File name: Pandora25s1_HoustonTX_20220712_L2Fit_fout2c6d20220503p1-8.txt File generation date: 20250922T152348.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v6d20220503.txt Level 1 file used: Pandora25s1_HoustonTX_20220712_L1_smca1c6d20220503p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20220712 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update session 4 for SO2 First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.1116 305.2524 305.3931 305.5338 305.6745 305.8152 305.9558 306.0965 306.2371 306.3777 306.5183 306.6589 306.7995 306.9401 307.0806 307.2212 307.3617 307.5022 307.6427 307.7832 307.9236 308.0641 308.2045 308.3449 308.4853 308.6257 308.7661 308.9065 309.0468 309.1872 309.3275 309.4678 309.6081 309.7484 309.8886 310.0289 310.1691 310.3093 310.4495 310.5897 310.7299 310.8701 311.0102 311.1504 311.2905 311.4306 311.5707 311.7108 311.8509 311.9909 312.1310 312.2710 312.4110 312.5510 312.6910 312.8310 312.9709 313.1109 313.2508 313.3907 313.5306 313.6705 313.8104 313.9503 314.0901 314.2300 314.3698 314.5096 314.6494 314.7892 314.9290 315.0687 315.2085 315.3482 315.4879 315.6276 315.7673 315.9070 316.0466 316.1863 316.3259 316.4656 316.6052 316.7448 316.8843 317.0239 317.1635 317.3030 317.4425 317.5821 317.7216 317.8611 318.0005 318.1400 318.2794 318.4189 318.5583 318.6977 318.8371 318.9765 319.1159 319.2552 319.3946 319.5339 319.6732 319.8125 319.9518 320.0911 320.2304 320.3696 320.5089 320.6481 320.7873 320.9265 321.0657 321.2049 321.3441 321.4832 321.6223 321.7615 321.9006 322.0397 322.1788 322.3178 322.4569 322.5960 322.7350 322.8740 323.0130 323.1520 323.2910 323.4300 323.5689 323.7079 323.8468 323.9857 324.1246 324.2635 324.4024 324.5413 324.6801 324.8190 324.9578 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220712T122010.7Z 8228.514012 181 1 50.16 2 80.74 69.97 118.19 253.17 0.00 1 0.00 1 0 25 5.899e-01 2.930e-02 2.675e-01 6.605e-03 7.230551e-01 3.731837e-03 7.769282e-03 -6.000000e+00 3.455103e-01 230.15 -2.00 3.24 -2.00 321.45 0.00e+00 2.982733e-03 1.982184e-03 3.326019e-03 -6.000000e+00 1.724658e-02 294.05 -2.00 20.00 -2.00 320.78 0.00e+00 5.899 0.002 302.00 328.00 3 2.8698e+00 1.3974e-02 6.9984e-02 -6.0000e+00 8.6390e-01 4.1560e-01 1.9144e-02 4.0433e-02 -6.0000e+00 9.3855e-01 -5.9837e-01 1.6535e-02 1.9897e-02 -6.0000e+00 5.5711e-01 2.4756e-01 7.7232e-03 5.3526e-03 -6.0000e+00 2.3968e-01 3.9409e-05 -1.2090e-03 1.8718e-04 9.1552e-05 -6.0000e+00 1.7469e-02 -2.2239e-03 1.4322e-04 12 8 8 10 0 0 58.17 24.59 0.68 -0.00222 -0.01131 26 6 1 5 0 1928.780 27.05 20.00 24.59 35.00 26.0 1008.99 -29615 900000 -317 900000 -183775 -229205 900000 -112500 900000 -7339 -188849 900000 -123906 900000 -88845 900000 128221 97546 148341 900000 228684 11667 -84203 900000 -3126 83433 -12510 -24924 18166 -99444 900000 119670 220375 -16797 -19648 38251 900000 900000 113354 10331 20231 111146 109092 114032 45613 77566 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-3862 -521 -80 -3015 763 -3838 -1850 -5212 2948 693 -2334 -2129 2860 -1705 -1360 1264 2512 -1197 462 64 -537 -141 -465 -1667 896 4190 3377 1891 -408 4501 -360 3096 -141 1626 863 111 -818 5481 -2135 22 1709 961 109 -2159 208 -6404 -893 SS 20220712T123000.1Z 8228.520834 186 1 49.33 2 78.73 71.06 120.13 254.02 0.00 1 0.00 1 0 25 1.269e+00 5.937e-02 1.414e-01 3.063e-03 5.624916e-01 1.625774e-03 1.536512e-02 -6.000000e+00 7.397200e-01 230.15 -2.00 3.24 -2.00 320.63 0.00e+00 4.676912e-02 7.229288e-04 2.009031e-02 -6.000000e+00 3.628342e-02 294.05 -2.00 20.00 -2.00 319.92 0.00e+00 4.938 0.001 302.00 328.00 3 2.5467e+00 5.4731e-03 9.5129e-02 -6.0000e+00 1.8479e+00 8.6134e-01 6.2905e-03 6.9406e-02 -6.0000e+00 2.0040e+00 -1.4230e+00 3.0779e-03 1.5153e-02 -6.0000e+00 1.1884e+00 6.6030e-01 1.7378e-03 3.4802e-03 -6.0000e+00 5.0952e-01 1.3749e-04 -1.4683e-03 8.4394e-05 5.8922e-04 -6.0000e+00 3.5738e-02 -1.7559e-03 9.4361e-05 12 8 8 10 0 0 63.80 24.60 0.50 -0.00176 -0.01279 57 12 1 5 0 865.280 27.05 19.99 24.60 35.36 26.3 1011.14 -39914 900000 476242 900000 348852 286630 900000 228821 900000 447705 147949 900000 188250 331760 268113 318054 350078 292400 295621 344666 267184 235858 171853 210882 151227 165314 120352 139831 142629 128422 240199 191126 186370 146969 140415 153833 167752 147791 102674 80450 69370 79581 80782 84387 84192 85417 74431 76500 88933 66631 78232 58718 54175 47350 42851 29262 23318 5970 12462 14619 26059 22861 24960 26016 23853 23466 20158 12792 11851 7091 6024 1147 -528 -3349 -72 464 -9153 -4232 -2862 -536 -2301 -4954 -6267 -4580 -8841 -10536 -8287 -7188 -7118 -4558 -6252 -5838 -9316 -11440 -10477 -7215 -6523 -3284 -2697 -2002 -1281 -3200 -3665 -5251 -2970 -3666 -3161 -2211 441 34 163 460 301 -664 -863 67 803 2045 2764 3210 3677 5441 5727 4870 4033 5258 3647 4759 3685 3651 3179 1991 1600 1477 -361 -1070 -984 -1190 -1657 -2225 -1575 -3461 -4209 -17837 900000 1777 900000 3124 3689 900000 3287 900000 1336 2805 900000 3801 2352 4601 3856 3330 5182 5073 3472 5283 5456 5914 4248 4354 3947 4036 4121 4182 5186 4212 6073 6806 7767 6976 6158 5861 6590 7625 7363 7223 7693 8184 8731 9200 9702 9762 10084 10484 10076 11156 10758 10170 9617 8791 6504 5212 1508 2885 3431 5976 6177 7567 8668 8333 7863 6697 4555 4576 3047 2787 562 -253 -1527 -29 174 -3564 -1627 -1189 -261 -1325 -3124 -4286 -3216 -6859 -8410 -6790 -6006 -5965 -3768 -4893 -4213 -6620 -8554 -8775 -6579 -6656 -3753 -3198 -2456 -1459 -3340 -3700 -5457 -3109 -4113 -3769 -2712 582 49 255 722 488 -1042 -1281 95 1158 3090 4447 5185 5906 8662 8786 7260 6045 7486 5109 6866 5783 6177 5887 3798 3190 2989 -790 -2379 -2229 -2738 -3818 -4959 -3401 -7154 -8740 SS 20220712T123600.5Z 8228.525006 189 1 49.39 2 77.50 71.72 121.32 254.54 0.00 1 0.00 1 0 25 9.764e-01 5.017e-02 1.656e-01 2.168e-03 5.240220e-01 1.121242e-03 1.105467e-02 -6.000000e+00 5.644123e-01 230.15 -2.00 3.24 -2.00 320.38 0.00e+00 3.534288e-02 4.335767e-04 1.209266e-02 -6.000000e+00 2.630002e-02 294.05 -2.00 20.00 -2.00 319.58 0.00e+00 4.486 0.001 302.00 328.00 3 2.5133e+00 3.5663e-03 6.6101e-02 -6.0000e+00 1.4083e+00 4.8748e-01 4.1977e-03 4.2900e-02 -6.0000e+00 1.5255e+00 -8.6544e-01 2.5946e-03 2.0197e-02 -6.0000e+00 9.0945e-01 4.1301e-01 1.3677e-03 1.0052e-02 -6.0000e+00 3.8776e-01 2.4697e-04 -1.0284e-03 5.9692e-05 4.1132e-04 -6.0000e+00 2.6668e-02 -1.9901e-03 7.4787e-05 12 9 8 11 8 0 73.55 24.60 0.42 -0.00199 -0.00972 79 17 1 5 0 625.070 27.05 20.00 24.60 35.49 26.1 1012.00 -116042 314985 278661 432775 176667 190293 395170 167972 900000 195775 52344 320511 110857 196257 144842 320948 183430 169220 198555 166927 169016 126743 116906 104249 91778 73972 72994 71853 88818 67420 129952 108186 101780 90800 75988 87345 76819 80725 52279 45435 31222 40512 40752 42735 45468 47654 44533 43146 52154 37757 44692 31179 31315 25270 20732 12745 7346 -738 3070 5509 12412 12989 13860 14857 12159 13654 9943 6101 4833 2566 1895 -1511 -2846 -4128 -2773 -3772 -6955 -4568 -2261 -1912 -1903 -4869 -5297 -4480 -6494 -7500 -5878 -5529 -4761 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