File name: Pandora25s1_HoustonTX_20220620_L2Fit_fout2c6d20220503p1-8.txt File generation date: 20250922T150734.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v6d20220503.txt Level 1 file used: Pandora25s1_HoustonTX_20220620_L1_smca1c6d20220503p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20220620 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update session 4 for SO2 First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.1116 305.2524 305.3931 305.5338 305.6745 305.8152 305.9558 306.0965 306.2371 306.3777 306.5183 306.6589 306.7995 306.9401 307.0806 307.2212 307.3617 307.5022 307.6427 307.7832 307.9236 308.0641 308.2045 308.3449 308.4853 308.6257 308.7661 308.9065 309.0468 309.1872 309.3275 309.4678 309.6081 309.7484 309.8886 310.0289 310.1691 310.3093 310.4495 310.5897 310.7299 310.8701 311.0102 311.1504 311.2905 311.4306 311.5707 311.7108 311.8509 311.9909 312.1310 312.2710 312.4110 312.5510 312.6910 312.8310 312.9709 313.1109 313.2508 313.3907 313.5306 313.6705 313.8104 313.9503 314.0901 314.2300 314.3698 314.5096 314.6494 314.7892 314.9290 315.0687 315.2085 315.3482 315.4879 315.6276 315.7673 315.9070 316.0466 316.1863 316.3259 316.4656 316.6052 316.7448 316.8843 317.0239 317.1635 317.3030 317.4425 317.5821 317.7216 317.8611 318.0005 318.1400 318.2794 318.4189 318.5583 318.6977 318.8371 318.9765 319.1159 319.2552 319.3946 319.5339 319.6732 319.8125 319.9518 320.0911 320.2304 320.3696 320.5089 320.6481 320.7873 320.9265 321.0657 321.2049 321.3441 321.4832 321.6223 321.7615 321.9006 322.0397 322.1788 322.3178 322.4569 322.5960 322.7350 322.8740 323.0130 323.1520 323.2910 323.4300 323.5689 323.7079 323.8468 323.9857 324.1246 324.2635 324.4024 324.5413 324.6801 324.8190 324.9578 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220620T120133.6Z 8206.501084 206 1 48.04 2 82.95 67.00 37.92 179.82 0.00 1 0.00 1 0 25 1.512e+00 7.308e-02 3.056e-01 1.344e-02 8.683598e-01 1.072308e-02 2.060562e-02 -6.000000e+00 9.626995e-01 230.79 -2.00 3.24 -2.00 307.12 0.00e+00 8.831262e-02 5.165281e-03 9.332083e-03 -6.000000e+00 5.291788e-02 292.90 -2.00 20.00 -2.00 307.18 0.00e+00 7.469 0.005 302.00 328.00 3 1.7696e+00 4.0517e-02 9.5929e-02 -6.0000e+00 2.4151e+00 2.8441e+00 4.6557e-02 1.3514e-01 -6.0000e+00 2.6451e+00 -3.3584e+00 1.7451e-02 2.1366e-02 -6.0000e+00 1.5494e+00 1.3322e+00 1.1778e-02 6.4542e-02 -6.0000e+00 6.5995e-01 1.1674e-05 -8.8478e-03 4.7680e-04 1.2863e-03 -6.0000e+00 4.8591e-02 7.0610e-03 -1.0649e-04 12 8 8 10 0 0 32.78 23.91 0.65 0.00706 -0.05943 13 3 1 5 0 3694.980 26.51 20.01 23.91 34.98 25.7 1011.95 -87 900000 758208 900000 900000 900000 900000 900000 900000 325673 181728 900000 232071 900000 900000 900000 900000 900000 484346 900000 900000 388585 301423 900000 153980 900000 167666 169003 225003 93576 900000 338699 900000 436572 145499 900000 900000 900000 900000 410075 89993 900000 900000 900000 900000 900000 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9222 6750 6913 3103 6506 5608 -6910 2974 5587 2884 4745 1752 -2955 12097 4369 -6681 -3846 -3488 -5970 -4434 -951 2832 -4775 -6324 -18619 -3010 -6557 2278 245 -2215 4726 -5390 669 -8692 6430 -100 -15149 -10331 7752 31947 -4835 -928 5795 -8462 -2612 -4391 -2453 764 1208 3155 2792 8664 8505 6865 -692 10319 -3369 6228 -1279 5127 926 2094 134 11182 -5635 -3230 2715 1594 -2887 -2196 4820 -11233 -3739 SS 20220620T121241.6Z 8206.508814 209 1 49.74 2 80.71 68.24 37.95 184.23 0.00 1 0.00 1 0 17 5.647e-01 1.356e-02 2.261e-01 4.041e-03 7.422523e-01 2.282798e-03 7.644487e-03 -6.000000e+00 3.340405e-01 230.79 -2.00 3.24 -2.00 321.46 0.00e+00 -1.508147e-03 1.258635e-03 7.041962e-04 -6.000000e+00 1.679345e-02 292.90 -2.00 20.00 -2.00 320.82 0.00e+00 5.884 0.002 302.00 328.00 3 2.1526e+00 8.6627e-03 6.8962e-02 -6.0000e+00 8.3603e-01 6.4786e-02 1.2709e-02 3.7283e-02 -6.0000e+00 9.0918e-01 -1.5949e-01 1.2586e-02 1.9082e-02 -6.0000e+00 5.3559e-01 6.4379e-02 5.7794e-03 5.4743e-03 -6.0000e+00 2.3074e-01 8.8588e-05 -5.6990e-04 1.1347e-04 6.3750e-05 -6.0000e+00 1.6148e-02 1.2776e-03 6.1376e-05 12 8 8 10 0 0 -5.34 23.93 0.53 0.00128 -0.00300 59 13 1 5 0 842.940 26.51 19.99 23.93 35.56 25.7 1015.15 900000 900000 -223846 900000 -176775 900000 900000 -45220 900000 -129370 -276011 900000 -169238 900000 -69136 900000 56921 345480 75797 900000 14603 -83966 -75190 -7453 6344 -15405 -17041 -61476 -25278 -61298 900000 -10684 13908 13376 -61377 26896 55031 148552 30170 681 -7591 26907 41434 32305 30290 24790 -15282 -8473 22315 -3303 29518 -202 2015 11942 7746 2819 11758 -12572 7836 2825 9567 -5700 -503 5441 80 4260 953 -76 4130 4558 5373 2201 3272 3176 4127 4511 -7583 -2907 1864 -163 -153 -2658 -2718 3391 -173 -2249 429 778 -1454 470 1643 2014 -331 -837 -3689 235 -549 707 -602 -1091 -400 -1849 -958 -1386 915 -482 -1574 -989 1201 -546 44 304 1084 -148 56 42 -285 220 -424 -111 -520 849 650 586 -463 1696 -196 1048 116 -75 200 -360 -193 968 -183 -134 296 185 -340 -301 531 -776 -373 900000 900000 -2312 900000 -1040 900000 900000 -178 900000 -857 -8161 900000 -2773 900000 -691 900000 224 1359 299 900000 114 -1742 -1574 -92 75 -240 -272 -1453 -427 -1648 900000 -258 307 310 -2790 548 979 1312 1028 36 -489 1347 1893 1633 1585 1399 -1294 -707 1490 -307 2282 -23 249 1471 1058 425 1680 -2239 1123 419 1394 -1063 -102 1167 19 950 222 -19 1118 1403 1786 778 1124 1029 1212 1202 -2171 -835 587 -62 -67 -1350 -1499 1878 -106 -1478 287 531 -1005 308 1004 1169 -194 -520 -2647 187 -501 716 -658 -1189 -409 -1751 -844 -1246 857 -480 -1662 -1108 1441 -736 65 464 1658 -224 81 60 -409 328 -664 -178 -825 1292 963 847 -656 2298 -265 1472 182 -130 374 -711 -398 2077 -416 -317 707 447 -824 -706 1182 -1669 -782 SS 20220620T122222.4Z 8206.515537 214 1 49.61 2 78.75 69.31 38.13 188.04 0.00 1 0.00 1 0 25 2.700e-01 6.140e-03 1.572e-01 1.851e-03 6.407884e-01 9.877781e-04 6.725829e-03 -6.000000e+00 1.576886e-01 230.79 -2.00 3.24 -2.00 320.79 0.00e+00 1.011212e-03 4.434417e-04 3.565860e-04 -6.000000e+00 7.131644e-03 292.90 -2.00 20.00 -2.00 320.06 0.00e+00 4.948 0.001 302.00 328.00 3 1.7873e+00 3.2917e-03 5.8345e-02 -6.0000e+00 3.9375e-01 -1.2366e-02 4.3947e-03 3.1496e-02 -6.0000e+00 4.2668e-01 -1.8942e-02 4.1530e-03 1.5798e-02 -6.0000e+00 2.5411e-01 -7.9925e-04 2.0317e-03 4.9656e-03 -6.0000e+00 1.0738e-01 3.3733e-04 -5.1769e-04 5.1050e-05 5.3434e-05 -6.0000e+00 7.4718e-03 1.4656e-03 4.8935e-05 10 0 0 10 0 0 13.74 23.91 0.34 0.00147 -0.00242 133 28 1 5 0 372.910 26.51 20.01 23.91 36.13 25.9 1018.30 -103726 -62631 -91598 44844 -40044 -103289 900000 -74996 25385 -85121 -139281 116948 -64694 18826 -45792 900000 -13055 22275 -28942 27918 -26474 -7858 -35762 -6024 -19412 -7560 -4433 -20827 -4384 -20720 26412 -2111 5175 -4380 -16024 -3510 4078 11406 2605 -1755 -6751 2141 2172 4896 4086 2935 -6050 2290 1880 953 4612 412 1045 2592 641 118 3001 -4062 1869 -1698 2413 -1354 1752 1297 -7 601 -646 -386 981 1100 1311 1269 337 951 629 999 -2894 -977 -424 -660 -885 -1240 -1753 -413 -308 -1035 317 471 909 774 1443 766 200 62 -669 43 164 132 -120 -55 -166 -855 -792 -723 -394 -844 -1176 -1004 5 1778 226 299 420 28 275 -9 211 31 -156 -337 -470 -193 105 69 187 588 18 754 95 205 16 -28 -278 167 -131 -58 -91 84 31 -91 272 -351 -65 -647 -298 -616 81 -145 -729 900000 -529 75 -824 -2491 211 -838 136 -789 900000 -216 289 -622 394 -605 -166 -995 -151 -558 -205 -117 -630 -124 -707 741 -86 226 -219 -865 -173 213 676 209 -162 -731 228 242 544 466 348 -805 292 254 142 744 78 215 573 143 28 703 -1014 429 -402 577 -375 537 444 -2 208 -226 -142 400 482 626 627 165 435 281 402 -1148 -393 -194 -335 -524 -837 -1214 -300 -240 -866 274 418 797 651 1123 563 143 46 -572 40 175 151 -148 -67 -188 -933 -803 -751 -439 -998 -1394 -1276 6 2558 364 479 668 46 419 -13 314 49 -247 -553 -764 -317 166 106 274 829 27 1084 155 356 30 -54 -564 343 -289 -127 -207 194 72 -200 591 -723 -129 SS 20220620T122821.7Z 8206.519695 217 1 49.52 2 77.54 69.95 38.31 190.38 0.00 1 0.00 1 0 25 2.611e-01 4.893e-03 1.059e-01 1.376e-03 5.872944e-01 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