561047 249 1 49.39 2 65.40 79.81 58.23 210.16 0.00 1 0.00 1 0 17 9.501e-03 4.638e-03 2.120e-03 5.082e-04 3.195003e-01 2.585481e-04 3.484851e-03 -6.000000e+00 5.487439e-03 231.01 -2.00 3.24 -2.00 317.84 0.00e+00 2.440542e-04 4.380715e-05 7.476198e-05 -6.000000e+00 2.480871e-04 290.59 -2.00 20.00 -2.00 316.94 0.00e+00 2.386 0.000 302.00 328.00 3 2.2573e+00 6.9591e-04 2.8410e-02 -6.0000e+00 1.3702e-02 -2.7779e-02 7.8848e-04 1.5429e-02 -6.0000e+00 1.4836e-02 4.9768e-03 4.8631e-04 7.4511e-03 -6.0000e+00 8.8555e-03 -4.6630e-03 2.4505e-04 2.0436e-03 -6.0000e+00 3.7552e-03 3.5211e-03 -6.3193e-05 1.4721e-05 2.2225e-05 -6.0000e+00 2.5909e-04 5.5230e-03 -2.9458e-05 10 0 0 10 0 0 100.00 23.41 0.22 0.00552 0.00505 534 113 1 5 0 92.480 26.11 20.01 23.41 34.52 25.3 1012.67 49 -1313 -2517 -1603 -5024 -2885 -1901 -759 -489 -1885 -3553 -1128 -2294 -1339 -352 376 73 141 51 749 954 338 384 -79 247 211 297 -223 -763 -103 1274 1248 1068 -520 -2390 -1524 -1914 -818 -625 -801 -783 -560 -369 -569 -148 -366 -430 -458 -401 80 627 478 784 881 529 705 685 535 485 540 726 1122 1223 1458 388 -137 -455 -521 375 450 239 391 256 302 269 -96 -554 -800 -236 -583 -821 -1035 -1755 -1289 -843 -480 -194 173 493 473 470 474 243 441 337 182 416 613 53 -272 -468 -863 -479 -214 -465 -757 -435 -566 -78 352 270 116 171 25 -74 132 130 -8 55 20 -299 -83 110 184 346 349 216 785 577 473 311 -93 -32 73 117 21 -48 109 -29 -209 -227 -350 -444 4 -108 -211 -121 -359 -203 -146 -66 -47 -188 -361 -121 -290 -182 -54 63 13 26 10 150 193 69 82 -18 60 53 73 -52 -169 -23 312 314 293 -144 -635 -410 -584 -294 -254 -375 -372 -277 -188 -291 -75 -187 -217 -228 -199 41 343 282 463 548 341 465 460 356 317 354 497 788 938 1181 311 -102 -323 -372 292 377 217 366 237 266 229 -74 -415 -590 -178 -478 -760 -1007 -1829 -1346 -942 -546 -231 210 595 545 522 505 241 437 361 209 508 793 70 -362 -581 -1032 -547 -255 -576 -993 -597 -784 -114 529 413 179 265 35 -103 182 181 -11 80 30 -462 -126 162 269 482 483 286 1058 807 713 477 -148 -50 119 197 37 -84 195 -52 -364 -393 -584 -756 SS 20220521T133531.4Z 8176.566336 254 1 8.81 2 63.77 80.62 59.04 211.94 0.00 1 0.00 1 0 17 4.282e-02 8.075e-03 1.250e-02 3.417e-03 3.041851e-01 1.740899e-03 3.331015e-03 -6.000000e+00 2.473862e-02 231.01 -2.00 3.24 -2.00 317.50 0.00e+00 -6.474130e-05 2.703859e-04 6.612605e-05 -6.000000e+00 1.118249e-03 290.59 -2.00 20.00 -2.00 316.61 0.00e+00 2.249 0.000 302.00 328.00 3 4.3300e+00 4.6520e-03 2.6872e-02 -6.0000e+00 6.1772e-02 -9.5332e-03 5.2485e-03 1.4684e-02 -6.0000e+00 6.6878e-02 1.7431e-02 3.1771e-03 7.0877e-03 -6.0000e+00 3.9920e-02 -1.0646e-02 1.5822e-03 1.9244e-03 -6.0000e+00 1.6931e-02 5.0987e-04 2.2007e-04 9.8459e-05 2.1590e-05 -6.0000e+00 1.1677e-03 5.0753e-03 1.0541e-05 12 9 1 12 1 1 99.89 23.41 0.06 0.00508 0.00673 6 8 1 5 0 1233.700 26.11 20.00 23.41 35.07 25.4 1015.57 -15588 6148 -16395 8157 -18262 4811 12874 4111 16281 -1355 7968 3014 -802 -5414 -1552 27537 1436 971 1952 -4315 2385 3536 -738 862 -1231 1817 -1229 2138 -4792 -2724 -6164 3662 2739 -856 -2402 -541 1125 1217 189 -1565 -1296 64 -891 -910 -798 -616 -1275 -642 1596 744 -2227 681 -385 1227 -11 1462 547 -243 -1298 40 1370 30 1809 1183 85 -236 256 -765 650 -1511 857 203 1259 782 595 -142 -596 129 -84 -61 -471 -606 -1580 -168 -392 -972 -202 137 287 568 624 -61 809 78 598 360 504 518 623 -333 -123 -996 -1347 -222 39 -1431 -237 -570 32 -512 382 221 134 -40 212 -61 3 -484 415 -82 -133 -154 111 -140 610 459 67 977 815 456 193 -55 -547 135 169 -239 335 76 -47 -533 -180 -21 -265 -1621 562 -1840 675 -1766 380 1035 404 1568 -158 853 362 -114 -916 -286 4224 290 206 426 -1029 541 797 -180 220 -335 496 -338 541 -1233 -704 -1763 1043 841 -270 -729 -165 374 467 84 -790 -692 35 -500 -512 -450 -346 -712 -353 859 412 -1330 420 -250 819 -8 1015 386 -172 -911 28 978 23 1450 988 70 -186 193 -584 525 -1345 791 192 1174 710 511 -114 -453 97 -66 -52 -440 -604 -1647 -180 -439 -1141 -243 168 348 669 699 -65 817 79 634 409 614 669 827 -437 -154 -1198 -1585 -268 50 -1879 -319 -789 46 -766 585 341 202 -58 292 -82 4 -674 598 -122 -200 -230 163 -201 846 619 88 1296 1132 663 289 -84 -852 215 278 -407 575 133 -82 -918 -303 -35 -432 SS 20220521T134106.9Z 8176.570219 257 1 49.43 2 62.57 81.21 59.66 213.22 0.00 1 0.00 1 0 25 6.351e-02 1.110e-02 1.716e-02 3.476e-03 3.023886e-01 1.769787e-03 3.355944e-03 -6.000000e+00 3.664592e-02 231.01 -2.00 3.24 -2.00 318.40 0.00e+00 2.004309e-04 3.430225e-04 2.375177e-04 -6.000000e+00 1.657395e-03 290.59 -2.00 20.00 -2.00 317.49 0.00e+00 2.159 0.000 302.00 328.00 3 5.4155e+00 4.8363e-03 2.6169e-02 -6.0000e+00 9.1506e-02 1.4309e-02 5.5239e-03 1.4786e-02 -6.0000e+00 9.9102e-02 1.8876e-02 3.4835e-03 7.1323e-03 -6.0000e+00 5.9154e-02 -1.3606e-02 1.7712e-03 1.9418e-03 -6.0000e+00 2.5068e-02 1.8528e-04 -1.3764e-03 1.0301e-04 2.2435e-05 -6.0000e+00 1.7322e-03 6.5186e-03 -1.9129e-04 12 8 8 10 0 0 99.99 23.41 0.16 0.00652 -0.00382 183 39 1 5 0 270.060 26.11 20.00 23.41 35.39 25.3 1016.95 -57384 -126 -283 11758 138 2193 20941 452 12890 1478 -6969 18168 -9928 8021 -6197 17223 -2454 6050 -3143 5853 777 523 -380 -3378 2057 1752 3011 -2129 2942 -8947 13094 4142 4475 1360 -4004 1146 1145 4030 -108 -1748 -3687 325 9 315 -432 -391 -1568 -1588 351 427 1798 363 -324 2227 1206 632 2692 -2019 1037 -202 268 -426 466 1418 -109 51 -869 66 343 1752 -573 840 -219 945 1298 1198 -3056 -683 1020 100 -156 -1271 -1809 98 26 -2061 -627 -629 -334 440 1228 888 72 162 -1631 727 -373 902 15 110 -522 -1383 -1272 -664 -762 -402 -384 -706 -17 3433 445 -17 625 -393 82 187 59 -192 -671 -324 -893 204 372 945 -452 1299 -179 1309 -45 179 -70 -403 -41 773 -322 -100 324 179 55 -554 340 -962 -117 -6361 -9 -20 709 8 133 1176 34 944 123 -623 1396 -1107 873 -863 2100 -372 891 -522 930 130 88 -67 -652 397 350 584 -407 515 -1779 2308 860 996 311 -907 252 281 1129 -37 -692 -1591 141 4 140 -194 -175 -701 -700 151 188 835 182 -173 1219 685 369 1563 -1214 597 -118 162 -279 327 1037 -79 35 -564 43 240 1348 -482 718 -187 767 978 820 -2013 -432 680 75 -131 -1168 -1759 99 27 -2368 -742 -761 -402 504 1306 877 67 150 -1639 785 -446 1161 20 145 -653 -1625 -1441 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